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Chemical Science is an interdisciplinary field that explores the composition, structure, properties, and changes of matter at the molecular and atomic levels. This course provides a comprehensive overview of fundamental chemical principles including atomic theory, chemical bonding, thermodynamics, kinetics, and equilibrium. Students will investigate the behavior of gases, liquids, and solids, study the periodic table and its implications, and explore the essentials of organic and inorganic chemistry. Laboratory sessions reinforce theoretical concepts through hands-on experiments, fostering skills in observation, analysis, and scientific reasoning. The course lays a strong foundation for advanced study in chemistry, environmental science, materials science, and related fields.
Recommended Textbook
General Chemistry 11th Edition by Darrell D. Ebbing
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Q1) The boiling point of chlorine is 172 K.This temperature corresponds to A)-82°C.
B)101°C.
C)172°C.
D)-172°C.
E)-101°C.
Answer: E
Q2) A car averages 28.5 miles per gallon of gasoline.How many liters of gasoline will be needed for a trip of 415 km? Some conversion factors that may be helpful are the following:
1 qt = 0.946 L
1 mile = 1.609 km
4 qt = 1 gal (exact)
1 ft = 12 in (exact)
A)3 × 10<sup>1</sup> L
B)5 × 10<sup>3</sup> L
C)2 × 10<sup>3</sup> L
D)9 × 10<sup>1</sup> L
E)3 × 10<sup>4</sup> L
Answer: A
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Q1) Which one of the following lists gives the correct symbols for the elements phosphorus,potassium,silver,chlorine,and sulfur?
A)P,Po,Ag,Cl,S
B)K,Ag,Po,Cl,S
C)P,K,Ag,Cl,S
D)Ph,K,Ag,S,Cl
E)Ph,Po,Ag,Cl,S
Answer: C
Q2) The elements in a row of the periodic table are known as A)metals.
B)a period.
C)metalloids.
D)a family.
E)a group.
Answer: B
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Q1) How many grams of potassium are present in 28.7 g of K<sub>2</sub>Cr<sub>2</sub>O<sub>7</sub>?
A)7.63 g
B)1.468 g
C)3.81 g
D)78.2 g
E)14.4 g
Answer: A
Q2) How many molecules are there in 60 g of acetic acid,C<sub>2</sub>H<sub>4</sub>O<sub>2</sub>?
A)(6.02 × 10<sup>23</sup>)/ 60
B)60
C)6.02 × 10<sup>23</sup>
D)30
E)60 × (6.02 × 10<sup>23</sup>)
Answer: C
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Q1) Which of the following do you need to know to be able to calculate the molarity of a salt solution?
I.the mass of salt added
II.the molar mass of the salt
III.the volume of water added
IV.the total volume of the solution
A)II and III only
B)I,II,and IV only
C)I,II,and III only
D)I and III only
E)You need all of the information.
Q2) What is the balanced reduction half-reaction for the reaction
3Mg(s)+ N<sub>2</sub>(g) Mg<sub>3</sub>N<sub>2</sub>(s)
A)Mg<sup>2+</sup> + 2e Mg
B)Mg Mg<sup>2+</sup> + 2e
C)Mg<sup>2+</sup> Mg + 2e
D)N<sub>2</sub> + 6e 2N<sup>3</sup><sup> </sup>
E)N<sub>2</sub> 2N<sup>3</sup><sup> </sup>+ 6e
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Q1) What is the partial pressure of carbon dioxide in a container that contains 3.63 mol of oxygen,1.49 mol of nitrogen,and 4.49 mol of carbon dioxide when the total pressure is 871 mmHg?
A)329 mmHg
B)763 mmHg
C)135 mmHg
D)406 mmHg
E)871 mmHg
Q2) Absolute zero is the point at which
A)a straight-line graph of V versus T (°C)intersects the origin.
B)a straight-line graph of 1/V versus P at constant T intersects the origin.
C)gaseous helium liquefies.
D)a straight-line graph of V versus 1/P at constant T intersects the origin.
E)a straight-line graph of V versus T (K)intersects the origin.
Q3) At STP,as the molar mass of the molecules that make up a pure gas increases,the
A)root mean square speed of the molecules increases.
B)root mean square speed of the molecules decreases.
C)root mean square speed of the molecules remains constant.
