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Manufactured Ceramic & Porcelain Tiles & Panels

Page 1


SAFETYDATASHEET

MANUFACTUREDCERAMICAND PORCELAINTILESANDPANELS

Section1-Identification

ProductIdentifier

MANUFACTUREDCERAMICANDPORCELAINTILESANDPANELS

CompanyName

NATIONALTILESPTYLTD(ABN57007381599)

Address

3/174-178TorquayRdGrovedale VIC3216Australia

Telephone/FaxNumber

Tel:1300.733.000

EmergencyPhoneNumber

PoisonsInformationCentre:131126(24hours)

ForAmbulance,PoliceorFireServices:CallTripleZero(000)

Recommendeduseofthechemicalandrestrictionsonuse

BuildingMaterial–forfloorandwallcladding

Section2-Hazard(s)Identification

GHSclassificationofthesubstance/mixture

ClassifiedasHazardousaccordingtotheGloballyHarmonisedSystemofClassificationandlabellingofChemicals(GHS)including Work,HealthandSafetyregulations,Australia.

NotclassifiedasDangerousGoodsaccordingtotheAustralianCodefortheTransportofDangerousGoodsbyRoadandRail.(7th edition)

Eyedamage/irritation:Category2

Carcinogenicity:Category1A

Specifictargetorgantoxicity(singleexposure):Category3(Respiratorytractirritation)

Specifictargetorgantoxicity(repeatedexposure):Category1

SignalWord(s)

DANGER

HazardStatement(s)

H319Causesseriouseyeirritation.

H350Maycausecancerbyinhalation.

H335Maycauserespiratoryirritation.

H372Causesdamagetoorgans(lungs)throughprolongedorrepeatedexposurebyinhalation.

Pictogram(s)

Healthhazard,Exclamationmark

PrecautionaryStatement–Prevention

P201Obtainspecialinstructionsbeforeuse.

P202Donothandleuntilallsafetyprecautionshavebeenreadandunderstood.

P260Donotbreathedust/fume/gas/mist/vapours/spray.

P264Washskinthoroughlyafterhandling.

P270Donoteat,drinkorsmokewhenusingthisproduct.

P271Useonlyoutdoorsorinawell-ventilatedarea.

P280Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection.

PrecautionaryStatement–Response

P312CallaPOISONCENTER/doctorifyoufeelunwell.

P304+P340IFINHALED:Removepersontofreshairandkeepcomfortableforbreathing.

P308+P313IFexposedorconcerned:Getmedicaladvice/attention.

P305+P351+P338IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo. Continuerinsing.

P337+P313Ifeyeirritationpersists:Getmedicaladvice/attention.

PrecautionaryStatement–Storage

P403+P233Storeinawell-ventilatedplace.Keepcontainertightlyclosed.

P405Storelockedup.

PrecautionaryStatement–Disposal

P501Disposeofcontents/containertoanapprovedwastedisposalplant.

IMPORTANTNOTE(S)

Theclassificationshownisonlyapplicablefordustproducedbythetileduringprocessessuchascuttingordrilling.Theproduct,as awhole,withnofreedustisconsiderednon-hazardous.

Section3-CompositionandInformationonIngredients

Section4-FirstAidMeasures

Inhalation

Ifinhaled,removeaffectedpersonfromcontaminatedarea.Applyartificialrespirationifnotbreathing.Seekmedicalattention.

Ingestion

Donotinducevomiting.Washoutmouththoroughlywithwater.Seekmedicalattention.

Skin

Washaffectedareathoroughlywithsoapandwater.Ifsymptomsdevelopseekmedicalattention.

Eye

Ifineyes,holdeyelidsapartandflushtheeyescontinuouslywithrunningwater.Removecontactlenses.Continueflushingfor severalminutesuntilallcontaminantsarewashedoutcompletely.Seekmedicalattention. Page2/8

FirstAidFacilities

Eyewash,safetyshowerandnormalwashroomfacilities.

AdvicetoDoctor

Treatsymptomatically.

OtherInformation

Foradviceinanemergency,contactaPoisonsInformationCentre(PhoneAustralia131126)oradoctoratonce.

Section5-FirefightingMeasures

SuitableExtinguishingMedia

Useappropriatefireextinguisherforsurroundingenvironment.

HazardsfromCombustionProducts Noncombustiblematerial.

Specifichazardsarisingfromthechemical Thisproductisnoncombustible.

