Chemistry for Engineers Exam Answer Key - 3323 Verified Questions

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Chemistry for Engineers

Exam Answer Key

Course Introduction

Chemistry for Engineers introduces the fundamental principles of chemistry with a focus on applications relevant to engineering disciplines. The course covers atomic and molecular structure, chemical bonding, stoichiometry, thermodynamics, kinetics, equilibrium, and electrochemistry. Emphasis is placed on understanding how these concepts underpin processes and materials commonly encountered in various branches of engineering, such as civil, mechanical, electrical, and chemical engineering. Laboratory experiments and problem-solving sessions help students develop practical skills and a deeper appreciation of the role of chemistry in technological innovation and sustainable solutions.

Recommended Textbook

General Chemistry Principles and Modern Applications 11th Edition by Ralph H. Petrucci

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28 Chapters

3323 Verified Questions

3323 Flashcards

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Chapter 1: Matter: Its Properties and Measurement

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Sample Questions

Q1) At what temperature will the numerical values of the Celsius and Fahrenheit scales be the same?

A)0 °

B)-40 °

C)40 °

D)-273 °

E)80 °

Answer: B

Q2) Calculate the length of a steel cable (density 7.91 g/cm<sup>3</sup>)with a mass of 160.0 g and cross-sectional area of 0.500 cm<sup>2</sup>.

A)40.5 cm

B)20.23 cm

C)40.46 cm

D)20.2 cm

E)10.1 cm

Answer: A

Q3) A homogeneous mixture has regions that are different in composition or phase. A)True

B)False

Answer: False

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Chapter 2: Atoms and the Atomic Theory

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Sample Questions

Q1) Which of the following statements is FALSE?

A)Michael Faraday discovered cathode rays.

B)J .J.Thomson suggested the "plum pudding" model of the atom.

C)Robert Millikan determined the charge on an electron.

D)J.J.Thomson determined the mass-to-charge ratio for electrons.

E)Michael Faraday determined that cathode rays were the fundamental negatively charged particles and called them electrons.

Answer: E

Q2) Main group elements are those in groups ________.

A)1 and 2

B)1,2,and 13 to 18

C)13 to 18

D)1 and 18

E)3 to 12

Answer: B

Q3) The number of protons and neutrons in the nucleus of a given atom is called the atomic number.

A)True

B)False

Answer: False

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Chapter 3: Chemical Compounds

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Sample Questions

Q1) How many grams of Cr are found in 1.00 × 10<sup>2</sup> g of K<sub>2</sub>Cr<sub>2</sub>O<sub>7</sub>?

A)35.4 g

B)24.3 g

C)12.2 g

D)48.6 g

E)33.8 g

Answer: A

Q2) An organic compound contains C,H,and O.The percentages of H and C are 6.73% H,and 39.99% C by mass.The molecular mass is 60.06 u.What is the molecular formula of the compound?

A)CH<sub>2</sub>O

B)C<sub>3</sub>H<sub>6</sub>O3

C)C<sub>2</sub>H<sub>3</sub>O<sub>2 </sub>

D)C<sub>2</sub>H<sub>4</sub>O<sub>2 </sub>

E)C<sub>4</sub>H<sub>8</sub>O<sub>4 </sub>

Answer: D

Q3) Determine the mass percent (to the hundredths place)of H in sodium bicarbonate (NaHCO<sub>3</sub>).

Answer: 1.20

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Chapter 4: Chemical Reactions

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Sample Questions

Q1) 24.0 g of ethane (C<sub>2</sub>H<sub>6</sub>)are burned to form CO<sub>2</sub> and H<sub>2</sub>O.How many grams of CO<sub>2</sub> are produced?

A)32.8 g

B)14.4 g

C)43.2 g

D)35.1 g

E)70.3 g

Q2) Write the complete balanced equation for the complete combustion reaction expected to occur between C<sub>3</sub>H<sub>7</sub>OH and O<sub>2</sub>.

