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Corrosion Mechanisms in Theory and Practice

Third Edition

CORROSION TECHNOLOGY

Editor, Philip A. Schweitzer, P.E., Consultant, York, Pennsylvania

Corrosion Protection Handbook, Second Edition, Revised and Expanded, Philip A. Schweitzer

Corrosion Resistant Coatings Technology, Ichiro Suzuki

Corrosion Resistance of Elastomers, Philip A. Schweitzer

Corrosion Resistance Tables: Metals, Nonmetals, Coatings, Mortars, Plastics, Elastomers and Linings, and Fabrics, Third Edition, Revised and Expanded (Parts A and B), Philip A. Schweitzer

Corrosion-Resistant Piping Systems, Philip A. Schweitzer

Corrosion Resistance of Zinc and Zinc Alloys: Fundamentals and Applications, Frank Porter

Corrosion of Ceramics, Ronald A. McCauley

Corrosion Mechanisms in Theory and Practice, P. Marcus and J. Oudar

Corrosion Resistance of Stainless Steels, C. P. Dillon

Corrosion Resistance Tables: Metals, Nonmetals, Coatings, Mortars, Plastics, Elastomers and Linings, and Fabrics, Fourth Edition, Revised and Expanded (Parts A, B, and C), Philip A. Schweitzer

Corrosion Engineering Handbook, Philip A. Schweitzer

Atmospheric Degradation and Corrosion Control, Philip A. Schweitzer

Mechanical and Corrosion-Resistant Properties of Plastics and Elastomers, Philip A. Schweitzer

Environmental Degradation of Metals, U. K. Chatterjee, S. K. Bose, and S. K. Roy

Environmental Effects on Engineered Materials, Russell H. Jones

Corrosion-Resistant Linings and Coatings, Philip A. Schweitzer

Corrosion Mechanisms in Theory and Practice, Second Edition, Revised and Expanded, Philippe Marcus

Electrochemical Techniques in Corrosion Science and Engineering, Robert G. Kelly, John R. Scully, David W. Shoesmith, and Rudolph G. Buchheit

Metallic Materials: Physical, Mechanical, and Corrosion Properties, Philip A. Schweitzer

Corrosion Resistance Tables: Metals, Nonmetals, Coatings, Mortars, Plastics, Elastomers and Linings, and Fabrics, Fifth Edition, Philip A. Schweitzer

Corrosion of Ceramic and Composite Materials, Second Edition, Ronald A. McCauley

Analytical Methods in Corrosion Science and Engineering, Philippe Marcus and Florian Mansfeld

Paint and Coatings: Applications and Corrosion Resistance, Philip A. Schweitzer

Corrosion Control Through Organic Coatings, Amy Forsgren

Corrosion Engineering Handbook, Second Edition - 3 Volume Set, Philip A. Schweitzer

Fundamentals of Corrosion: Mechanisms, Causes, and Preventative Methods, Philip A. Schweitzer

Corrosion Mechanisms in Theory and Practice, Third Edition, Philippe Marcus

Corrosion Mechanisms in Theory and Practice

Third Edition

CRC Press

Taylor & Francis Group

6000 Broken Sound Parkway NW, Suite 300

Boca Raton, FL 33487-2742

© 2012 by Taylor & Francis Group, LLC

CRC Press is an imprint of Taylor & Francis Group, an Informa business

No claim to original U.S. Government works

Printed in the United States of America on acid-free paper

Version Date: 20110526

International Standard Book Number: 978-1-4200-9462-6 (Hardback)

This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint.

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Library of Congress Cataloging‑in‑Publication Data

Corrosion mechanisms in theory and practice. -- 3rd ed. / edited by Philippe Marcus. p. cm. -- (Corrosion technology ; 26)

Summary: “Building on previous editions described as “a useful contribution to the current literature on corrosion science, engineering, and technology” by Corrosion Review, this third installment offers real-world applications and problem-solving techniques to reduce the occurrence of pits, cracks, and deterioration in industrial, automotive, marine, and electronic structures. It also details the electrochemical and chemical properties, adsorption mechanisms, environmental parameters, and microstructural factors that influence corrosion formation. Including contributions from authors around the world, this reorganized third edition covers the most recent advances in the field, adding three new chapters on Fundamentals of Corrosion from a Surface Science and Electrochemical Basis, High-Temperature Oxidation, and Atomistic Modeling of Corrosion”-- Provided by publisher.

Includes bibliographical references and index.

ISBN 978-1-4200-9462-6 (hardback)

1. Corrosion and anti-corrosives. I. Marcus, P. (Philippe), 1953- II. Title. III. Series.

TA462.C65575 2011 620.1’1223--dc22

Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com

and the CRC Press Web site at http://www.crcpress.com

2010053752

1. Fundamentals of Corrosion...................................................................................................1

Hans-Henning Strehblow and Philippe Marcus

2. Surface Effects on Hydrogen Entry into Metals...........................................................105

Elie Protopopoff and Philippe Marcus

3. Anodic Dissolution.............................................................................................................149

Michel Keddam

4. Thin Oxide Film Formation on Metals...........................................................................217

Francis P. Fehlner and Michael J. Graham

5. Passivity of Metals..............................................................................................................235

Hans-Henning Strehblow, Vincent Maurice, and Philippe Marcus

6. Passivity of Austenitic Stainless Steels..........................................................................327

Clive R. Clayton and lngemar Olefjord

7. Mechanisms of Pitting Corrosion....................................................................................349

Hans-Henning Strehblow and Philippe Marcus

8. Sulfur-Assisted Corrosion Mechanisms and the Role of Alloyed Elements..........395 Philippe Marcus

9. Further Insights on the Pitting Corrosion of Stainless Steels...................................419

Bernard Baroux

10. Crevice Corrosion of Metallic Materials........................................................................449 Pierre Combrade

11. Stress-Corrosion Cracking Mechanisms........................................................................499

Roger C. Newman

12. Corrosion Fatigue Mechanisms in Metallic Materials................................................545 T. Magnin

13. High-Temperature Corrosion............................................................................................573

Michael Schütze

14. Corrosion Prevention by Adsorbed Organic Monolayers and Ultrathin Plasma Polymer Films........................................................................................................617 Michael Rohwerder, Martin Stratmann, and Guido Grundmeier

15. Atmospheric Corrosion......................................................................................................669 Christofer Leygraf

16. Corrosion of Aluminum Alloys........................................................................................705 Nick Birbilis, T.H. Muster, and Rudolph G. Buchheit

17. Microbially Influenced Corrosion...................................................................................737 Dominique Thierry and Wolfgang Sand

18. Corrosion in Nuclear Systems: Environmentally Assisted Cracking in Light Water Reactors......................................................................................................777 F.P. Ford and P.L. Andresen

19. Corrosion of Microelectronic and Magnetic Data-Storage Devices.........................825 Gerald S. Frankel and Jeffrey W. Braithwaite

20. Organic Coatings.................................................................................................................863

J.H.W. de Wit, D.H. van der Weijde, and G. Ferrari

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