D)root mean square speed increases to a maximum,then decreases.
E)none of the above.
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Q1) What is H° for the following reaction?
2C<sub>2</sub>H<sub>2</sub>(g)+ 5O<sub>2</sub>(g) 4CO<sub>2</sub>(g)+ 2H<sub>2</sub>O(l)
Substance
H°<sub>f</sub> (kJ/mol)
C<sub>2</sub>H<sub>2</sub>(g)
+226.7
CO<sub>2</sub>(g) -393.5
H<sub>2</sub>O(l)
-285.8
A)+1692.2 kJ
B)-452.6 kJ
C)-1692.2 kJ
D)+2599.0 kJ
E)-2599.0 kJ
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Q1) The square of the wave function, <sup>2</sup>,of an electron in an atom
A)is inversely proportional to the distance between the electron and the nucleus.
B)specifies the momentum of the electron.
C)describes the energy of the electron.
D)is proportional to the velocity of the electron.
E)gives the probability of finding the electron in a region of space.
Q2) What is the energy per mole of photons with a wavelength of 307.1 nm?
(c=3.00×10<sup>8</sup> m/s,h=6.63×10<sup>-34</sup>
J·s,N<sub>A</sub>=6.02×10<sup>23</sup>mol<sup>-1</sup>)
A) 6.48×10<sup>-19</sup> kJ/mol
B)1.85×10<sup>14</sup> kJ/mol
C)5.88×10<sup>35</sup> kJ/mol
D)9.77×10<sup>14</sup> kJ/mol
E)3.9×10<sup>2</sup> kJ/mol
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Q1) The change in energy for which of the following processes corresponds to the first ionization energy of beryllium?
A)Be(g) Be<sup>+</sup>(g)+ e<sup>-</sup>
B)Be(s) Be<sup>+</sup>(s)+ e<sup>-</sup>
C)Be(s) Be<sup>+</sup>(g)+ e<sup>-</sup>
D)Be(g) Be<sup>2+</sup>(g)+ 2e<sup>-</sup>
E)Be(s)+ e<sup>- </sup> Be<sup>-(s)</sup>
Q2) What is the ground-state electron configuration of sulfur (S)?
A)[Ne]3s<sup>3</sup>3p<sup>3</sup>
B)[Ar]3s<sup>2</sup>3p<sup>4</sup>
C)[Ar]3p<sup>6</sup>
D)[Ne]3s<sup>2</sup>3p<sup>4</sup>
E)[Ne]3p<sup>6</sup>
Q3) What is the valence-shell electron configuration for the fourth-period element in Group VA?
A)4s<sup>2</sup>5p<sup>5</sup>
B)5s<sup>2</sup>5p<sup>5</sup>
C)4s<sup>2</sup>4p<sup>3</sup>
D)5s<sup>2</sup>4p<sup>5</sup>
E)4s<sup>2</sup>3d<sup>3</sup>
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Q1) What is the total number of valence electrons in N<sub>2</sub>O?
A)16
B)17
C)34
D)11
E)22
Q2) The electronic structure of which of the following species cannot be adequately described by a single Lewis formula?
A)CS<sub>2</sub>
B)POF<sub>3</sub>
C)HNNH
D)NO<sub>3</sub><sup>-</sup>
E)H<sub>2</sub>NNH<sub>2</sub>
Q3) All of the following species are isoelectronic except
A)S<sup>2-</sup>
B)K<sup>+</sup>
C)Na<sup>+</sup>
D)Ar
E)Cl<sup>-</sup>
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Q1) The configuration ( <sub>2s</sub>)<sup>2</sup>( <sub>2s</sub>*)<sup>2</sup>( <sub>2py</sub>)<sup>1 </sup>( <sub>2px</sub>)<sup>1</sup> is the molecular orbital description for the ground state of A)C<sub>2</sub>.
B)B<sub>2</sub>.
C)Be<sub>2</sub>.
D)Li<sub>2</sub><sup>+</sup>.
E)B<sub>2</sub><sup>2-</sup>.
Q2) The approximate H-C-H bond angle in CH<sub>3</sub><sup>+</sup> is A)60°.
B)90°.
C)120°.
D)109°.
E)180°.
Q3) Which molecule or ion has a trigonal planar molecular geometry?
