Safety Data Sheet
KERANET polvere
Safety Data Sheet dated: 08/10/2020 - version 3
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Mixture identification:
Trade name: KERANET polvere
Trade code: 900151
CAS number: 5329-14-6
EC number: 226-218-8
Index number: 016-026-00-0
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use: Acidic cleaner for ceramic tiles
Uses advised against: Data not available
1.3. Details of the supplier of the safety data sheet
Company: MAPEI S.p.A. - Via Cafiero, 22 - 20158 Milano
Tel: +39-02-376731
Fax: +39-02-37673.214
Responsable: sicurezza@mapei.it
1.4. Emergency telephone number
Poison Centre - Ospedale di Niguarda - Milan - Tel. +39/02/66101029
MAPEI S.p.A. - Tel. +(39)02376731 - (office hours)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Regulation (EC) n. 1272/2008 (CLP)
Skin Irrit. 2 Causes skin irritation.
Eye Irrit. 2 Causes serious eye irritation.
Aquatic Chronic 3 Harmful to aquatic life with long lasting effects.
Adverse physicochemical, human health and environmental effects: No other hazards
2.2. Label elements
Regulation (EC) n. 1272/2008 (CLP)
Pictograms and Signal Words
Warning
Hazard statements:
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements:
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P501 Dispose of contents/container in accordance with applicable regulations.
Special provisions according to Annex XVII of REACH and subsequent amendments: None
2.3. Other hazards
SECTION 3: Composition/information on ingredients
3.1. Substances N.A.
3.2. Mixtures
Mixture identification: KERANET polvere
Hazardous components within the meaning of the CLP regulation and related classification:
Quantity Name
≥75 - <100 % sulphamidic acid; sulphamic acid
SECTION 4: First aid measures
4.1. Description of first aid measures
In case of skin contact:
Ident. Numb. Classification
CAS:5329-14-6
EC:226-218-8
Index:016-02600-0 Eye Irrit. 2, H319; Skin Irrit. 2, H315; Aquatic Chronic 3, H412
Immediately take off all contaminated clothing.
Areas of the body that have - or are only even suspected of having - come into contact with the product must be rinsed immediately with plenty of running water and possibly with soap.
Wash thoroughly the body (shower or bath).
Remove contaminated clothing immediately and dispose of safely.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist immediately.
Protect uninjured eye.
In case of Ingestion:
Do not induce vomiting, get medical attention showing the SDS and the hazard label. In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
4.2. Most important symptoms and effects, both acute and delayed
Eye irritation
Eye damages
Skin Irritation
Erythema
4.3. Indication of any immediate medical attention and special treatment needed In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Treatment:
(see paragraph 4.1)
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media: Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons: None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
5.3. Advice for firefighters
Use suitable breathing apparatus.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment. Remove persons to safety.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Limit leakages with earth or sand.
Limit leakages with earth or sand.
6.3. Methods and material for containment and cleaning up
Take up mechanically and dispose of according to local/state/federal regulations
Scoop into containers and seal for disposal.
Retain contaminated washing water and dispose it.
6.4. Reference to other sections
See also section 8 and 13
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals in the containers. Contaminated clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
Keep away from food, drink and feed. Incompatible materials:
None in particular.
Instructions as regards storage premises: Adequately ventilated premises.
7.3. Specific end use(s)
Recommendation(s)
None in particular
Industrial sector specific solutions:
None in particular
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Predicted No Effect Concentration (PNEC) values
Component
sulphamidic acid; sulphamic acid
5329-14-6 0.173 mg/kg Freshwater sediments 0.0173 mg/kg Marine water sediments
Derived No Effect Level. (DNEL)
Component CAS-No. Worker Industr y Worker Profess ional Consu mer
sulphamidic acid; sulphamic acid
5329-14-6 10 mg/kg 5 mg/kg
8.2. Exposure controls
Eye protection:
Use close fitting safety goggles, don't use eye lens.
Protection for skin:
Protection for hands:
Suitable materials for safety gloves; EN 374:
Human Oral Long Term, systemic effects
Human Dermal Long Term, systemic effects 5 mg/kg
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Polychloroprene - CR: thickness >=0,5mm; breakthrough time >=480min.
Nitrile rubber - NBR: thickness >=0,35mm; breakthrough time >=480min.
Butyl rubber - IIR: thickness >=0,5mm; breakthrough time >=480min.
Fluorinated rubber - FKM: thickness >=0,4mm; breakthrough time >=480min.
Neoprene gloves are suggested (0,5 mm) not recommended gloves: not waterproof gloves
Respiratory protection:
Personal Protective Equipment should comply with relevant CE standards (as EN 374 for gloves and EN 166 for goggles), correctly maintained and stored. Consult the supplier to check the suitability of equipment against specific chemicals and for user information.
information.