DecompositionTemperature

Notavailable

PrecautionsinconnectionwithFire

FirefightersshouldwearSelf-ContainedBreathingApparatus(SCBA)operatedinpositivepressuremodeandfullprotectiveclothing topreventexposuretovapoursorfumes.Waterspraymaybeusedtocooldownheat-exposedcontainers.

Section6-AccidentalReleaseMeasures

EmergencyProcedures

Increaseventilation.Evacuateallunprotectedpersonnel.Wearsufficientrespiratoryprotectionandfullprotectiveclothingto preventexposure.Sweepupmaterialavoidingdustgenerationordampenspilledmaterialwithwatertoavoidairbornedust,then transfermaterialtoasuitablecontainer.Washsurfaceswellwithsoapandwater.Sealallwastesinlabelledcontainersfor subsequentrecyclingordisposal.Disposeofwasteaccordingtotheapplicablelocalandnationalregulations.Ifcontaminationof sewersorwaterwaysoccursinformthelocalwaterandwastemanagementauthoritiesinaccordancewithlocalregulations.

Section7-HandlingandStorage

PrecautionsforSafeHandling

Avoidinhalationofdust,andskinoreyecontact.Useonlyinawellventilatedarea.Keepcontainerssealedwhennotinuse. Preventthebuildupofdustintheworkatmosphere.Maintainhighstandardsofpersonalhygienei.e.Washinghandspriorto eating,drinking,smokingorusingtoiletfacilities.Wetcuttingmethodsarepreferabletominimisedustgeneration. Avoidexposure.Donothandleuntilallsafetyprecautionshavebeenreadandunderstood.

Conditionsforsafestorage,includinganyincompatibilities

Storeinacool,dry,well-ventilatedarea,outofdirectsunlightandmoisture.Storeinsuitable,labelledcontainers.Keepcontainers tightlyclosed.Storeawayfromincompatiblematerials.Ensurethatstorageconditionscomplywithapplicablelocalandnational regulations.

Section8-ExposureControlsandPersonalProtection

Occupationalexposurelimitvalues

Noexposurestandardshavebeenestablishedforthismaterial.However,theavailableexposurelimitsfortheingredientsthatmay bepresentintheproductsdustarelistedbelow:

Fumedsilica(respirabledust)

TWA:2mg/m³

Silica–Crystalline-Quartz(respirabledust)

TWA:0.05mg/m³

Note:Carc.1A

Aluminiumoxide

TWA:10mg/m³

Ironoxidefume(Fe2O3)(asFe)

TWA:5mg/m³

Titaniumdioxide

TWA:10mg/m³

Calciumoxide

TWA:2mg/m³

Magnesiumoxide(fume)

TWA:10mg/m³

TWA(TimeWeightedAverage):Theaverageairborneconcentrationofaparticularsubstancewhencalculatedoveranormal eight-hourworkingday,forafive-dayweek.

Carc.1A:Knowntohavecarcinogenicpotentialforhumans.

Source:SafeWorkAustralia.

BiologicalMonitoring Nobiologicallimitallocated.

ControlBanding Notavailable

EngineeringControls

Thissubstanceishazardousandshouldbeusedwithalocalexhaustventilationsystem,drawingsolid/dustawayfromworkers' breathingzone.Iftheengineeringcontrolsarenotsufficienttomaintainconcentrationsofparticulatesbelowtheexposure standards,suitablerespiratoryprotectionmustbeworn.

RespiratoryProtection

Ifengineeringcontrolsarenoteffectiveincontrollingairborneexposurethenanapprovedrespiratorwithareplaceable dust/particulatefiltershouldbeused.P2particulaterespiratorminimumwhendustgenerationispossible;P3respiratorstrongly recommendedforextendedoperations.Refertorelevantregulationsforfurtherinformationconcerningrespiratoryprotective requirements.

ReferenceshouldbemadetoAustralianStandardsAS/NZS1715,Selection,UseandMaintenanceofRespiratoryProtectiveDevices; andAS/NZS1716,RespiratoryProtectiveDevices,inordertomakeanynecessarychangesforindividualcircumstances.

EyeandFaceProtection

Safetyglasseswithsideshields,chemicalgogglesorfull-faceshieldasappropriateshouldbeused.Finalchoiceofappropriate eye/faceprotectionwillvaryaccordingtoindividualcircumstances.Eyeprotectiondevicesshouldconformtorelevantregulations. EyeprotectionshouldconformwithAustralian/NewZealandStandardAS/NZS1337(series)-EyeProtectorsforIndustrial Applications.

