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Cyanotype Variations & Inventions

Herschel's Chrysotype-From the Athenaeum

August 20, 1842...............................................................254

Mike Ware's New Chrysotype Process ....... ................ .. 255

New Chrysotype Sensitizer 255

ChemicalsRequiredfor the Chrysotype Sensitizer ........ 255

Table Setup-Making Chrysotype Sensitizer

Stock A-B-C ..................................................... ........ .......256

Preparing Stock Solution S-Version Chrysotype ............ 257

StockA: Ligand................................................................ 257

Stock B: Gold (B-1) 257

Stock B: Gold (B-2) 257

Stock C: Iron Solution .....................................................258

Table Setupfor Mixing Sensitizer-Version S ................259

Mixing the Chrysotype Sensitizer ...................................259

Component Volumes To Make 10 ml Sensitizer-

Version S 260

Coating 260

Humidity.......................................................................... 261

Exposure .......................................................................... 261

Chemistry Requiredfor Chrysotype Processing .... 261

Developing Agents (One or More ofthe Following) 261

Clearing Agents................................................................ 261

Sink Setup for Ch1ysotype................. . ........................... 261

Processing the Chrysotype . ........ ... ........ .... .. 262

Post-Exposure Hydration (Optional)..............................262

Normal Chrysotype Processing .......................................263

Drying the Print 263 Last Comments 263

tHAtrtlt11

Fumed Silica

Overview & fa.'})ectations......... .......... .. ......... ....... ...264 What Is Fumed Silica? 266

Materials and Application 267

Table Setupfor Fumed Silica/FumedAlumina 267

Fumed Silica Pre-Coating Paper Preparation.................268 Paper................................................................................268

Paper Preparation: Optional Acidification 268

Silica Sizing Solution: Dry Version 268

Dick Sullivan's Fumed Silica Dry Coating Option 268

FollowThese Steps ..........................................................269

Josh Partridge's Wet Coating Option..............................269

How Does Fumed SilicaWork?.......................................270

Applying Sensitizer to the Fumed SilicaCoatedPaper 270

Streaking Issues with Fumed Silica

CHAtrtlt1z

and Fix Alternative for

t.NAtrtlt1:3

for EDTA Clearing Bath: Kitchen Blend 320 Old School 1% HydrochloricAcid Platinum Clearing Bath ..................................................................320

Simple Citric Acid Clearing Bath.....................................320

Hypo Clearing Agent (Sodium Sulphite) Clearing Bath

Convenience Store Emergency Clearing Bath 320 The Sensitizer

Pradip Malde, Test Data, #141, 1983

the Ware-Malde and Ziatype

5% Gold: Color & Contrast Control Swap with LiPd

The Albumen Process

Method #2: The Matte A bumen Process ....

401

The Single-Session Matte Albumen Process 401

Hiibl's Matte Albumen Formula (1896).........................-402

Hiibl's Sensitizer Solution ............................................-402

OnThe Road &Lab Wet Plate Collodion Needs.............425

Additional In-the-Lab Wet Plate Needs .......... -427

Glass And Metal Plate Preparation .. .. .. . 428 Whiting Formula for Glass Cleaning............................-428

Table Setup for Matte Albumen Paper Preparation -402

Matte Albumen Starch Solution: Ingredients................-403

AVery QuickWord Regarding Paper.............................-404

Flattening Albumen Paper .............................................-404

Silver Nitrate Sensitizing Solution for MatteAlbumen ... 404

Alternative Method: Powdered and Liqu d Ready-To-Use

Albun1en . . . . . .. . . A05

Old Albumen is GoodAlbumen -405

The Chloride &Negative Relationship............ ............ .-406

Ammonia Fuming for Contrast ..

