FULBAT MSDS - Lithium Battery

Page 1


Version 4.0

Lithium Iron Phosphate Battery

According to Regulation (EU) No 2020/878

According to Regulation (EC) No 1272/2008

1.PRODUCT AND COMPANYIDENTIFICATION COMPANY IDENTIFICATION

Product identifier:

ProductForm: Article

Issue date: 14/04/2018

Update date : 15/11/2022

Productname: FLTSeries-Lithium-IronPhosphate(LiFePO4)batteries

Models: FLTK01(24Wh)-FLTX4L/5L/FLTZ5S/6S(25.6Wh)-FLTX7L/FLTZ7S (38.4Wh)-FLT7B/9B(51.2Wh)-FLTX7A/9/12/14/FLTZ10S/12S/14S (64Wh)-FLT12B/14B(76.8Wh)-FLTX20HL(153.6Wh)-FLTX20H (153.6Wh)-FLTX30HL(230.4Wh)

UFIcode: N/A

Relevant identified uses of the substance and uses advised against: Identified uses: Motorcycleandpowersportstarterbattery Uses advised against: Notavailable.

Details of the supplier of the safety data sheet:

Supplier: FULBAT S.a.s

Address: 30RuePasteur 92150 Suresnes France

Telephone: (France)+3318362 4555

Emergencytelephone Number:

CHEMTREC(US,Canada&Mexico) 0086-1-800-424-9300

CHEMTREC(International) 0086-1-703-527-3887

Availableoutsideofficehours? YES NO X

2.HAZARDS IDENTIFICATION

Forthebatterycell,chemicalmaterialsarestoredinahermeticallysealedAluminumlaminatedcase, designedtowithstandtemperaturesandpressuresencounteredduringnormaluse.Asaresult,during normal use, there is no physical danger of ignition or explosion and chemical danger of hazardous materials' leakage. This product meets the definition of an ā€œarticleā€ and is not subject to the hazards normallyassociatedwiththeindividualcomponentswhenusedasintended. However,thisSafetyDataSheet(SDS)containsvaluableinformationcriticaltothesafehandlingand

properuseofthisproduct.ThisSDSshouldberetainedandavailableforemployeesandotherusers ofthisproduct.Alwaysbeawareoftheriskoffire,explosionorburns.Donotshortcircuittheterminals withanyothermetals.Donotdisassembleormodifythebattery.Donotsolderabatterydirectly.Keep awayfromfireoropenflame.

3.COMPOSITION / INFORMATIONON INGREDIENTS

IMPORTANTNOTE:Thebatterycellshouldnotbeopenedorexposedtoheatbecauseexposureto thefollowingingredientscontainedwithincouldbeharmfulundersomecircumstances.

Weight% listed is based on approximate percent of the averageweight of the battery

4.

FIRST-AID MEASURES

Spilled internal cellmaterials

惻Inhalation:

Makethevictimblowhis/hernose,gargle.Seekmedicalattentionifnecessary.

惻Skincontact:

Removecontaminatedclothesandshoesimmediately.Washextraneousmatterorcontactregionwith soapandplentyofwaterimmediately.

惻Eyecontact:

Donotrubone’seyes.Immediatelyflusheyeswithwatercontinuouslyforatleast15minutes. Seekmedicalattentionimmediately.

A battery cell and spilled internal cell materials

惻Ingestion:

Makethevictimvomit.Whenitisimpossibleorthefeelingisnotwellaftervomiting,seek medicalattention.

5.FIRE-FIGHTING MEASURE

惻Suitableextinguishingmedia:Plentyofwater,carbondioxidegas,nitrogengas,chemicalpowder fireextinguishingmediumandfirefoam

惻Specifichazards:Corrosivegasmaybeemittedduringfire.

惻Specificmethodsoffirefighting:Whenthebatteryburnswithothercombustibles

simultaneously,takefireextinguishingmethodwhichcorrespondtothecombustibles.Extinguisha firefromthewindwardasmuchaspossible.

惻Specialprotectiveequipmentforfirefighters:

Respiratoryprotection:Respiratoryequipmentofagascylinderstyleorprotection-against-dustmask.

Handprotection:Protectivegloves

Eyeprotection:GoggleorprotectiveglassesdesignedtoprotectagainstliquidsplashesSkinand bodyprotection:Protectivecloth

6. ACCIDENTALRELEASE MEASURES

Spilledinternalcellmaterials,suchaselectrolyteleakedfromabatterycell,arecarefullydealtwith accordingtothefollowings.

惻Precautionsforhumanbody: Removespilledmaterialswithprotectiveequipment(protectiveglassesandprotectivegloves).Do notinhalethegasasmuchaspossible.Moreover,avoidtouchingasmuchaspossible.

