We have developed a simple, low-cost LED lamp reactor that was used efficiently to investigate the photochemistry
reactivity of nitrosyl complex. It was possible to ratify the proposal for a photoinduced isomerization of nitrito-N (NOO-
) ligand
for nitrito-O (ONO-
) and nitrosyl-N (NO+
) for nitrosyl-O (ON+
), in the cis-[Ru(NO)(NO2)(bpy)2](PF6)2 complex, as well as the
photoresolution of NO in the cis-[Ru(NO)(NO2)(phen)2](PF6)2 complex.