A)C<sub>3</sub>H<sub>7</sub>OH + O<sub>2</sub> 3 CO<sub>2</sub> + 4 H<sub>2</sub>O

B)3 C<sub>3</sub>H<sub>7</sub>OH + 9 O<sub>2</sub> 6 CO<sub>2</sub> + 8 H<sub>2</sub>O + 3 C

C)2 C<sub>3</sub>H<sub>7</sub>OH + 6 O<sub>2</sub> CO + 8 H<sub>2</sub>O

D)2 C<sub>3</sub>H<sub>7</sub>OH + 9 O<sub>2</sub> 6 CO<sub>2</sub> + 8 H<sub>2</sub>O

E)2 C<sub>3</sub>H<sub>7</sub>OH + 9 O<sub>2</sub> 6 C + 8 H<sub>2</sub> + 10 O<sub>2 </sub>

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Chapter 5: Introduction to Reactions in Aqueous Solutions

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Sample Questions

Q1) Based on the balanced chemical equation shown below,what volume of 0.250 mol L<sup>-1</sup> K<sub>2</sub>S<sub>2</sub>O<sub>3</sub>(aq)is needed to completely react with 24.88 mL of 0.125 mol L<sup>-1</sup> KI<sub>3</sub>(aq),according to the following chemical equation: 2 S<sub>2</sub>O<sub>3</sub><sup>2-</sup>(aq)+ I<sub>3</sub><sup>-</sup>(aq) S<sub>4</sub>O<sub>6</sub><sup>2-</sup>(aq)+ 3 I<sup>-</sup>(aq)

A)6.22 mL

B)12.4 mL

C)24.9 mL

D)99.5 mL

Q2) Which of the following would have the strongest tendency of producing OH<sup>-</sup> ions in an aqueous solution?

A)Fe(OH)<sub>2</sub>

B)Fe(OH)<sub>3</sub>

C)Ba(OH)<sub>2</sub>

D)NaOH

E)HOCl

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Chapter 6: Gases

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Sample Questions

Q1) A sample of gas weighs 0.250 g and occupies a volume of 112 cm<sup>3</sup> at 0 °C and 1 atm.The molar mass of the gas is ________.

A)25.0 g/mol

B)50.0 g/mol

C)2.23 g/mol

D)8.0 g/mol

E)200 g/mol

Q2) A balloon filled with helium gas at 20 °C occupies 4.91 L at 1.00 atm.The balloon is immersed in liquid nitrogen at -196 °C,while the pressure is raised to 5.20 atm.What is the volume of the balloon in the liquid nitrogen?

A)0.25 L

B)3.6 L

C)6.7 L

D)97 L

Q3) The relationship between the "absolute temperature" on the Kelvin scale and the Celsius temperature is given by T(K)= 5/8[t(°C)] - 32.

A)True

B)False

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Chapter 7: Thermochemistry

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Sample Questions

Q1) The standard heat of formation of solid ammonium bromide is -270.8 kJ/mol.Write the chemical equation for the reaction to which this value applies.

Q2) Determine the enthalpy change in the following equation: Cl<sub>2</sub>(g)+ H<sub>2</sub>O(l) 2 HCl(g)+ 1/2 O<sub>2</sub>(g) <sub>f</sub>H° H<sub>2</sub>O(l)= -285.8 kJ/mol <sub>f</sub>H° HCl(g)= -92.31 kJ/mol

A)193.5 kJ/mol

B)-470.4 kJ/mol

C)470.4 kJ/mol

D)101.2 kJ/mol

E)-101.2 kJ/mol

Q3) A 50.0 g sample of liquid water at 25.0 °C is mixed with 23.0 g of water at 89.0 °C.The final temperature of the water is ________ °C.

A)132

B)27.3

C)57.0

D)260

E)45.2

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Chapter 8: Electrons in Atoms

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Sample Questions

Q1) Four of the 3d orbitals are alike except for the orientation with respect to the axes.

A)True

B)False

Q2) Which element has the ground-state electron configuration [Rn]7s<sup>2</sup> <sup> </sup><sup> </sup>6<sup>d </sup><sup>2</sup>?

A)Rf

B)Sg

C)Th

D)Pa

Q3) What is the energy in joules of a mole of photons with the energy of the 656 nm spectral line of hydrogen?

