Safety Data Sheet
MAPEFLEX PU 45 FT
Safety Data Sheet dated: 11/04/2022 - version 3
Date of first edition: 04/07/2018
1. Identification
GHS Product identifier
Mixture identification:
Trade name: MAPEFLEX PU 45 FT
Trade code: 906PG9990
Recommended use of the chemical and restrictions on use
Recommended use: Polyurethane-based adhesive
Uses advised against: Data not available
Supplier's details
Company: MAPEI AUSTRALIA Pty Ltd 180 Viking Drive Wacol QLD 4076 Australia
T. +61 7 32765000 (Mon-Fri 8am to 4.30pm)
F. +61 7 32765076
Responsible: sales@mapei.com.au
Emergency phone number
Australian Poisons Information Centre 24 Hour Service 13 11 26
Police or Fire Brigade 000
2. Hazard identification
Classification of the Hazardous chemical
Resp. Sens. 1 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Adverse physicochemical, human health and environmental effects: No other hazards
GHS label elements, including precautionary statements
Pictograms and Signal Words
Danger
Hazard statements:
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Precautionary statements:
P261 Avoid breathing mist/vapours/spray.
P285 In case of inadequate ventilation wear respiratory protection.
P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P501 Dispose of contents/container in accordance with applicable regulations.
Other hazards which do not result in a classification
Other Hazards: No other hazards
3. Composition/information on ingredients
Substances no data available
Mixtures
Mixture identification: MAPEFLEX PU 45 FT
Hazardous components within the meaning of the "Australian Work Health and Safety (WHS)" regulation and related classification:
Concentration (% w/w)
≥25 - <50 % Calcium carbonate
≥1 - <2.5 % N,N-dibenzyliden polyoxypropylene diamine
≥0.49 - <1 % 4-isocyanatesulphonyltoluene; tosyl isocyanate
≥0.25 - <0.49 % diphenylmethanediisocyanate isomers and homologues
CAS:471-34-1
EC:207-439-9
CAS:136855-71-5, 524730-13-0
EC:679-523-7
CAS:4083-64-1
EC:223-810-8
Index:615-01200-7
CAS:9016-87-9
EC:618-498-9
Index:615-00500-9
Skin Irrit. 2, H315
Eye Irrit. 2A, H319; STOT SE 3, H335; Skin Irrit. 2, H315; Resp. Sens. 1, H334
Acute Tox. 4, H332; Eye Irrit. 2A, H319; STOT SE 3, H335; Skin Irrit. 2, H315; Resp. Sens. 1, H334; Skin Sens. 1, H317; STOT RE 2, H373; Carc. 2, H351
Exempted
01-2119980050-47-XXXX
≥0.1 - <0.25 % diphenylmethane-4,4'-diisocyanate;
CAS:101-68-8
EC:202-966-0
Index:615-00500-9
≥0.1 - <0.25 % o-(p-isocyanatobenzyl)phenyl isocyanate; diphenylmethane-2,4'diisocyanate
CAS:5873-54-1
EC:227-534-9
Index:615-00500-9
Acute Tox. 4, H332; Eye Irrit. 2A, H319; STOT SE 3, H335; Skin Irrit. 2, H315; Resp. Sens. 1, H334; Skin Sens. 1, H317; STOT RE 2, H373; Carc. 2, H351
Carc. 2, H351; STOT RE 2, H373; Eye Irrit. 2A, H319; STOT SE 3, H335; Skin Irrit. 2, H315; Resp. Sens. 1, H334; Skin Sens. 1, H317; Acute Tox. 4, H332
01-2119457014-47-XXXX
01-2119480143-45-0000
4. First-aid measures
Description of necessary first-aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
Areas of the body that have - or are only even suspected of having - come into contact with the product must be rinsed immediately with plenty of running water and possibly with soap.
Wash thoroughly the body (shower or bath).
Remove contaminated clothing immediately and dispose of safely.
In case of eyes contact:
Wash immediately with water.
In case of Ingestion:
Do not induce vomiting, get medical attention showing the SDS and the hazard label. In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
Symptoms caused by exposure no data available
Medical attention and special treatment
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).
Treatment: (see paragraph 4.1)
5. Fire-fighting measures
Suitable extinguishing media
None in particular. Water.
Carbon dioxide (CO2).
Specific hazards arising from the chemical
Do not inhale explosion and combustion gases. Burning produces heavy smoke.
Hazardous combustion products: no data available
Explosive properties: no data available
Oxidizing properties: no data available
Special protective equipment and precautions for fire-fighters
Use suitable breathing apparatus.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.
Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Limit leakages with earth or sand. Methods and material for containment and cleaning up
Suitable material for taking up: absorbing material, organic, sand
Retain contaminated washing water and dispose it.
7. Handling and storage
Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists. Don't use empty container before they have been cleaned. Before making transfer operations, assure that there aren't any incompatible material residuals in the containers. Contaminated clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment. Conditions for safe storage, including any incompatibilities
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.
8. Exposure controls/personal protection
Control parameters – exposure standards, biological monitoring
List of components with OEL value
diisocyanate;
sensitization (listed under Methylene bisphenyl isocyanate (MDI))
o-(pisocyanatobenzyl)phenyl isocyanate; diphenylmethane-2,4'diisocyanate
Predicted No Effect Concentration (PNEC) values
Component
o-(pisocyanatobenzyl)phenyl isocyanate; diphenylmethane-2,4'diisocyanate
Derived No Effect Level. (DNEL)
Intermittent
diphenylmethane-4,4'diisocyanate;
101-68-8
6.1 mg/kg
6.1 mg/kg
50 mg/kg
0.1 mg/m3
0.1 mg/m3
0.05 mg/m3
0.05 mg/m3
25 mg/kg
0.05 mg/m3
Human Oral Long Term, systemic effects
Human Oral Short Term, systemic effects
Human Dermal Short Term, systemic effects
Human Inhalation Short Term, systemic effects
Human Inhalation Short Term, local effects
Human Inhalation Long Term, systemic effects
Human Inhalation Long Term, local effects
Human Dermal Short Term, systemic effects
Human Inhalation Short Term, systemic effects
Human Oral Short Term, systemic effects
Human Inhalation Short Term, local effects
Human Inhalation Long Term, systemic effects 0.025 mg/m3
Human Inhalation Long Term, local effects
Human Dermal Short Term, local effects
o-(pisocyanatobenzyl)phenyl isocyanate; diphenylmethane-2,4'diisocyanate
5873-54-1 50 mg/kg 25 mg/kg
Appropriate engineering controls no data available
Human Dermal Short Term, systemic effects 0.1 mg/m3 0.05 mg/m3
0.1 mg/m3 0.05 mg/m3
Human Inhalation Short Term, systemic effects
Human Dermal Short Term, local effects
Human Inhalation Short Term, local effects 0.05 mg/m3 0.025 mg/m3
0.05 mg/m3 0.025 mg/m3
20 mg/kg
Human Inhalation Long Term, systemic effects
Human Inhalation Long Term, local effects
Human Oral Short Term, systemic effects
Individual protection measures, such as personal protective equipment (PPE) Eye protection:
Not needed for normal use. Anyway, operate according good working practices. Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton. Protection for hands:
Suitable materials for safety gloves; AS/NZS 2161.10:
Polychloroprene - CR: thickness >=0,5mm; breakthrough time >=480min.
Nitrile rubber - NBR: thickness >=0,35mm; breakthrough time >=480min.
Butyl rubber - IIR: thickness >=0,5mm; breakthrough time >=480min.
Butyl rubber - IIR: thickness >=0,5mm; breakthrough time >=480min.
Fluorinated rubber - FKM: thickness >=0,4mm; breakthrough time >=480min.
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
Respiratory protection:
Respiratory protection must be used where exposure levels exceed workplace exposure limits. Refer to AS/NZS 1715-1716 for information on selection and use of appropriate respiratory protection equipment. Use respiratory protection where ventilation is insufficient or exposure is prolonged.
9. Physical and chemical properties
Physical state Liquid
Color various
Appearance: paste
Odour: Characteristic
Odour threshold: no data available
pH: no data available
Melting point / freezing point: no data available
Initial boiling point and boiling range: no data available
Flash point: no data available
Evaporation rate: no data available
Flammability (Solid, Gas): no data available
Upper/lower flammability or explosive limits: no data available
Vapour pressure: no data available
Vapour density: no data available
Relative density: 1.35 g/cm3
Solubility in water: Insoluble
Solubility in oil: partly soluble
Partition coefficient (n-octanol/water): no data available
Auto-ignition temperature: no data available
Decomposition temperature: no data available
Viscosity: 1,300,000.00 cPs
Specific heat value: no data available
Saturated vapour concentration: no data available
Release of invisible flammable vapours and gases: no data available
Particle size: no data available
Particle size distribution: no data available
Shape and aspect ratio: no data available
Crystallinity: no data available
Dustiness: no data available
Specific surface area: no data available
Degree of aggregation or agglomeration, and dispersibility: no data available
Biodurability or biopersistence: no data available
Surface coating or chemistry: no data available
VOC % (Volatile Organic Compound) : 5.6 (Rule 1168) g/l
10. Stability and reactivity
Reactivity
Stable under normal conditions
Chemical stability no data available
Possibility of hazardous reactions
None.