..-406

What To Do with the Egg Yolks: Creme Bn'.Hee! ... .... ... .-406

AGreat Recipe forCreme Brlilee ................................. 406

Exposing Traditional and MatteAlbumen A07

Exposure Control 407

What to Look For During Exposure A07

Silver Albumenate/Highlight Yellowing........................ 408

Final Distilled Water Rinse as a Yellowing Preventive ....A09

Color &Exposure: Usingthe Right Negative.................-409

Sink Setup for Albumen Processing

-409

Processing Albumen

....-409

Salt/Citric WashFirst Bath .................................. -409

Albumen Toning 410

Optional Toning Prior to Fixing ..................................... 410

Albumen GoldToner.......................................................410

Salted PaperToners forAlbumen .................................. 410

FixingtheAlbumen Print er Toning

15% Standard Sodium Thiosulphate

All

Fixing Bath: Two-Tray Setup ..........................................All

Se d'or Toner/Fixer Monobath for Albumen . . All

Sel d'or Toner/Fixer Monobath All

Sel d'or Toner/Fixer Formula All

Stock Gold Solution for Sel d'or Toner/Fixer .................All

1% Sodium Sulphite Hypo Clearing Bath

tHAtrtlt1r

Wet Plate Collodion Process: Tintypes, Ambrotypes, & Glass

Plate Negatives

412

Super-Clean Last Step with Bon Ami A29 Prepared BlackMetal Sheets, Cut to Size, with a Film Laminate ......................

Wet Plate Collodion Chemistry ... . .. ....

-429

-429

Collodion: PreparingYour Salted Collodion..................A29

Safety Issue: Flammable Fumes......................................430

Basic CollodionIngredients ...........................................-430

Collodion Ingredients -430

Using AgedCollodion 431

Disposing ofOld or Contaminated Collodion................. 431

Collodion Recipes ..

Bostick & Sullivan PreparedSalted Collodion...............A32

Bostick & Sullivan Working Mixed Collodion Ratios ..

412

Final Wash 412 Fumed Silica

Overview &Expectations

414

A Little History .

416

Wet Plate Irony................................................................ 417

Alabastrine Positive Process from The Silver Sunbeam (1864) ............................................................................... 419

Alabastrine Formula Solution .........................................420

A Little History Continued .............................................. 421

The Wet Plate Collodion Process: Materials

Scully &Osterman Conventional Film Holder Conversion..............

-423

...................................... . .................424

Dry Plate Holder for Wet Plate Process .........................A24

Antique Camera, or Holga, with No Plate Holder ........ 424

Lund Acetal Resin Plate Holder......................................424

Plate Dipperfor Sensitizing and Fixing -425

A Comprehensive Wet Collodion Packing List ...........-425

Bostick & Sullivan Stock Developer for Positives and Negatives 447

Hot Weather Developer: Sugar-Free Recipe 447

Hot Weather Developer: Using Bostick & Sullivan

Stock Developer..............................................................-448

SOS Iron Negative Developer in Hot Weather 448

Sweet & Sour Developer (Vinegar-Sugar Developer) 448

Glass Plate Negatives and Intensification -449

SubbingYour Glass Plate .

........-449

Iodizing the Platefor a Contact Negative.......................-449

TripleYour Exposure

449

A Simple Intensificationwith the Sun 450

A Chemical Intensification When the Plate is Wet -450

Intensification and Workflow

Step #2: Silver Intensification Stage....

450

-450

Iodine/Pyro Redevelopment for Glass Plate Negatves 451

Wet Plate Collodion Fixers -452

Sodium Thiosulphate Fixer.......................

-452

Sodium Thiosulphate Fixerfor Positives: 20% Solution ...452

Sodium Thiosulphate Fixerfor Negatives:

15% Solution 452

Potassium Cyanide Fixer 453

The Good Things About Potassium Cyanide 453

A FewNot So Good Things About Potassium Cyanide 454

Recipe for a 1.2% Potassium Cyanide Fixer···················-454

Using Potassium Cyanide Fixer .....................................-455

Safe Disposal of Potassium Cyanide 455

Neutralizing Potassium Cyanide to a Non-Hazardous

Potassium Cyanate .........................................................455

Neutralizing Waste Water After Using Potassium Cyanide Fixer.......................................

