Safety Data Sheet
KERAQUICK MAXI S1
Safety Data Sheet dated: 07/07/2020 - version 4
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Mixture identification:
Trade name: KERAQUICK MAXI S1
Trade code: 9001259
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use: Cement based powder adhesive
Uses advised against: Data not available
1.3. Details of the supplier of the safety data sheet
Company: MAPEI S.p.A. - Via Cafiero, 22 - 20158 Milano
Tel: +39-02-376731
Fax: +39-02-37673.214
Responsable: sicurezza@mapei.it
1.4. Emergency telephone number
Poison Centre - Ospedale di Niguarda - Milan - Tel. +39/02/66101029
MAPEI S.p.A. - Tel. +(39)02376731 - (office hours)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Regulation (EC) n. 1272/2008 (CLP)
Eye Irrit. 2 Causes serious eye irritation.
Skin Sens. 1B May cause an allergic skin reaction.
Adverse physicochemical, human health and environmental effects: No other hazards
2.2. Label elements
Regulation (EC) n. 1272/2008 (CLP)
Pictograms and Signal Words
Warning
Hazard statements:
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
Precautionary statements:
P261 Avoid breathing dust.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents/container in accordance with applicable regulations.
Contains:
Special provisions according to Annex XVII of REACH and subsequent amendments: None
2.3. Other hazards
Portland cement, Cr(VI) < 2 ppm No PBT/vPvB Ingredients are present
Other Hazards: No other hazards
Prolonged exposition and/or intensive inhalation of respirable free crystalline silica (average diameter less than 10 micron in accordance with ACGIH) can cause pulmonary fibrosis commonly referred to as silicosis.
Prolonged exposition and/or intensive inhalation of respirable free crystalline silica (average diameter less than 10 micron in accordance with ACGIH) can cause pulmonary fibrosis commonly referred to as silicosis. This preparation contains cement. Contact between cement and body fluids (e.g. sweat and eye fluids) may cause irritation or burns.
SECTION 3: Composition/information on ingredients
3.1. Substances
N.A.
3.2. Mixtures
Mixture identification: KERAQUICK MAXI S1
Hazardous components within the meaning of the CLP regulation and related classification:
Quantity Name
≥50 - <75 % free crystalline silica (Ø >10 µ)
≥1 - <2.5 % Portland cement, Cr(VI) < 2 ppm
≥0.25<0.49 % free crystalline silica (Ø <10 µ)
SECTION 4: First aid measures
4.1. Description of first aid measures
In case of skin contact:
Ident. Numb. Classification Registration Number
CAS:14808-60-7
EC:238-878-4
CAS:65997-15-1
EC:266-043-4
CAS:14808-60-7
EC:238-878-4
Immediately take off all contaminated clothing.
Skin Irrit. 2, H315; Skin Sens. 1B, H317; Eye Dam. 1, H318; STOT SE 3, H335
STOT RE 1, H372
Areas of the body that have - or are only even suspected of having - come into contact with the product must be rinsed immediately with plenty of running water and possibly with soap.
Wash thoroughly the body (shower or bath).
Remove contaminated clothing immediately and dispose of safely.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist immediately.
Protect uninjured eye.
In case of Ingestion:
Do not induce vomiting, get medical attention showing the SDS and the hazard label. In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
4.2. Most important symptoms and effects, both acute and delayed
Eye irritation
Eye damages
4.3. Indication of any immediate medical attention and special treatment needed
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).
Treatment:
(see paragraph 4.1)
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media: Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons: None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
5.3. Advice for firefighters
Use suitable breathing apparatus.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.
Remove persons to safety.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
6.3. Methods and material for containment and cleaning up
Take up mechanically and dispose of according to local/state/federal regulations
Scoop into containers and seal for disposal.
Retain contaminated washing water and dispose it.
6.4. Reference to other sections
See also section 8 and 13
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists. Don't use empty container before they have been cleaned. Before making transfer operations, assure that there aren't any incompatible material residuals in the containers. Contaminated clothing should be changed before entering eating areas. Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises: Adequately ventilated premises.
7.3. Specific end use(s)
Recommendation(s)
None in particular
Industrial sector specific solutions:
None in particular
SECTION 8: Exposure controls/personal
8.1. Control parameters
List of components with OEL value
protection
5 mg/m3 TWA (containing <1% of free Silica, respirable dust);10 mg/m3 TWA (containing <1% of free Silica, total dust)
A4 - Not Classifiable as a Human Carcinogen;pulmonary function;respiratory symptoms;asthma
5 mg/m3 TWA (containing <1% of free Silica, respirable dust);10 mg/m3 TWA (containing <1% of free Silica, total dust) National
5 mg/m3 TWA (containing <1% of free Silica, respirable dust);10 mg/m3 TWA (containing <1% of free Silica, total dust)
A4 - Not Classifiable as a Human Carcinogen;pulmonary function;respiratory symptoms;asthma
8.2. Exposure controls
Eye protection:
Use close fitting safety goggles, don't use eye lens.