A)2.62 × 10<sup>-7 </sup>J

B)78.3 J

C)3.03<sup> </sup>J

D)8.73 × 10<sup>-25 </sup>J

E)1.82 × 10<sup>5 </sup>J

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Chapter 9: The Periodic Table and Some Atomic Properties

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Sample Questions

Q1) Why is the electron affinity slightly positive for some of the group 2 elements?

A)The added electron would have to go into a new shell.

B)The added electron would have to be added into the half-filled p subshell.

C)The added electron would have to be added into the p subshell.

D)The groups 2 elements are diatomic elements.

E)Electrons can't be added to metals.

Q2) Moseley used X-rays to determine the atomic mass of each element.

A)True

B)False

Q3) Which atom in each group (I and II)has the smallest atomic radius?

(I)Ba,Hf,At

(II)As,Sb,Bi

A)Ba;As

B)Ba;Bi

C)At;As

D)At;Bi

Q4) The ionization energy is the energy required for a gaseous atom to lose an electron.

A)True B)False

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Chapter 10: Chemical Bonding I: Basic Concepts

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Sample Questions

Q1) A Lewis structure is a combination of Lewis symbols representing either the transfer or the sharing of electrons in a chemical bond.

A)True

B)False

Q2) Which chloride should have the greatest covalent character?

A)NaCl

B)BeCl<sub>2 </sub>

C)KCl

D)BaCl<sub>2 </sub>

E)CaCl<sub>2 </sub>

Q3) Which compound would be expected to have the shortest nitrogen-nitrogen bond?

A)H<sub>2</sub>NNH<sub>2 </sub>

B)HNNH

C)N<sub>2 </sub>

D)O<sub>2</sub>NNO<sub>2 </sub>

E)(CH<sub>3</sub>)<sub>2</sub>NNH<sub>2 </sub>

Q4) In a Lewis structure,the number of valence electrons shown is one less for each negative charge.

A)True

B)False

Page 12

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Chapter 11: Chemical Bonding Ii: Valence Bond and

Molecular Orbital Theories

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Sample Questions

Q1) What is the molecular geometry of ClF<sub>4</sub> <sup>-</sup>?

A)seesaw

B)square planar

C)square pyramidal

D)tetrahedral

Q2) Which of the pairs of molecules below have the same hybridization on the central atom? (The central atom is underlined. )

A)HOCl,ClF<sub>3 </sub>

B)H<sub>2</sub>O,HNO

C)HCN,CO<sub>2 </sub>

D)BeH<sub>2</sub>,NH<sub>3 </sub>

E)H<sub>3</sub>COH,CH<sub>2</sub>O

Q3) Which statement regarding VB theory is INCORRECT?

A)A single bond is a sigma bond.

B)A triple bond is two sigma bonds and a pi bond.

C)A double bond requires each atom to have an unhybridized p orbital.

D)Both atoms in a triple bond have linear geometry.

E)sp<sup>3</sup> hybridization produces tetrahedral geometry.

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Chapter 12: Intermolecular Forces: Liquids and Solids

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Sample Questions

Q1) The heat of deposition equals the negative of the heat of ________.

A)fusion

B)condensation

C)sublimation

D)solidification

E)reposition

Q2) The heat of fusion for water is 6.01 kJ/mol and for ethyl alcohol is 5.01 kJ/mol.The amount of heat that would melt 25.0 grams of water would melt how many grams of ethyl alcohol?

A)76.7 g

B)53.3 g

C)11.7 g

D)8.2 g

E)30.0 g

Q3) An atom at the corner of cubic unit cell is shared among:

A)six adjoining unit cells

B)four adjoining unit cells

C)eight adjoining unit cells

D)ten adjoining unit cells

E)twelve adjoining unit cells

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Chapter 13: Spontaneous Change: Entropy and Gibbs Energy

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Sample Questions

Q1) What is <sub>r</sub>G° at 25 °C?

CO<sub>2</sub>(g) CO<sub>2</sub>(aq) <sub>r</sub>H° = -19.4 kJ <sub>r</sub>S° = 92.3 J/K

A)2.1 kJ

B)-46.9 kJ

C)-17.1 kJ

D)-19.5 kJ

E)-21.7 kJ

Q2) The chemical potential of a substance,m,represents the ability of a substance to change the Gibbs energy of a system.