A dust mask (P2) should be worn if above exposure limits (EN 149)
Hygienic and Technical measures
N.A.
Appropriate engineering controls: N.A.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state: Solid
Appearance and colour: Powder white
Odour: Odourless
Odour threshold: N.A.
pH: 1.00
Melting point / freezing point: 190 °C (374 °F)
Initial boiling point and boiling range: N.A.
Flash point: N.A.
Evaporation rate: N.A.
Upper/lower flammability or explosive limits: N.A.
Vapour density: N.A.
Vapour pressure: N.A.
Relative density: N.A.
Solubility in water: soluble
Partition coefficient (n-octanol/water): N.A.
Auto-ignition temperature: N.A.
Decomposition temperature: N.A.
Viscosity: N.A.
Explosive properties: ==
Oxidizing properties: N.A.
Solid/gas flammability: N.A.
9.2. Other information
No additional information
SECTION 10: Stability and reactivity
10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
Stable under normal conditions
10.3. Possibility of hazardous reactions
None.
10.4. Conditions to avoid
Stable under normal conditions.
10.5. Incompatible materials
None in particular.
10.6. Hazardous decomposition products
None.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicological information of the mixture: KERANET polvere a) acute toxicity LD50 Oral Rat > 2000 mg/kg
Toxicological information on main components of the mixture: sulphamidic acid; sulphamic acid a) acute toxicity
LD50 Oral Rat = 2065 mg/kg
LD50 Oral Rat = 1450 mg/kg
If not differently specified, the information required in Regulation (EU)2015/830 listed below must be considered as N.A.
a) acute toxicity
b) skin corrosion/irritation
c) serious eye damage/irritation
d) respiratory or skin sensitisation
e) germ cell mutagenicity
f) carcinogenicity
g) reproductive toxicity
h) STOT-single exposure
Toxicological kinetics, metabolism and distribution information
i) STOT-repeated exposure
j) aspiration hazard
SECTION 12: Ecological information
12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment. Eco-Toxicological Information:
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
List of Eco-Toxicological properties of the product
Component Ecotox Infos
KERANET polvere a) Aquatic acute toxicity : LC50 Fish = 70.3 mg/L 96
List of components with eco-toxicological properties
Component Ident. Numb. Ecotox Infos sulphamidic acid; sulphamic acid CAS: 5329-14-6EINECS: 016-02600-0 - INDEX: 226218-8
a) Aquatic acute toxicity : LC50 Fish = 70.3 mg/L 96
a) Aquatic acute toxicity : EC50 Daphnia > 71 mg/L 24
a) Aquatic acute toxicity : LC50 Fish Pimephales promelas = 14.2 mg/L 96h EPA
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
No PBT/vPvB Ingredients are present
12.6. Other adverse effects
N.A.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
The generation of waste should be avoided or minimized wherever possible. Recover if possible.
A waste code (EWC) according to European List of Waste (LoW) cannot be specified, due to dependence on the usage. Contact and send to an authorized waste disposal service.
Methods of disposal:
Disposal of this product, solutions, packaging and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.
Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor.
Do not dispose of waste into sewers.
Hazardous waste: Yes
Disposal considerations:
Do not allow to enter drains or watercourses.
Dispose of product according to all federal, state and local applicable regulations. If this product is mixed with other wastes, the original waste product code may no longer apply and the appropriate code should be assigned.
08/10/2020
If this product is mixed with other wastes, the original waste product code may no longer apply and the appropriate code should be assigned.
Dispose of containers contaminated by the product in accordance with local or national legal provisions. For further information, contact your local waste authority.
Special precautions:
This material and its container must be disposed of in a safe way. Care should be taken when handling untreated empty containers. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Empty containers or liners may retain some product residues. Do not re-use empty containers.