惻Environmentalprecautions:Donotthrowoutintotheenvironment.

惻Methodofcleaningup: Thespilledsolidsareputintoacontainer.Theleakedplaceiswipedoffwithdrycloth.

惻Preventionofsecondaryhazards: Avoidre-scattering.Donotbringthecollectedmaterialsclosetofire.

7. HANDLING ANDSTORAGE

HandlingTechnical measures

Preventionofuserexposure:Notnecessaryundernormaluse. Preventionoffireandexplosion:Notnecessaryundernormaluse. Precautionforsafehandling:Donotdamageorremovetheexternaltube. Specificsafehandlingadvice: Neverthrowoutcellsinafireorexposetohightemperatures.Donotsoakcellsinwaterorseawater. Donotexposetostrongoxidizers.Donotgiveastrongmechanicalshockorfling. Neverdisassemble, modify or deform. Do not connect the positive terminal to the negative terminal with electrically conductive material. In the case of charging, use only dedicated charger or charge according to the conditionsspecifiedbyFULBAT.

惻Storage Technicalmeasures

Storageconditions(suitable,tobeavoid):Avoiddirectsunlight,hightemperature,highhumidity.Store incoolplace(temperature:-20~35degreeC,humidity:45~85%).

Incompatibleproducts:Conductivematerials,water,seawater,strongoxidizersandstrongacids Packingmaterial(recommended,notsuitable):Insulativeandtearproofmaterialsarerecommended.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

惻Controlparameters: Notestablished

惻Appropriateengineeringcontrols

Undernormalconditions(duringdischarge)releaseofingredientsdoesnot occur.ACGIH:AmericanConferenceofGovernmentalIndustrialHygienists,Inc.

TLV-TWA:ThresholdLimitValue-TimeWeightedAverageconcentrationBEI:

BiologicalExposureIndices

惻Personalprotectiveequipment

Respiratoryprotection:Respiratorwithaircylinder,dustmaskHand protection:Protectivegloves

Eyeprotection:Goggleorprotectiveglassesdesignedtoprotectagainstliquidsplashes

Skinandbodyprotection:Workingclotheswithlongsleeveandlongtrousers

9. PHYSICAL AND CHEMICALPROPERTIES

惻Appearance

Physicalstate:Solid

Form:Prismatic

Color:Metalliccolor(withouttube)

Odor:Noodor

惻pH:NA

惻Specifictemperatures/temperaturerangesatwhichchangesinphysicalstateoccur: Thereisnousefulinformationfortheproductasamixture.

惻Flashpoint:NA

惻Explosionproperties:NA

惻Density:NA

惻Solubility,withindicationofthesolvent(s):Insolubleinwater

10. STABILITYAND REACTIVITY

Stability:Stableundernormaluse

惻Hazardousreactionsoccurringunderspecificconditions

・Conditionstoavoid:Heatabove70°orincinerate.Deform,mutilate,crush,disassemble,overcharge,shortcircuit, exposeoveralongperiodtohumidconditions.Donotputitundersunlightandhighhumiditydirectly.

惻Materialstoavoid:Conductivematerials,water,seawater,strongoxidizersandstrongacids.

惻Hazardousdecompositionproducts:Acridorharmfulgasisemittedduringfire.

11. TOXICOLOGICAL INFORMATION

Thereisnoavailabledataontheproductitself.Theinformationoftheinternalcellmaterialsisas follows.

Lithium Iron Phosphate– LiFePO4

Acutetoxicity:Noapplicabledata.

惻Localeffects:Unknown.

惻Sensitization:Thenervoussystemofrespiratoryorgansmaybestimulatedsensitively.

惻Chronictoxicity/Longtermtoxicity:Noapplicabledata.

惻Skincausticity:Althoughitisveryrare,therashoftheskinandallergicerythemamayresult. Aluminum

惻Localeffects:Aluminumitselfhasnotoxicity.Whenitgoesintoawound,dermatitismaybecaused.

惻Chronictoxicity/Longtermtoxicity:Bythelong-terminhalationofcoarseparticulateorfume,it ispossibletocausealungdamage(aluminumlungs).

Graphite

惻Acutetoxicity:Unknown.

惻Localeffects:Whenitgoesintoone’seyes,itstimulatesone’seyes;conjunctivitis,thickening ofcornealepitheliumoredematousinflammationpalpebramaybecaused.

惻Chronictoxicity/Longtermtoxicity:Long-terminhalationmaybecomeacauseofalungdiseaseora trachealdisease.

惻Carcinogenicity:Graphiteisnotrecognizedasacauseofcancerbyresearchorganizationsand naturaltoxicsubstanceresearchorganizationsofcancer.