A)True

B)False

Q3) Order the following by increasing entropy.

CO(g),COCl<sub>2</sub>(g),CO<sub>2</sub>(g),CaO(s)

A)CO<sub>2</sub> < CO < CaO < COCl<sub>2 </sub>

B)CaO < CO < CO<sub>2</sub> < COCl<sub>2 </sub>

C)COCl<sub>2</sub> < CO < CaO < CO<sub>2 </sub>

D)CO<sub>2</sub> < CaO < COCl<sub>2</sub> < CO

E)CO < CaO < COCl<sub>2</sub> < CO<sub>2 </sub>

Page 15

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Chapter 14: Solutions and Their Physical Properties

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Sample Questions

Q1) An unsaturated solution will have some undissolved solid in the bottom of the container.

A)True

B)False

Q2) 100 mL of LiNO<sub>3</sub>(aq),0.241 M is mixed with 240 mL of 0.618 M

Ca(NO<sub>3</sub>)<sub>2</sub>(aq).What is the final concentration of NO<sub>3</sub><sup>-</sup>(aq)in the solution?

A)0.508 M

B)1.01 M

C)0.943 M

D)0.756 M

E)1.38 M

Q3) A solution prepared by dissolving 4.00 g KCl in 36.0 g H<sub>2</sub>O is said to be:

A)11.1% KCl by mass

B)0.100% KCl by mass

C)0.111% KCl by mass

D)10.0% KCl by mass

E)9.00% KCl by mass

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Chapter 15: Principles of Chemical Equilibrium

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Sample Questions

Q1) For the reaction: N<sub>2</sub>(g)+ 2 O<sub>2</sub>(g) 2 NO<sub>2</sub>(g),K<sub>c</sub> = 8.3 × 10<sup>-10</sup> M<sup>-1 </sup>at 25 °C.What is the concentration of N<sub>2</sub> gas at equilibrium when the concentration of NO<sub>2</sub> is five times the concentration of O<sub>2</sub> gas?

A)3.3 × 10<sup>-</sup><sup>11</sup> mol L<sup>-1</sup>

B)1.7 × 10<sup>-10</sup> mol L<sup>-1</sup>

C)6.0 × 10<sup>9</sup> mol L<sup>-1</sup>

D)3.0 × 10<sup>10</sup> mol L<sup>-1</sup>

Q2) The value of the equilibrium constant for a given reaction depends on the initial concentrations of reactants.

A)True

B)False

Q3) One method to aid in working out equilibrium problems is the ICE table.

A)True

B)False

Q4) For a solute (X)aq,in an ideal aqueous solution,its activity equals its concentration.

A)True

B)False

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Chapter 16: Acids and Bases

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Sample Questions

Q1) What is the pH of a 0.475 M aqueous solution of sodium nitrite? Ka (nitrous acid)= 7.2 × 10<sup>-4</sup>

A)8.58

B)8.41

C)12.27

D)5.42

E)5.59

Q2) What is the pH of a 0.375 M aqueous solution of benzoic acid? K<sub>a</sub> = 6.3 × 10<sup>-5 </sup>

A)8.9

B)5.1

C)2.3

D)0.43

E)11.7

Q3) At 25 °C,the pH of pure water is: A)0

B)>0,<7

C)7

D)>7,<14

E)14

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Chapter 17: Additional Aspects of Acidbase Equilibria

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Sample Questions

Q1) What is the pH of a solution made by mixing 30.00 mL of 0.10 mol L<sup>-1</sup> aqueous acetic acid (CH<sub>3</sub>COOH)with 50.00 mL of 0.100 mol L<sup>-1</sup> KOH(aq)? Assume that the volumes of the solutions are additive.K<sub>a</sub> = 1.8 × 10<sup>-5 </sup>for CH<sub>3</sub>COOH

A)8.26

B)9.26

C)11.13

D)12.40

Q2) Phenol red indicator changes from yellow to red in the pH range from 6.6 to 8.0.State what color the indicator will assume in the following solution: 0.1 M NaCl(aq).

A)red

B)yellow

C)red-yellow mixture

D)orange

E)The indicator keeps its original color.

Q3) Mixing comparable amounts of a strong acid and its conjugate base will form a buffer.