HandProtection

Wearglovesofimperviousmaterial.Finalchoiceofappropriategloveswillvaryaccordingtoindividualcircumstances.i.e.methods ofhandlingoraccordingtoriskassessmentsundertaken.Occupationalprotectiveglovesshouldconformtorelevantregulations. ReferenceshouldbemadetoAS/NZS2161.1:Occupationalprotectivegloves-Selection,useandmaintenance.

ThermalHazards

Nofurtherrelevantinformationavailable.

BodyProtection

Suitableprotectiveworkwear,e.g.cottonoverallsbuttonedatneckandwristisrecommended.Chemicalresistantapronis recommendedwherelargequantitiesarehandled.

Section9-PhysicalandChemicalProperties

Properties

Form

Colour Variouscolours

MeltingPoint >1204°C

DecompositionTemperature Notavailable

Odour Odourless

BoilingPoint Notavailable

SolubilityinWater Insoluble

SpecificGravity 1.6-2.1 pH Notavailable

VapourPressure Notavailable

EvaporationRate Notavailable

Viscosity Notavailable

PartitionCoefficient: n-octanol/water(logvalue) Notavailable

RelativeVapourDensity(Air=1) Notavailable

OdourThreshold Notavailable

VolatileComponent 0g/L(VOCs)

FlashPoint Notapplicable Flammability Non-combustiblesolid

Auto-IgnitionTemperature Notapplicable

ExplosionLimit-Upper Notavailable

ExplosionLimit-Lower Notavailable ExplosionProperties Notavailable

OxidisingProperties Notavailable

Section10-StabilityandReactivity

Reactivity

Reactswithincompatiblematerials.

ChemicalStability

Stableundernormalconditionsofstorageandhandling.

Possibilityofhazardousreactions

Reactswithincompatiblematerials.

ConditionstoAvoid

ParticleCharacteristics Notavailable

Dustyconditions.Extremesoftemperatureanddirectsunlight.Avoidcontactwithacids.

IncompatibleMaterials

Avoidcontactwithacids(e.g.,acetic,hydrofluoric,etc.).

HazardousDecompositionProducts

Thermaldecompositionmayresultinthereleaseoftoxicand/orirritatingfumes.

HazardousPolymerization Willnotoccur.

Section11-ToxicologicalInformation

ToxicologyInformation

Notoxicitydataavailableforthismaterial.Theavailableacutetoxicitydatafortheingredient/sis/aregivenbelow.

AcuteToxicity-Oral

CrystallineSilica(Quartz)

LD50(Rat):>22500mg/kg

LD50(Mouse):>15000mg/kg

LC50(Carp)>10000mg/l/72h

Ingestion

Ingestionofthisproductmayirritatethegastrictractcausingnauseaandvomiting.

Inhalation

Inhalationofdusts/fibresmayirritatetherespiratorysystem.

Maycauserespiratoryirritation.Inhalationofproductdustcancauseirritationofthenose,throatandrespiratorysystem.

Repeatedexposuretorespirablecrystallinesilicadustmayleadtosilicosis,orotherseriousdelayedlunginjury.Theonsetof silicosisisusuallyslowandlungdamagemayoccurevenwhennosymptomsorsignsofill-healthhaveoccurred.Silicosiscan developtoamoreseriousdegreeevenafterexposurehasceased,andmayalsoleadtootherdiseasesincludingheartdiseaseand scleroderma.Exposurebyinhalationmayaggravatepre-existingupperrespiratoryandlungdisorderssuchasbronchitis, emphysaemaandasthma.

Skin

Skincontactmaycausemechanicalirritationresultinginrednessanditching.

Eye

Productdustscausesseriouseyeirritation.Oneyecontactthisproductwillcausetearing,stinging,blurredvision,andredness.

RespiratorySensitisation

Notexpectedtobearespiratorysensitiser.

SkinSensitisation

Notexpectedtobeaskinsensitiser.

GermCellMutagenicity

Notconsideredtobeamutagenichazard.

Carcinogenicity

Productdustsmaycausecancerbyinhalation.ClassifiedasaKnownorpresumedhumancarcinogen.

Silicadust,crystallineintheformofquartzislistedasaGroup1:CarcinogenictohumansaccordingtoInternationalAgencyfor ResearchonCancer(IARC).

TitaniumdioxideislistedasaGroup2B:PossiblycarcinogenictohumansaccordingtoInternationalAgencyforResearchonCancer (IARC).