A)PCl<sub>3</sub>
B)HCN
C)CO<sub>3</sub><sup>2-</sup>
D)HCCH
E)AsF<sub>3</sub>
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Q1) Which of the following indicates the existence of strong intermolecular forces of attraction in a liquid?
A)a very low critical temperature
B)a very low boiling point
C)a very low vapor pressure
D)a very low viscosity
E)a very low enthalpy of vaporization
Q2) Which of the following pure substances has the highest melting point?
A)CCl<sub>4</sub>
B)AlCl<sub>3</sub>
C)NCl<sub>3</sub>
D)LiCl
E)MgCl<sub>2</sub>
Q3) The strongest intermolecular forces present in a sample of pure I<sub>2</sub> are A)London forces.
B)dipole-dipole forces.
C)metallic bonds.
D)covalent network bonds.
E)covalent bonds.
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Q1) Which of the following pure liquids is the best solvent for carbon disulfide?
A)C<sub>6</sub>H<sub>6</sub>(l)
B)NH<sub>3</sub>(l)
C)CH<sub>3</sub>OH(l)
D)H<sub>2</sub>O(l)
E)HBr(l)
Q2) A suspension of silver particles in water is most likely to form what type of colloid?
A)aerosol
B)micelle
C)hydrophobic colloid
D)association colloid
E)hydrophilic colloid
Q3) A 3.140 molal solution of NaCl is prepared.How many grams of NaCl are present in a sample containing 2.692 kg of water?
A)299.7 g
B)494.0 g
C)144.6 g
D)845.3 g
E)none of these
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Q1) Which of the following statements is incorrect?
A)The rates of most chemical reactions change with time.
B)The rate constant for a reaction can be changed by changing the temperature.
C)The rate constant is dependent on the reactant concentrations.
D)In a series of stepwise reactions,the rate-determining step is the slowest one.
E)The rate of a catalyzed reaction is dependent on the concentration of the catalyst.
Q2) When the concentrations of the reactants are increased,the rate of the reaction increases.This is best explained by
A)an increase in the fraction of molecules that have enough energy to react.
B)an increase in the rate constant.
C)an increase in the average potential energy of the molecules.
D)an increase in the frequency of the molecular collisions.
E)an increase in the kinetic energy of the molecules.
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Q1) For which of the following values of the equilibrium constant does the reaction mixture contain mostly products?
A)10<sup>0</sup>
B)10<sup>1</sup>
C)10<sup>9</sup>
D)10<sup>-1</sup>
E)10<sup>-9</sup>
Q2) For a specific reaction,which of the following statements can be made about the equilibrium constant?
A)It can be changed by the addition of a catalyst.
B)It increases when the concentration of one of the products is increased.
C)It increases when the concentration of one of the reactants is increased.
D)It always remains the same.
E)It changes with changes in the temperature.
Q3) Which of the following represents a dynamic equilibrium?
A)a stoppered flask half full of water
B)a coin spinning in mid-air
C)two people of equal mass balanced on the ends of a seesaw
D)an open pan of boiling water
E)an object traveling at a constant speed
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Q1) What is the pOH of a solution prepared by dissolving 0.591 g of KOH(s)in 7.50 L of water?
A)11.148
B)2.852
C)1.977
D)12.023
E)7.000
Q2) What is the hydronium-ion concentration of a 0.0017 M Ba(OH)<sub>2</sub> solution?
A)3.4 × 10<sup>-3</sup> M
B)1.7 × 10<sup>-3</sup> M
C)2.9 × 10<sup>-12</sup> M
D)5.9 × 10<sup>-12</sup> M
E)1.0 × 10<sup>-7</sup> M
Q3) Which solution would cause blue litmus to turn red?
A)a solution of pH 10
B)a solution of 0.01 M NH<sub>3</sub>
C)a solution of pOH 4
D)a solution of 0.005 M CH<sub>3</sub>COOH
E)a solution of 0.10 M NaOH
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Q1) In a 0.20 M solution of a diprotic acid H<sub>2</sub>A (Ka<sub>1</sub> = 1.3 × 10<sup>-5</sup> and Ka<sub>2</sub> = 2.7 × 10<sup>-10</sup> at 25°C),what is the equilibrium concentration of A<sup>2-</sup>?