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Protection for hands:
Suitable materials for safety gloves; EN 374:
Polychloroprene - CR: thickness >=0,5mm; breakthrough time >=480min.
Nitrile rubber - NBR: thickness >=0,35mm; breakthrough time >=480min.
Butyl rubber - IIR: thickness >=0,5mm; breakthrough time >=480min.
Fluorinated rubber - FKM: thickness >=0,4mm; breakthrough time >=480min.
Nitrile gloves are suggested (1,3 mm; 480 min). Not recommended gloves: not waterproof gloves
Respiratory protection:
Personal Protective Equipment should comply with relevant CE standards (as EN 374 for gloves and EN 166 for goggles), correctly maintained and stored. Consult the supplier to check the suitability of equipment against specific chemicals and for user information.
A dust mask (P2) should be worn if above exposure limits (EN 149)
Hygienic and Technical measures
N.A.
Appropriate engineering controls: N.A.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state: Solid
Appearance and colour: Powder white/grey
Odour: cement like
Odour threshold: N.A.
pH: N.A.
Melting point / freezing point: N.A.
Initial boiling point and boiling range: N.A.
Flash point: N.A.
Evaporation rate: N.A.
Upper/lower flammability or explosive limits: N.A.
Vapour density: N.A.
Vapour pressure: N.A.
Relative density: N.A.
Apparent density: 1.5
Solubility in water: <5 g/l
Partition coefficient (n-octanol/water): N.A.
Auto-ignition temperature: N.A.
Decomposition temperature: N.A.
Viscosity: N.A.
Explosive properties: ==
Oxidizing properties: N.A.
Solid/gas flammability: N.A.
9.2. Other information
No additional information
SECTION 10: Stability and reactivity
10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
Stable under normal conditions
10.3. Possibility of hazardous reactions
None.
10.4. Conditions to avoid
Stable under normal conditions.
10.5. Incompatible materials
None in particular.
10.6. Hazardous decomposition products
None.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Contains cement. Cement gives a strong alkaline reaction with water and body fluids (e.g. sweat and eye fluids), therefore the contact with skin and eyes should be carefully avoided.
Toxicological information of the mixture:
There is no toxicological data available on the mixture. Consider the individual concentration of each component to assess toxicological effects resulting from exposure to the mixture.
Toxicological information on main components of the mixture:
free crystalline silica (Ø >10 µ)
a) acute toxicity
LD50 Oral > 2000 mg/kg
LD50 Skin > 2000 mg/kg
free crystalline silica (Ø <10 µ) a) acute toxicity
LD50 Oral Rat = 500 mg/kg
If not differently specified, the information required in Regulation (EU)2015/830 listed below must be considered as N.A.
a) acute toxicity
b) skin corrosion/irritation
c) serious eye damage/irritation
d) respiratory or skin sensitisation
e) germ cell mutagenicity
f) carcinogenicity
g) reproductive toxicity
h) STOT-single exposure
Toxicological kinetics, metabolism and distribution information
i) STOT-repeated exposure
j) aspiration hazard
SECTION 12: Ecological information
12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment. Eco-Toxicological Information:
List of Eco-Toxicological properties of the product
No data available
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
N.A.
12.5. Results of PBT and vPvB assessment
No PBT/vPvB Ingredients are present
12.6. Other adverse effects
N.A.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Recover if possible. In so doing, comply with the local and national regulations currently in force. A waste code according to European waste catalogue (EWC) cannot be specified, due to dependence on the usage. Contact an authorized waste disposal service.
Product:
Do not dispose of waste into sewers.
Do not contaminate ponds, waterways or ditches with chemical or used container. Send to an authorized waste disposal service.
Contaminated packaging:
Empty remaining content.
Dispose of as unused product. Do not re-use empty containers.
SECTION 14: Transport information
Not classified as dangerous in the meaning of transport regulations.
14.1. UN number
N.A.
14.2. UN proper shipping name
N.A.
14.3. Transport hazard class(es)
N.A.
14.4. Packing group
N.A.
14.5. Environmental hazards
N.A.
14.6. Special precautions for user
N.A.
Road and Rail ( ADR-RID ) :
N.A.
ADR-Hazard identification number: NA
Air ( IATA ) :
N.A.
Sea ( IMDG ) :
N.A.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
N.A.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture VOC (2004/42/EC) : N.A. g/l
The product contains Cr (VI) under the limits established by annex. XVII pt.47. Respect the duration according to the information described on the packaging.