A)True

B)False

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Page 19

Chapter 18: Solubility and Complex-Ion Equilibria

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Sample Questions

Q1) Write the solubility product constant expression for the following salt: Ca(OH)<sub>2</sub>(s).<sub> </sub>

A)[Ca<sup>2+</sup>][OH<sup>-</sup>]

B)[Ca<sup>2+</sup>]<sup>2</sup>[OH<sup>-</sup>]

C)[Ca<sup>2+</sup>]<sup>3</sup>[OH<sup>-</sup>]

D)[Ca<sup>2+</sup>]<sup>2</sup>[OH<sup>-</sup>]<sup>2 </sup>

E)[Ca<sup>2+</sup>][OH<sup>-</sup>]<sup>2 </sup>

Q2) What is the molar solubility of AgCl(s)in 0.10 mol L<sup>-1</sup> NaCN(aq)if the colourless complex ion Ag(CN)<sub>2</sub><sup>-</sup>(aq)forms? K<sub>sp</sub> for AgCl(s)is 1.8 × 10<sup>-10</sup> and K<sub>f</sub> for Ag(CN)<sub>2</sub><sup>-</sup>(aq)is 1.0 × 10<sup>21</sup>.

A)0.050 mol L<sup>-1</sup>

B)0.10 mol L<sup>-1</sup>

C)0.20 mol L<sup>-1</sup>

D)0.40 mol L<sup>-1</sup>

Q3) Qualitative cation analysis has been replaced in recent years by instrumental analysis.

A)True

B)False

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Chapter 19: Electrochemistry

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Sample Questions

Q1) Choose the INCORRECT statement.

A)When a half reaction is reversed,the sign of the potential is changed.

B)Reversing a half reaction makes it a reduction potential.

C)Each electrochemical cell consists of a reduction half cell and an oxidation half cell.

D)A voltaic cell is also called a battery.

E)The potential difference of a cell is the voltage of the cell.

Q2) One mole of electrons has a charge of:

A)96,485 A

B)1.60 × 10<sup>-19 </sup>

C)6.02 × 10<sup>23</sup> A

D)96,485 C

E)96,485 F

Q3) Calculate the mass of I<sub>2</sub>(s)produced at the anode if a current of 2.85 A is passed through a solution of KI(aq)for 56 minutes.

A)0.42 g

B)0.13 g

C)13 g

D)25 g

E)4.3 g

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Page 21

Chapter 20: Chemical Kinetics

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Sample Questions

Q1) Why is rate = k[HgCl<sub>2</sub>] <sup>2</sup>[C<sub>2</sub>O<sub>4</sub><sup>2-</sup>] not the rate law for the following mechanism?

2 HgCl<sub>2</sub> + C<sub>2</sub>O<sub>4</sub><sup>2-</sup> 2 Cl<sup>-</sup> + 2 CO<sub>2</sub> + Hg<sub>2</sub>Cl<sub>2</sub> (overall reaction)

HgCl<sub>2</sub> + C<sub>2</sub>O<sub>4</sub><sup>2-</sup> HgCl<sub>2</sub>C<sub>2</sub>O<sub>4</sub><sup>2-</sup> (fast)

HgCl<sub>2</sub>C<sub>2</sub>O<sub>4</sub><sup>2-</sup> + C<sub>2</sub>O<sub>4</sub><sup>2-</sup> Hg + 2 C<sub>2</sub>O<sub>4</sub>Cl<sup>2-</sup> (slow)

Hg + HgCl<sub>2</sub> Hg<sub>2</sub>Cl<sub>2</sub> (fast)

2 C<sub>2</sub>O<sub>4</sub>Cl<sup>2-</sup> C<sub>2</sub>O<sub>4</sub><sup>2-</sup> + 2 Cl<sup>-</sup> + 2 CO<sub>2</sub> (fast)

A)The rate law is not based on the slow step of the proposed mechanism.

B)The steps do not add to the overall reaction.

C)The rate law does not agree with the overall reaction.

D)The exponents of HgCl<sub>2</sub> and C<sub>2</sub>O<sub>4</sub><sup>2-</sup> are not equal.

E)The first step is not the slow step.