Copper

Acutetoxicity:60-100mgsizedcoarseparticulatecausesagastrointestinaldisturbancewithnausea andinflammation.TDLo,hypodermic-Rabbit375mg/kg

惻Localeffects:Coarseparticulatestimulatesanoseandatracheal. Whenitgoesintoone’seyes, thesymptomofthereddeningandthepainiscaused.

Sensitization:Sensitizationoftheskinmaybecausedbylong-termorrepetitivecontact.

惻Reproductiveeffects:TDLo,oral-Rat152mg/kg

Organic Electrolyte

惻Acutetoxicity:LD50,oral-Rat2,000mg/kgormore

惻Localeffects:Unknown.

惻Skinirritationstudy:Rabbit–Mild

惻eyeirritationstudy:Rabbit-Verysevere

12. ECOLOGICAL INFORMATION

惻Persistence/degradability:donotburyorthrowoutintotheenvironment.

13. DISPOSAL CONSIDERATIONS

惻Recommendedmethodsforsafeandenvironmentallypreferreddisposal: Product (waste from residues) Donotthrowoutausedbatterycell.Recycleitthroughtherecyclingcompany. Contaminated packaging Neitheracontainernorpackingiscontaminatedduringnormaluse.Wheninternalmaterialsleaked fromabatterycellcontaminates,disposeasindustrialwastessubjecttospecialcontrol.

14. TRANSPORT INFORMATION

SHIPPING BY SEA or BY ROAD (≤100Wh)

14.1UN Number : UN3480

14.2UN Proper shipping name : LITHIUM IONBATTERIES

14.3Transport Hazard class : -

14.4Packing group : -

14.5Environmental hazards :No

14.6ADR, IMDG Transport: SP188

SHIPPING BY SEA or BY ROAD (>100Wh)

14.1 UN Number : UN3480

14.2 UN Proper shipping name : LITHIUM IONBATTERIES

14.3 Transport Hazard class : 9

14.4 Packing group : II

14.5 Environmental hazards :No

14.6 IMDG Transport : P903

SHIPPING BY AIR

14.1UN Number : 3480

14.2UN Proper shipping name : LITHIUM IONBATTERIES

14.3Transport Hazard class : 9

14.4Packing group : II

14.5Environmental hazards :No

14.6IATA Transport : PI965-Section IB(≤100Wh)orPI965-SectionIA(>100Wh)

15. REGULATORYINFORMATION

怊Classification,LabelingandPackagingRegulation怋

怊REACH(EC)1907/2006怋

怊DangerousGoodsRegulation怋

怊RecommendationsonTransportofDangerousGoodsModelRegulations怋

怊InternationalMaritimeDangerousGoods怋

怊TechnicalInstructionsfortheSafeTransportofDangerousGoods怋

怊Classificationandcodeofdangerousgoods怋

怊OccupationalSafetyandHealthAct怋(OSHA)

怊ToxicSubstancesControlAct怋(TSCA)

怊ConsumerProductSafetyAct怋(CPSA)

怊FederalEnvironmentalPollutionControlAct怋(FEPCA)

怊TheOilPollutionAct怋(OPA)

怊ResourceConservationandRecoveryAct怋(RCRA)

怊SafetyDrinkingWaterAct怋(CWA)

怊CodeofFederalRegulations怋(CFR)

InaccordancewithallFederal,Stateandlocallaws

16. OTHER INFORMATION

惻TheinformationcontainedinthisSafetydatasheetisbasedonthepresentstateofknowledgeand currentlegislation.

惻Thissafetydatasheetprovidesguidanceonhealth,safetyandenvironmentalaspectsofthe productandshouldnotbeconstruedasanyguaranteeoftechnicalperformanceorsuitabilityfor particularapplications.

惻Reference

Chemical substances information: Japan Advanced Information center of Safety and Health

InternationalChemicalSafetyCards(ICSCs): InternationalOccupationalSafetyandHealthInformationCentre(CIS)

2002 TLVs and BEIs: American Conference of Governmental Industrial Hygienists (ACGIH) New DangerousGoodsBestPractice008--inthe51stEditionIATADGR(2010)(witheffectfrom01January 2010)

GB/T16483-2008SafetydatasheetforchemicalproductsContentandorderofsectionsISO 11014:2009(E)Safetydatasheetforchemicalproducts–ContentandorderofsectionsIMDG Code–2008Edition:InternationalMaritimeOrganization(IMO)

RTECS(CD-ROM)

MSDSofrawmaterialspreparedbythemanufacturesFirst Edition:Feb.14/04/18

LatestEdition:15/11/2022

PreparedandapprovedbyFULBATS.a.s

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