SECTION 14: Transport information
14.1. UN number
2967
14.2. UN proper shipping name
ADR-Shipping Name: SULPHAMIC ACID
IATA-Technical name: SULPHAMIC ACID
IMDG-Technical name: SULPHAMIC ACID
14.3. Transport hazard class(es)
ADR-Class: 8
IATA-Class: 8
IMDG-Class: 8
14.4. Packing group
ADR-Packing Group: III
IATA-Packing group: III
IMDG-Packing group: III
14.5. Environmental hazards
Marine pollutant: No
Environmental Pollutant: No
14.6. Special precautions for user Road and Rail ( ADR-RID ) :
ADR-Label: 8
ADR-Hazard identification number: NA
ADR-Special Provisions: -
ADR-Transport category (Tunnel restriction code): gal Air ( IATA ) :
IATA-Passenger Aircraft: 860
IATA-Cargo Aircraft: 864
IATA-Label: 8
IATA-Subsidiary hazards: -
IATA-Erg: 8L
IATA-Special Provisioning: A803 Sea ( IMDG ) :
IMDG-Stowage Code: Category A
IMDG-Stowage Note: -
IMDG-Subsidiary hazards: -
IMDG-Special Provisioning: -
IMDG-EMS: F-A, S-B
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code N.A.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture VOC (2004/42/EC) : N.A. g/l
Dir. 98/24/EC (Risks related to chemical agents at work) Dir. 2000/39/EC (Occupational exposure limit values)
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EU) 2015/830
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013
Regulation (EU) n. 2018/669 (ATP
Regulation (EU) n. 2018/669 (ATP 11 CLP)
Regulation (EU) n. 2019/521 (ATP 12 CLP)
Regulation (EU) n. 286/2011 (ATP 2 CLP)
Regulation (EU) n. 618/2012 (ATP 3 CLP)
Regulation (EU) n. 487/2013 (ATP 4 CLP)
Regulation (EU) n. 944/2013 (ATP 5 CLP)
Regulation (EU) n. 605/2014 (ATP 6 CLP)
Regulation (EU) n. 2015/1221 (ATP 7 CLP)
Regulation (EU) n. 2016/918 (ATP 8 CLP)
Regulation (EU) n. 2016/1179 (ATP 9 CLP)
Regulation (EU) n. 2017/776 (ATP 10 CLP)
Regulation (EU) n. 2018/669 (ATP 11 CLP)
Regulation (EU) n. 2018/1480 (ATP 13 CLP)
Provisions related to directive EU 2012/18 (Seveso III):
German Water Hazard Class.
1
N.A.
Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH) and subsequent modifications:
Restrictions related to the product: None
Restrictions related to the substances contained: None
SVHC Substances:
No data available
Produktregisteret Norge: 12591
15.2. Chemical safety assessment
No Chemical Safety Assessment has been carried out for the mixture.
SECTION 16: Other information
Code Description
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H412 Harmful to aquatic life with long lasting effects.
Code Hazard class and hazard category
3.2/2
3.3/2
Skin Irrit. 2
Eye Irrit. 2
Description
Skin irritation, Category 2
Eye irritation, Category 2
4.1/C3 Aquatic Chronic 3 Chronic (long term) aquatic hazard, category 3
Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]:
Classification according to Regulation (EC) Nr. 1272/2008
3.2/2
3.3/2
4.1/C3
Classification procedure
Calculation method
Calculation method
Calculation method
This document was prepared by a competent person who has received appropriate training. Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This SDS cancels and replaces any preceding release.
Legend to abbreviations and acronyms used in the safety data sheet:
ACGIH: American Conference of Governmental Industrial Hygienists
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road. AND: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ATE: Acute Toxicity Estimate
ATEmix: Acute toxicity Estimate (Mixtures)
BCF: Biological Concentration Factor
BCF: Biological Concentration Factor
BEI: Biological Exposure Index
BOD: Biochemical Oxygen Demand
CAS: Chemical Abstracts Service (division of the American Chemical Society).
CAV: Poison Center
CE: European Community
CLP: Classification, Labeling, Packaging.
CMR: Carcinogenic, Mutagenic and Reprotoxic
COD: Chemical Oxygen Demand
COV: Volatile Organic Compound
CSA: Chemical Safety Assessment
CSR: Chemical Safety Report
DMEL: Derived Minimal Effect Level
DNEL: Derived No Effect Level.
DPD: Dangerous Preparations Directive
DSD: Dangerous Substances Directive
EC50: Half Maximal Effective Concentration
ECHA: European Chemicals Agency
EINECS: European Inventory of Existing Commercial Chemical Substances.
ES: Exposure Scenario
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of Chemicals.
IARC: International Agency for Research on Cancer
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).
IC50: half maximal inhibitory concentration
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
IRCCS: Scientific Institute for Research, Hospitalization and Health Care
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
LDLo: Leathal Dose Low
N.A.: Not Applicable
N/A: Not Applicable
N/D: Not defined/ Not available
NA: Not available
NIOSH: National Institute for Occupational Safety and Health
NOAEL: No Observed Adverse Effect Level
OSHA: Occupational Safety and Health Administration.
PBT: Persistent, Bioaccumulative and Toxic
PGK: Packaging Instruction
PNEC: Predicted No Effect Concentration.
PSG: Passengers
RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
vPvB: Very Persistent, Very Bioaccumulative.
WGK: German Water Hazard Class.
Paragraphs modified from the previous revision:
- 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
- 2. HAZARDS IDENTIFICATION
- 4. FIRST AID MEASURES
- 7. HANDLING AND STORAGE
- 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
- 9. PHYSICAL AND CHEMICAL PROPERTIES
- 11. TOXICOLOGICAL INFORMATION
- 12. ECOLOGICAL INFORMATION
- 13. DISPOSAL CONSIDERATIONS
- 14. TRANSPORT