AmorphoussilicaandIronoxidearelistedasaGroup3:NotclassifiableastocarcinogenicitytohumansaccordingtoInternational AgencyforResearchonCancer(IARC).

ReproductiveToxicity

Notconsideredtobetoxictoreproduction.

STOT-SingleExposure

Productdustsmaycauserespiratoryirritation.

STOT-RepeatedExposure

Productdustsmaycausedamagetoorgans(lungs)throughprolongedexposureifinhaled.

AspirationHazard

Notexpectedtobeanaspirationhazard.

Section12-EcologicalInformation

Ecotoxicity

Noecologicaldataavailableforthismaterial.

Persistenceanddegradability

Notavailable Mobility Notavailable

BioaccumulativePotential Notavailable

OtherAdverseEffects Notavailable

EnvironmentalProtection

Preventthismaterialenteringwaterways,drainsorsewers.

HazardoustotheOzoneLayer

Thisproductisnotexpectedtodepletetheozonelayer.

Section13-DisposalConsiderations

DisposalConsiderations

Thedisposalofthespilledorwastematerialmustbedoneinaccordancewithapplicablelocalandnationalregulations. Tominimisepersonalexposure,refertoSection8-ExposureControlsandPersonalProtection.

Section14-TransportInformation

TransportInformation

RoadandRailTransport(ADGCode):

NotclassifiedasDangerousGoodsaccordingtotheAustralianCodefortheTransportofDangerousGoodsbyRoadandRail(ADG Code)(7thedition).

MarineTransport(IMO/IMDG):

NotclassifiedasDangerousGoodsbythecriteriaoftheInternationalMaritimeDangerousGoodsCode(IMDGCode)fortransport bysea.

AirTransport(ICAO/IATA):

NotclassifiedasDangerousGoodsbythecriteriaoftheInternationalAirTransportAssociation(IATA)DangerousGoodsRegulations fortransportbyair.

UNNumber

NoneAllocated

ProperShippingName

NoneAllocated

TransportHazardClass

NoneAllocated

SpecialPrecautionsforUser Notavailable

IMDGMarinepollutant

No

TransportinBulk Notavailable

Section15-RegulatoryInformation

RegulatoryInformation

ClassifiedasHazardousaccordingtotheGloballyHarmonisedSystemofClassificationandLabellingofChemicals(GHS)including Work,HealthandSafetyRegulations,Australia.

NotclassifiedasaScheduledPoisonaccordingtotheStandardfortheUniformSchedulingofMedicinesandPoisons(SUSMP). PoisonsSchedule

NotScheduled

MontrealProtocol

Notlisted

StockholmConvention

Notlisted

RotterdamConvention

Notlisted

InternationalConventionforthePreventionofPollutionfromShips(MARPOL) Notavailable

AgriculturalandVeterinaryChemicalsAct1994 Notavailable

BaselConvention

Notavailable

Section16-AnyOtherRelevantInformation

DateofPreparation

SDScreated:October2025

VersionNumber 1.0

LiteratureReferences

PreparationofSafetyDataSheetsforHazardousChemicalsCodeofPractice. StandardfortheUniformSchedulingofMedicinesandPoisons. AustralianCodefortheTransportofDangerousGoodsbyRoad&Rail.

WorkHealthandSafetyRegulations,Schedule10:Prohibitedcarcinogens,restrictedcarcinogensandrestrictedhazardous chemicals.

CodeofPracticeforSupplyDiversionintoIllicitDrugManufacture. NationalCodeofPracticeforChemicalsofSecurityConcern. AgriculturalCompoundsandVeterinaryChemicalsAct. InternationalAgencyforResearchonCancer(IARC)Monographs. MontrealProtocolonSubstancesthatDepletetheOzoneLayer. StockholmConventiononPersistentOrganicPollutants(POPs).

RotterdamConventiononthePriorInformedConsentProcedureforCertainHazardousChemicalsandPesticidesinInternational Trade.

BaselConventionontheControlofTransboundaryMovementsofHazardousWastesandTheirDisposal. InternationalAirTransportAssociation(IATA)DangerousGoodsRegulations. InternationalMaritimeDangerousGoods(IMDG)Code.

Workplaceexposurestandardsforairbornecontaminants.

Adoptedbiologicalexposuredeterminants,AmericanConferenceofIndustrialHygienists(ACGIH). GloballyHarmonisedSystemofClassificationandLabellingofChemicals(7threvisededition). CodeofPractice:ManagingNoiseandPreventingHearingLossatWork.

ENDOFSDS

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