Conditions to avoid
Stable under normal conditions.
Incompatible materials
None in particular.
Hazardous decomposition products
SECTION 11: Toxicological information
Information on toxicological effects
Toxicological information on main components of the mixture:
Calcium carbonate a) acute toxicity
LD50 Oral Rat > 2000 mg/kg
LC50 Inhalation Rat > 3 mg/l
LD50 Skin Rat > 2000 mg/kg 4h
LD50 Oral Rat = 6450 mg/kg
g) reproductive toxicity NOAEL Rat = 1000 mg/kg
4isocyanatesulphonyltoluen e; tosyl isocyanate
a) acute toxicity
LC50 Inhalation Rat > 640 ppm 1h
LD50 Oral Rat = 2234 mg/kg
diphenylmethanediisocya nate isomers and homologues
a) acute toxicity
LD50 Oral Rat > 10000 mg/kg
LD50 Skin Rabbit > 9400 mg/kg
LC50 Inhalation Dust Rat = 0.31 mg/l 4h
LD50 Skin Rabbit > 9.4 g/kg
LC50 Inhalation Rat = 490 mg/m3 4h
LD50 Oral Rat = 49 g/kg
g) reproductive toxicity NOAEL Inhalation Rat = 12 mg/m3
diphenylmethane-4,4'diisocyanate;
a) acute toxicity
LD50 Oral Rat > 2000 mg/kg
LD50 Skin Rabbit > 9400 mg/kg
b) skin corrosion/irritation Skin Irritant Skin Rabbit Positive
d) respiratory or skin sensitisation Skin Sensitization Skin Mouse Positive
Respiratory Sensitization Inhalation Positive
f) carcinogenicity Carcinogenicity Inhalation Rat = 6.00000 mg/m3 2 y
g) reproductive toxicity NOAEL Inhalation Rat = 12.00000 mg/m3 20 d
o-(pisocyanatobenzyl)phenyl isocyanate; diphenylmethane-2,4'diisocyanate
a) acute toxicity
LD50 Skin Rabbit > 9400 mg/kg
LD50 Oral Rat > 2000 mg/kg
e) germ cell mutagenicity NOAEL Inhalation Rat = 12 mg/m3
12. Ecological information
Ecotoxicity
Adopt good working practices, so that the product is not released into the environment. Eco-Toxicological Information:
List of components with eco-toxicological properties
Component Ident. Numb. Ecotox Infos
Calcium carbonate
CAS: 471-34-1EINECS: 207-439-9
c) Bacteria toxicity : NOEC Bacteria = 1000 mg/L 3
d) Terrestrial toxicity : LC50 > 1000 mg/kg
d) Terrestrial toxicity : NOEC = 1000 mg/kg - 28 d
e) Plant toxicity : NOEC = 1000 mg/kg - 21 d diphenylmethanediisocyanate isomers and homologues
CAS: 9016-87-9EINECS: 618-498-9
- INDEX: 615-00500-9
a) Aquatic acute toxicity : LC50 Fish > 1000 mg/L 96
a) Aquatic acute toxicity : EC50 Daphnia > 1000 mg/L 24
diphenylmethane-4,4'diisocyanate;
CAS: 101-68-8EINECS: 202-966-0
- INDEX: 615-00500-9
b) Aquatic chronic toxicity : NOEC Daphnia > 10 mg/L - 21 d
a) Aquatic acute toxicity : EC50 Algae > 1640 mg/L 72
c) Bacteria toxicity : EC50 > 100 mg/L 3
d) Terrestrial toxicity : NOEC > 1000 mg/kg - 14 d
e) Plant toxicity : NOEC > 1000 mg/kg - 14 d
a) Aquatic acute toxicity : LC50 Fish > 1000 mg/L 96
a) Aquatic acute toxicity : EC50 Daphnia > 1000 mg/L 24
b) Aquatic chronic toxicity : NOEC Daphnia > 10 mg/L - 21 d
a) Aquatic acute toxicity : EC50 Algae > 1640 mg/L 72
c) Bacteria toxicity : EC50 > 100 mg/L 3
d) Terrestrial toxicity : NOEC > 1000 mg/kg - 14 d
e) Plant toxicity : NOEC > 1000 mg/kg - 14 d
o-(p-isocyanatobenzyl)phenyl isocyanate; diphenylmethane-2,4'diisocyanate
CAS: 5873-54-1 -
EINECS: 227-534-9
- INDEX: 615-00500-9
a) Aquatic acute toxicity : LC50 Fish > 1000 mg/L 96
a) Aquatic acute toxicity : EC50 Daphnia > 1000 mg/L 24
b) Aquatic chronic toxicity : NOEC Daphnia > 10 mg/L - 21 d
a) Aquatic acute toxicity : EC50 Algae > 1640 mg/L 72
c) Bacteria toxicity : EC50 > 100 mg/L 3
d) Terrestrial toxicity : NOEC > 1000 mg/kg - 14 d
e) Plant toxicity : NOEC > 1000 mg/kg - 14 d
Persistence and degradability
Bioaccumulative potential
Mobility in soil
no data available no data available no data available
Other adverse effects no data available
13. Disposal considerations
Disposal methods
The generation of waste should be avoided or minimized wherever possible. Recover if possible.