Dir. 98/24/EC (Risks related to chemical agents at work)
Dir. 2000/39/EC (Occupational exposure limit values)
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EU) 2015/830
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013
Regulation (EU) n. 286/2011 (ATP 2 CLP)
Regulation (EU) n. 618/2012 (ATP 3 CLP)
Regulation (EU) n. 487/2013 (ATP 4 CLP)
Regulation (EU) n. 944/2013 (ATP 5 CLP)
Regulation (EU) n. 605/2014 (ATP 6 CLP)
02/11/2020
Regulation (EU) n. 605/2014 (ATP 6 CLP)
Regulation (EU) n. 2015/1221 (ATP 7 CLP)
Regulation (EU) n. 2016/918 (ATP 8 CLP)
Regulation (EU) n. 2016/1179 (ATP 9 CLP)
Regulation (EU) n. 2017/776 (ATP 10 CLP)
Regulation (EU) n. 2018/669 (ATP 11 CLP)
Regulation (EU) n. 2019/521 (ATP 12 CLP)
Regulation (EU) n. 2018/1480 (ATP 13 CLP)
Provisions related to directive EU 2012/18 (Seveso III):
German Water Hazard Class.
N.A.
Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH) and subsequent modifications:
Restrictions related to the product: None
Restrictions related to the substances contained: None
SVHC Substances:
No data available
MAL-kode: 00-4
15.2. Chemical safety assessment
No Chemical Safety Assessment has been carried out for the mixture.
SECTION 16: Other information
Code Description
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H372 Causes damage to organs through prolonged or repeated exposure.
Code Hazard class and hazard category
3.2/2
Skin Irrit. 2
3.3/1 Eye Dam. 1
3.3/2 Eye Irrit. 2
3.4.2/1B Skin Sens. 1B
3.8/3 STOT SE 3
3.9/1 STOT RE 1
Description
Skin irritation, Category 2
Serious eye damage, Category 1
Eye irritation, Category 2
Skin Sensitisation, Category 1B
Specific target organ toxicity — single exposure, Category 3
Specific target organ toxicity — repeated exposure, Category 1
Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]:
Classification according to Regulation (EC) Nr. 1272/2008
3.3/2
Classification procedure
Calculation method
3.4.2/1B Calculation method
This document was prepared by a competent person who has received appropriate training. Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This SDS cancels and replaces any preceding release.
Legend to abbreviations and acronyms used in the safety data sheet:
ACGIH: American Conference of Governmental Industrial Hygienists
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
AND: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ATE: Acute Toxicity Estimate
ATEmix: Acute toxicity Estimate (Mixtures)
BCF: Biological Concentration Factor
BCF: Biological Concentration Factor
BEI: Biological Exposure Index
BOD: Biochemical Oxygen Demand
CAS: Chemical Abstracts Service (division of the American Chemical Society).
CAV: Poison Center
CE: European Community
CLP: Classification, Labeling, Packaging.
CMR: Carcinogenic, Mutagenic and Reprotoxic
COD: Chemical Oxygen Demand
COV: Volatile Organic Compound
CSA: Chemical Safety Assessment
CSR: Chemical Safety Report
DMEL: Derived Minimal Effect Level
DNEL: Derived No Effect Level.
DPD: Dangerous Preparations Directive
DSD: Dangerous Substances Directive
EC50: Half Maximal Effective Concentration
ECHA: European Chemicals Agency
EINECS: European Inventory of Existing Commercial Chemical Substances.
ES: Exposure Scenario
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of Chemicals.
IARC: International Agency for Research on Cancer
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).
IC50: half maximal inhibitory concentration
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
IRCCS: Scientific Institute for Research, Hospitalization and Health Care
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
LDLo: Leathal Dose Low
N.A.: Not Applicable
N/A: Not Applicable
N/D: Not defined/ Not available
NA: Not available
NIOSH: National Institute for Occupational Safety and Health
NOAEL: No Observed Adverse Effect Level
OSHA: Occupational Safety and Health Administration.
PBT: Persistent, Bioaccumulative and Toxic
PGK: Packaging Instruction
PNEC: Predicted No Effect Concentration.
PSG: Passengers
RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
vPvB: Very Persistent, Very Bioaccumulative.
WGK: German Water Hazard Class.
Paragraphs modified from the previous revision:
- 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
- 2. HAZARDS IDENTIFICATION
- 3. COMPOSITION/INFORMATION ON INGREDIENTS
- 7. HANDLING AND STORAGE
- 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
- 9. PHYSICAL AND CHEMICAL PROPERTIES
- 11. TOXICOLOGICAL INFORMATION
- 12. ECOLOGICAL INFORMATION
- 14. TRANSPORT