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Chapter 21: Chemistry of the Main-Group Elements I:

Groups 1,2,13,and 14

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Sample Questions

Q1) An analysis of a Solvay plant show that for every 4.30 tons of NaCl consumed,4.75 tons of NaHCO<sub>3</sub> is obtained.What is the % efficiency of this process for converting NaCl to NaHCO<sub>3</sub>?

A)76.8%

B)61.8%

C)63.0%

D)158%

E)90.5%

Q2) Which of the following metal hydroxides has the lowest solubility?

A)NaOH

B)LiOH

C)Mg(OH)<sub>2</sub>

D)Ba(OH)<sub>2</sub>

E)Sr(OH)<sub>2</sub>

Q3) In diborane,B<sub>2</sub>H<sub>6</sub>,the hybridization of each boron is:

A)sp<sup>3</sup>

B)sp<sup>2</sup>

C)sp<sup>3</sup><sup>d</sup>

D)sp

E)sp<sup>3</sup><sup>d</sup><sup>2</sup>

Page 23

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Chapter 22: Chemistry of the Main-Group Elements Ii:

Groups 18,17,16,15,and Hydrogen

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Sample Questions

Q1) Choose the INCORRECT statement.

A)Hydroxylammine,NH<sub>2</sub>OH,is a weak acid.

B)Laughing gas,an anesthetic used in dentistry,is N<sub>2</sub>O.

C)Nitrogen forms oxides with oxidation states that range between +1 and +5.

D)Azides contain the N<sub>3</sub><sup>-</sup> ion.

E)An acid anhydride reacts with water to form an acid.

Q2) Write a balanced half equation for the following couple: O<sub>2</sub>(g)| OH<sup>-</sup>(aq)<sup> </sup>(basic)

A)O<sub>2</sub>(g)+ OH<sup>-</sup>(aq)+ 4 e<sup>-</sup> 2 H<sub>2</sub>O(l) B)O<sub>2</sub>(g)+ 2 H<sub>2</sub>O(l)+ 4 e<sup>-</sup> 4 OH<sup>-</sup>(aq)<sup> </sup>

C)O<sub>2</sub>(g)+ H<sub>2</sub>O(l)+ e<sup>-</sup> 2 OH<sup>-</sup>(aq)<sup> </sup>

D)O<sub>2</sub>(g)+ 2 H<sub>2</sub>O(l) 4 OH<sup>-</sup>(aq)+ 4 e<sup>- </sup> E)O<sub>2</sub>(g)+ 2 H<sub>2</sub>O(l)+ 4 e<sup>-</sup> 8 OH<sup>-</sup>(aq)<sup> </sup>

Q3) Oxygen is obtained commercially from air by fractional distillation.

A)True

B)False

Page 24

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Chapter 23: The Transition Elements

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Sample Questions

Q1) Which of the following elements is likely to have an atomic radius of 124 pm?

A)Fe

B)Ru

C)Os

D)Mo

Q2) Galvanized steel is iron coated with cadmium to prevent rust.

A)True

B)False

Q3) Transition group elements differ from main group metals in several ways.Which differences of the following are correct?

A)many of the metals and their compounds having catalytic activity

B)many of the hydrated cations having distinctive colors

C)most of their compounds having bonds that involve d orbitals

D)many of the metals being paramagnetic,but none ferromagnetic

E)most having more than one common oxidation state

Q4) How many d electrons are there in CrO<sub>7</sub><sup>2-</sup>?

A)0

B)1

C)2

D)3

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Chapter 24: Complex Ions and Coordination Compounds

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Sample Questions

Q1) High spin refers to the maximum number of ligands attached to the metal ion.

A)True

B)False

Q2) The [Fe(CN)<sub>6</sub>]<sup>3-</sup> complex ion:

A)exhibits square planar geometry

B)is diamagnetic

C)exhibits octahedral geometry

D)has two unpaired electrons

E)has four unpaired electrons

Q3) Which element possesses the smallest number of unpaired electrons?

A)Co

B)Cr

C)Cu

D)Mn<sup> </sup>

E)Fe

Q4) Which ion would you expect to have the largest crystal field splitting, ?