457

Silver Recoveryfrom Neutralized Potassium Cyanide 457

Wet Plate Collodion Workflow ....

457

Coating the Plate with Salted Collodion 457

Sensitizing the Coated Plate in the Salted Silver Bath...-459

What Is Happening in the Silver Tank..........................--460

Watch Out for Legs................................ 460

Loading the Plate Holder or Camera 460

Exposure

461

iPhoneApp Exposure Meter: Pocket Light Meter.......... 461

In-Camera Exposure TestStrip.................

-462 When Exposure is Delayed, or Long, in Camera in HotWeather ................

-463 Plate Development -463

Flooding the Plate with Ferrous Sulphate Developer -463

When to Stop: Re-thinking Development Time .............464

Cold Developer Option at 1:3 ........................................-464

First Wash: Stopping Development -464 Fixing the Plate 465 Washingthe Plate 465 Drying the Plate -466

the Plate

C.#A/"-rtlt1t

The Gum Bichromate Process

The Dusting-OnProcess on Paper .................................566

litAfrtl{,11

Dichromate Process Options:The Gumoil Process, Photo-Resists, Chromatype, Bichromated Wash Drawings, Dusting-On Process, Gum Bichromate on Glass, Herschel's Breath Printing, Estabrook's 3-D Gums,Winther's

Bichro-Silver Process

Stippling the Paint with a Stencil Brush .........................549

Second WaterWash 550

Third Water Wash

Photo-Resists on Metal

A Simple Photo-Resist Formula for Intaglio .................. 551

Acid Etch Formulas: Nitric and Dutch Mordant .

Etching

552

553

A FewWordsAbout Metal Substrates 554

Coating, Exposure, Development, and Re-Exposure ..... 554

Robert Hunt's Chromatype Process (1843) .................... 555

ALittle Chromatype history..............

.........................555

How to Make a Robert Hunt Chromatype (1843) 556

Fixing Option: Talbot's Potassium Bromide Fix 557

Lilac Positives After a Salting Bath ................................. 557

Bichromated Wash Drawing .............

litAfrtl{,2-0

The Carbon Print Process

558

Materials You Will Need..................................................558

Sizing and Steaming ........................................................558

Applying the Pigment .............558

Sensitizing .................. ....................................559

Development.....................................................

The Dusting-On Process

559

559

A Little Dusting-On History............................................559

How Dusting-OnWorks .................................................. 561

Dusting-On for the Deceased .......................................... 561

Dusting-On Process with Ceramic Pigment 561

A Contemporary Dusting-On Process.............................562

Dichromated Gum Formula 562

Dusting-On With a Glass Substrate .........563

Gelatin Coating Option with Separate Glyoxal Bath 564

The Process on GlassContinues 565 The Traditional Dusting-On Formula 566 Materials Neededfor Dusting-On................... 566

Mating the Tissue to the Support 591

Phase 4: Developing the Print 591

Table Setup ...................................................................... 591

The Procedure 591

Toning: Chocolate Brown 592

Comments 592

Carbon on Canvas 593

A.M Marton's Carbon Transfer to Canvas 593

Carbon Positive & Negative Images on Glass .................594

A.M. Marton's Method #1 ...............................................594

Step 1: Insoluble Substratum on Glass ...........................594

Step 2 Preparation ofGlass Following Insoluble

Substratum 595

Sullivan's Method withAminoSilane............................. 595

MakingYour Own CarbonTissue ................................... 595

Mixing the Pigmented Gelatin: What You Need.............596

A: Mixing the Pigmented Gelatin....................................596

B: Hand Coating the Carbon Tissue................................ 597

The Coating Operation 597

Room Conditions 597

Coating with a Heated Rod or Tube 598

C: Drying the Tissue ........................................................599

Troubleshooting 599

C#AtrtltZ..1

TheVan Dyke Brown Process & Variations

Overview & Expectations 600

A Little History................................................................602

Arndt and Troost Brown Print Formula-1889 ..............602

HowVan Dyke Works 602

TheVan Dyke Process 604

Table Setup for Van Dyke 604

Van Dyke Sensitizer . ... ..... ......... .......... .................604

TheVan Dyke Formula....................................................605

Silver Nitrate Advisory ....................................................605

Mixing Sequence fortheVan Dyke Sensitizer ................605

Hypo Clearing Option

Washes....................................................................

theVan Dyke Print.............