Methods of disposal:
Disposal of this product, solutions, packaging and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.
Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor.
Do not dispose of waste into sewers.
Disposal considerations:
Do not allow to enter drains or watercourses.
Dispose of product according to all federal, state and local applicable regulations. If this product is mixed with other wastes, the original waste product code may no longer apply and the appropriate code should be assigned.
Dispose of containers contaminated by the product in accordance with local or national legal provisions. For further information, contact your local waste authority.
Special precautions:
This material and its container must be disposed of in a safe way. Care should be taken when handling untreated empty containers. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Empty containers or liners may retain some product residues. Do not re-use empty containers.
14. Transport information
Not classified as dangerous in the meaning of transport regulations. UN number
no data available
UN proper shipping name
no data available
Transport hazard class(es) no data available
Packing group, if applicable no data available
Environmental hazards no data available
Special precautions for user no data available
Additional Information no data available
HazChem Code/Emergency Action code no data available
15. Regulatory information
Safety, health and environmental regulations specific for the product in question
This Safety Data Sheet has been prepared according to the Australian Work Health and Safety (WHS) act and the Code of Practice on preparation of safety data sheets for Hazardous Chemicals.
AICS: all components are listed
16. Other information
Code Description
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H351 Suspected of causing cancer.
H373 May cause damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure if inhaled.
This document was prepared by a competent person who has received appropriate training. Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This SDS cancels and replaces any preceding release.
Legend to abbreviations and acronyms used in the safety data sheet:
ACGIH: American Conference of Governmental Industrial Hygienists
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
AND: European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ATE: Acute Toxicity Estimate
ATEmix: Acute toxicity Estimate (Mixtures)
BCF: Biological Concentration Factor
BEI: Biological Exposure Index
BOD: Biochemical Oxygen Demand
CAS: Chemical Abstracts Service (division of the American Chemical Society).
CAV: Poison Center
CE: European Community
CLP: Classification, Labeling, Packaging.
CMR: Carcinogenic, Mutagenic and Reprotoxic
COD: Chemical Oxygen Demand
COV: Volatile Organic Compound
CSA: Chemical Safety Assessment
CSR: Chemical Safety Report
DMEL: Derived Minimal Effect Level
DMEL: Derived Minimal Effect Level
DNEL: Derived No Effect Level.
DPD: Dangerous Preparations Directive
DSD: Dangerous Substances Directive
EC50: Half Maximal Effective Concentration
ECHA: European Chemicals Agency
EINECS: European Inventory of Existing Commercial Chemical Substances.
ES: Exposure Scenario
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of Chemicals.
IARC: International Agency for Research on Cancer
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).
IC50: half maximal inhibitory concentration
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
IRCCS: Scientific Institute for Research, Hospitalization and Health Care
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
LDLo: Leathal Dose Low
N.A.: Not Applicable
N/A: Not Applicable
N/D: Not defined/ Not available
NA: Not available
NIOSH: National Institute for Occupational Safety and Health
NOAEL: No Observed Adverse Effect Level
OSHA: Occupational Safety and Health Administration.
PBT: Persistent, Bioaccumulative and Toxic
PGK: Packaging Instruction
PNEC: Predicted No Effect Concentration.
PSG: Passengers
RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
vPvB: Very Persistent, Very Bioaccumulative.
WGK: German Water Hazard Class. Paragraphs modified from the previous revision:
- 3. COMPOSITION/INFORMATION ON INGREDIENTS
- 9. PHYSICAL AND CHEMICAL PROPERTIES
- 11. TOXICOLOGICAL INFORMATION
- 12. ECOLOGICAL INFORMATION