A)7.3 × 10<sup>-6</sup> M
B)2.7 × 10<sup>-10</sup> M
C)1.6 × 10<sup>-3</sup> M
D)0.40 M
E)0.20 M
Q2) What is K<sub>a</sub> for the anilinium cation,C<sub>6</sub>H<sub>5</sub>NH<sub>3</sub><sup>+</sup>,at 25°C? (K<sub>b</sub> for C<sub>6</sub>H<sub>5</sub>NH<sub>2</sub> = 4.2 × 10<sup>-10</sup> at 25°C.)
A)1.0 × 10<sup>-7</sup>
B)4.2 × 10<sup>4</sup>
C)4.2 × 10<sup>-24</sup>
D)2.4 × 10<sup>-5</sup>
E)4.2 × 10<sup>-10</sup>
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Q1) What is the molar solubility of nickel(II)sulfide in 0.091 M KCN? For NiS,K<sub>sp</sub> = 3.0 × 10<sup>-19</sup>; for Ni(CN)<sub>4</sub><sup>2-</sup>,K<sub>f</sub> = 1.0 × 10<sup>31</sup>.
A)5.5 × 10<sup>-10</sup> M
B)9.1 × 10<sup>-2</sup> M
C)1.5 × 10<sup>-19</sup> M
D)2.3 × 10<sup>-2</sup> M
E)2.9 × 10<sup>-5</sup> M
Q2) In which of these solutions would silver(I)carbonate have the lowest molar solubility? For silver(I)carbonate,K<sub>sp</sub> = 8.5 × 10<sup>-12</sup>.
A)0.03 M H<sub>2</sub>CO<sub>3</sub>
B)0.1 M AgNO<sub>3</sub>
C)0.01 M AgNO<sub>3</sub>
D)0.1 M Na<sub>2</sub>CO<sub>3</sub>
E)pure water
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Q1) The reaction CaO(s)+ SO<sub>3</sub>(g) CaSO<sub>4</sub>(s)is nonspontaneous at 2200 K,whereas it is spontaneous at room temperature.Which of the following statements is false?
A)The change in enthalpy is the main driving force of the reaction.
B)Both H and S are negative for the reaction.
C) G is negative at room temperature.
D)The change in entropy is the main driving force of the reaction.
E) G becomes zero at a temperature between 300 and 2200 K.
Q2) For a reaction that has an equilibrium constant of 6 × 10<sup>9</sup>,which of the following statements must be true?
A) S° is positive.
B) G° is negative.
C) G° is positive.
D) H° is negative.
E) H° is positive.
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Q1) If the value of E°<sub>cell</sub> is 2.10 V for the reaction F<sub>2</sub> (g)+ 2Fe<sup>2+</sup> (aq) 2Fe<sup>3+</sup> (aq)+ 2F<sup>-</sup> (aq),<sup> </sup><sup> </sup>
What is the value of E°<sub>cell</sub> for F<sup>-</sup> (aq)+ Fe<sup>3+</sup> (aq) Fe<sup>2+ </sup>(aq)+ 1/2 F<sub>2</sub>(g)?
A)-4.20 V
B)-1.05 V
C)2.10V
D)1.05 V
E)-2.10V
Q2) In a table of standard reduction potentials,the strongest reducing agents are the _______ species in the half-reactions with the _______ E° values.
A)reduced,most negative
B)oxidized,most positive
C)reduced,most positive
D)oxidized,most negative
E)none of these
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Q1) For which of the following radioactive decay processes does the atomic number not change?
A)electron capture
B)positron emission
C)alpha emission
D)gamma emission
E)beta emission
Q2) Which of the following corresponds to the most rapid nuclear decay?
A)t<sub>1/2</sub> = 1.0 × 10<sup>3</sup> min
B)t<sub>1/2</sub> = 1.0 × 10<sup>9</sup> year
C)k = 1.0 × 10<sup>-3</sup>/year
D)k = 1.0 × 10<sup>-1</sup>/day
E)k = 1.0 × 10<sup>-5</sup>/s
Q3) Which of the following nuclides will produce <sup>243</sup>Am upon undergoing alpha decay?
A)(<sup>247</sup>Bk)
B)(<sup>239</sup>Np)
C)(<sup>243</sup>Pu)
D)(<sup>243</sup>Cm)
E)(<sup>244</sup>Am)
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Q1) Which of the following compounds would not be expected to react with oxygen?