Toner ..............................................................

or Palladium Toning Sequence .............................. 616

......................................................................... 616 BlueToner ....................................................................... 616

Blue-Van-Dyke (B-V-D) Process 617

Few Final B-V-D Ideas 618 Galina Manikova's Van Dyke on Porcelain Workflow.... 619 Preparing the Porcelain Form.........................................

C#AtrtltZ..Z..

Paper

Contrast Control for Van Dyke........................................606

The Liam Lawless Contrast Control Sensitizer for Van Dyke 606

Liam's Contrast Control PartA 606

StandardVan Dyke Part B...............................................607

Standard Van Dyke Part C ..............................................607

MixingtheVan Dyke Sensitizer ......................................607

10% Potassium Dichromate Contrast Option.................607

Sun and Shade Contrast Control 608

Table Setup forVan Dyke with Pre-Mixed Sensitizer 608

The Paper 608

Sizing 609

The Negative .609

Sensitizing thePaper 609

Printing-Out 611

Sink Setup for Van Dyke 611

Processing theVan Dyke Print Following Exposure 611

Dechlorination Issue 613

WhatYouAre LookingAtAfter the Wash 613

Fixing Van Dyke 614

A 3% Sodium Thiosulphate Fixer Solution 614

Fixing the Print 614

C#AtrtltZ..:!>

Hand-Applied Emulsions

Black Magic RBM52 Liquid Hardener: A Solution for

Fragile Emulsions............................................................ 641

How to Make a Baryta Solution 641

Silverprint SE-1 Liquid Emulsion 642

Rockland's Liquid Light & Ag-Plus Emulsions 642

Foma Fomaspeed Liquid Emulsion & Hardener............643

The Light Farm LowTech Emulsion #1..........................643

The Light Farm LowTech Emulsion #1: Hershey's

Tornado Emulsion 643

Supplies & ChemistryNeeded 643

Setup for Making the Emulsion ......................................644

Pre-Weighed and Measured Chemicals 644

Chemical Preparation 645

Adding Finals Before Coating 645

The First Coating Pass Will Tell You Two Things 646

Final Emulsion Tips ........................................................646

Exposure Recommendations .......................................... 661

Exposure on Blackened Plates ........................................ 661

Exposure In-Camera for Pinhole Tintypes 662 Exposure Recommendations 662 Contemporary Tintype Processing .................................663

�HAt-rtltZ't

The Working Process....................................................... 647

Paper Preparation ...........................................................647

Working Under Safelight ................................................ 647

Basic Workflow 648

Emulsion on Glass, Ceramic, & Non-Porous Substrates....650

Whiting Formula forGlass Cleaning...............................650

Last Step with Bon Ami 650

Glass Pre-Coating Options 651

Gelatin Coating Option with Separate Glyoxal Bath 651

Printing on Glass .............................................................652

ExposingGlassPlates in the Developer..........................652

Liquid Emulsions on Metal 652

Prepared BlackMetal Sheets, Cut to Size, with a Film Laminate 652

Alternative Metal Preparation for Liquid Emulsions ........................................................................653

Working with Liquid Emulsions on Metal...................... 653

Materials You May Need 654

The Working Process ......................... .....654

In the Lab.........................................................................654

Sweet Cream Emulsion: How toAvoid Bubbles in Coating.........................................................................655

AContemporary Dry Plate Tintype Process .. 655

Metal Plates and AG-Plus................................................656

Humidity andAg-Plus 656

Processing the Plate-Developer 656

Fixer and Wash................................................................656