A)[Rh(CN)<sub>6</sub>]<sup>4-</sup>

B)[Rh(CN)<sub>6</sub>]<sup>3-</sup>

C)[Rh(H<sub>2</sub>O)<sub>6</sub>]<sup>2+</sup>

D)[Rh(H<sub>2</sub>O)<sub>6</sub>]<sup>3+</sup>

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Chapter 25: Nuclear Chemistry

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Sample Questions

Q1) The unit of radiation which is equivalent to 0.010 J/kg of matter is the:

A)curie

B)roentgen

C)rad

D)rem

E)MeV

Q2) What is the binding energy,in amu,of <sup>13</sup>C? Masses are: proton = 1.00728 amu,neutron = 1.00867 amu,electron = 0.00055 amu,and <sup>13</sup>C = 13.00335 amu.

A)0.10432 amu

B)0.0102 amu

C)0.10487 amu

D)0.10817 amu

E)0.00335 amu

Q3) Choose the INCORRECT statement.

A)Fusion is the basis of the hydrogen bomb.

B)Fusion is the splitting of a nucleus into two smaller nuclei.

C)Fusion is a reaction that occurs on the sun.

D)Fusion is not now used to produce electricity commercially.

E)Fusion can produce an almost unlimited amount of energy.

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Chapter 26: Structures of Organic Compounds

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Sample Questions

Q1) You found an organic compound containing chiral carbon atom with the following four substituents: HC C-,Cl-,O=C- and H<sub>2</sub>C=CH-.What would be the correct order of their priorities?

A)HC C- > O=C- > Cl- > H<sub>2</sub>C=CH-

B)Cl- > HC C- > O=C- > H<sub>2</sub>C=CH-

C)Cl- > O=C- > HC C- > H<sub>2</sub>C=CH-

D)Cl- > O=C-> H<sub>2</sub>C=CH- > HC C-

E)O=C- > Cl- > HC C- > H<sub>2</sub>C=CH-

Q2) Cis-trans isomerism is a type of isomerism generally known as stereoisomerism.

A)True

B)False

Q3) Name the following compound: CH<sub>3</sub>CH<sub>2</sub>NHCH<sub>3</sub>.

A)aminopropane

B)aminomethylethane

C)methylaminoethane

D)propylamine

E)ethylmethylamine

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Page 28

Chapter 27: Reactions of Organic Compounds

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Sample Questions

Q1) Markovnikof's rule predicts that when HBr is added to an unsymmetrical alkene or alkyne,the H atom will add to which carbon atom?

A)the carbon with the fewest attached hydrogens

B)the carbon with the Br

C)the carbon with the most attached hydrogens

D)the carbon next to the double or triple bond

E)HBr does not react with unsymmetrical alkenes or alkynes

Q2) What is "retrosynthesis"?

A)a chemical analysis followed by chemical synthesis

B)a chemical synthesis followed by chemical analysis

C)a synthetic procedure designed to check old synthetic procedure

D)a synthetic strategy that works from the desired compound towards starting materials

E)a synthetic strategy that works from the starting materials towards desired product

Q3) Nucleophiles are electron poor atoms,ions or groups.

A)True

B)False

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Chapter 28: Chemistry of the Living State

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Sample Questions

Q1) A typical E.coli bacterium is a cylindrical cell about 2 m long and 1 m in diameter,weighing about 1.8 × 10<sup>-12</sup> g and containing 80% water by volume.Calculate the number of lipid molecules present,assuming their average molecular weight is 688 g/mol and the lipid content is 1.9%.

A)8.3 × 10<sup>10 </sup>

B)2.1 × 10<sup>10 </sup>

C)2.4 × 10<sup>7 </sup>

D)1.6 × 10<sup>9 </sup>

E)3.0 × 10<sup>7 </sup>

Q2) Which of the following is a polysaccharide?

A)ribose

B)fructose

C)glucose

D)glycogen

E)pentose

Q3) Which of the following combinations make up the nucleic acid,RNA?

A)phosphate ribose and the bases A,G,U,C

B)phosphate ribose and the bases A,G,T,C

C)phosphate deoxyribose and the bases A,G,T,C

D)phosphate deoxyribose and the bases A,G,U,C

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