A)NH<sub>3</sub>
B)N<sub>2</sub>H<sub>4</sub>
C)N<sub>2</sub>O<sub>5</sub>
D)N<sub>2</sub>O<sub>4</sub>
E)Li<sub>3</sub>N
Q2) Which of the following reactions does not represent a commercial method for preparing hydrogen gas?
A)C<sub>3</sub>H<sub>8</sub>(g)+ 3H<sub>2</sub>O(g) 3CO(g)+ 7H<sub>2</sub>(g)
B)C(s)+ H<sub>2</sub>O(g) CO(g)+ H<sub>2</sub>(g)
C)2NH<sub>3</sub>(g) N<sub>2</sub>(g)+ 3H<sub>2</sub>(g)
D)2H<sub>2</sub>O(l) 2H<sub>2</sub>(g)+ O<sub>2</sub>(g)
E)CO(g)+ H<sub>2</sub>O(g) CO<sub>2</sub>(g)+ H<sub>2</sub>(g)
Q3) Which element is found in the ore galena?
A)aluminum
B)lead
C)silicon
D)germanium
E)tin
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Q1) Which of the following salts would not be expected to be colored in aqueous solution?
A)CrF<sub>3</sub>
B)NiF<sub>2</sub>
C)TiF<sub>3</sub>
D)ScF<sub>3</sub>
E)MnF<sub>3</sub>
Q2) The spectrochemical series is an arrangement of
A)ligands in order of their tendency to split the d orbitals of a transition metal ion.
B)coordination compounds in order of increasing ligand field splitting ( ).
C)complex ions in order of the wavelength of light absorbed.
D)ligands in the order of electronegativity.
E)ligands in order of Lewis basicity.
Q3) Which of the following is not a characteristic of the transition metals?
A)variable oxidation state
B)the ability to form many colored compounds
C)valence electrons in a d subshell
D)high electronegativity
E)the ability to form complex ions

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Q1) What is the common name for the following compound?
CH<sub>3</sub>CH<sub>2</sub>OCH<sub>2</sub>CH<sub>2</sub>CH<sub>3</sub>
A)2-pentanone
B)pentyl ether
C)2-pentanol
D)propoxyethane
E)ethyl propyl ether
Q2) What is the composition of crude oil?
A)mostly unsaturated hydrocarbons having 5-12 carbons per molecule
B)mostly hydrocarbons,but the precise composition varies widely depending on location
C)mostly aromatic hydrocarbons
D)mostly saturated hydrocarbons having 5-12 carbons per molecule
E)mostly saturated hydrocarbons having 12-20 carbons per molecule
Q3) Which of the following is the general formula for an alkane?
A)C<sub>n</sub>H<sub>2</sub><sub>n</sub><sub>+2</sub>
B)C<sub>2</sub><sub>n</sub>H<sub>2</sub><sub>n</sub><sub>-2</sub>
C)C<sub>n</sub>H<sub>n</sub>
D)C<sub>n</sub>H<sub>2</sub><sub>n</sub>
E)none of these
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Q1) What is the cell structure that contains the cell's DNA?
A)chromosome
B)codon
C)ribosome
D)gene
E)nucleus
Q2) Which of the following pairs of substances could form a polyester?
A)H<sub>2</sub>NCH<sub>2</sub>COOH +
H<sub>2</sub>NCH<sub>2</sub>CH<sub>2</sub>COOH
B)HO(CH<sub>2</sub>)<sub>4</sub>COOH + HOCH<sub>2</sub>CH=CHCH<sub>3</sub>
C)HOCH<sub>2</sub>CH<sub>2</sub>OH + HOOCCOOH
D)H<sub>2</sub>C=CHCH<sub>3</sub> + HOCH<sub>2</sub>CH<sub>2</sub>COOH
E)H<sub>2</sub>C=CHCN + H<sub>2</sub>C=CHCH<sub>3</sub>
Q3) Which of the following combinations can produce a condensation polymer? (R and R' are alkyl groups)
A)R OH + HOOC R' COOH
B)HO R OH + R' COOH
C)H<sub>2</sub>N R NH<sub>2</sub> + HOOC R' COOH
D)A and C
E)A,B,and C

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