Trouble ShootingforAg-Plus Tintypes...........................656

TheMetal Plate 657

Anodized Aluminum Sheeting 657

Metal Roofing Substrates 657

BakedCopper Enamel Plates .......................................... 657

Japanned Lacquer Plate Preparation 658

Prepared Aluminum Plates with Protective Laminate ..........................................................................658

Supplies You May Need and Sink Setupfor Contemporary Tintype ....................................................658

Film Positive ....................................................................659

The WorkingProcess for Contemporary Tintype 659

Makingthe Digital Film Positive 659

Chemistry Setup 660

Cleaning and Plate Preparation 661

Coating the Plate with Warm Emulsion 661 Pouring, Drying, and Waiting 24-48 Hours 661

Materials ...694

The Procedure 694

In Daylight ......................................................694

Under Safe Light.. .........................695

D-min D-maxTest: To determine ifyou have made the emulsion correctly 696 Finals 697

Doctors.............................................................................697

Coating Glass Plates with Gelatin Emulsions ................. 697

Equipment and Materials Needed ..................................698

Cutting & Cleaning Glass Plates ......................................698

Heating and Pouring the Emulsion

(under red safe light) 699

Processing Gelatin Emulsion Plates 700

Processing the Negative (under red safe light) ..............700

Troubleshooting .............................................................. 701

Formulae .........................................................................702

Appendix..........................................................................703

Photographic Plate Racks................................................703

Leveling Stands for a Marble ChillingTable............... 703

Materials..........................................................................703

Plate Drying Box 703

Further Reading 703

Sources ofSupply ................................................704

New55 P/NType Film ................................................... .704

New55 FILM ........................ .......................704

Several Simple Alternative Negative Options 707

The Cliche Verre 707

The Paper Negative 708 Projection 708

TheCopyMachine 708

The Desktop Printer 709

Acrylic Lift Transparencies from Printed Sources.......... 710

Basic Materials for Acrylic Lifts ..................................... 710

The Technique .................................................................711

A QuickTip ofthe Hat to In-Camera Films 711

Graphic Arts Films 712

Ilford Ortho Plus 712

Processing Ilford Ortho Plus 712

Arista Ortho Litho 2.0 713

Processing Arista Ortho Litho 2.0 713

Soemarko's LC-1 & LC-1B Low-Contrast Developer

Hollerith's Counter..........................................................728

Vannevar Bush & Engelbart's Mouse .......

The

The Print: Graham Nash, Mac Holbert, & Epson 734

The Art 737

CHAfrtl<..2-' Inkjet Photopolymer Gravure:

Direct To Plate

Overview& Expectations....... . .... .............. .............744

A Little History ................................................................746

The Traditional Photogravure.........................................746

The Premise ..................................................................... 747

A Few

Formulas for Continuous Tone Ortho Lith Film ........... 714

The Standard LC-1 Formula.............................................715

LC-1-B Low-Contrast Formula for Arista Ortho Lith Film for Both Inter-Positive and Negative Production 716

CHAfrtl<..2-Y,Paper andAlternative Substrates: History,

Consideration, Preparation, Sizing, &

Hardening

Fomapan R100-B & W Reversal Film 716

Pyro

CNAfrtl<..ZS

Digital Imagining

717

Overview & Expectations................................................. 718

A Little History ..................................................724

Jacquard's Loom, Vaucanson's Duck, & Engelbart's Mouse.......................................................................... 724

Mr. Babbage Lived on Cabbage....................................... 726

Ada Lovelace and the Analytical Engine......................... 727 BooleanAlgebra .............................728

Arches 88 Silk Screen and Intaglio Paper....................... 765

Somerset Satin................................................................. 765

Lana Royal White/Lana Royal Crown 765

Weston Diploma Parchment Plat-Pal ............................. 765

Rives BFK ........................................................................ 765

Cranes Kid Finish-AS 8111.. ......................... 765

Fabriano Artistico 765

Hahnemiihle-Photo Rag Inkjet Paper 765

Kozo ................................................................................. 765

Gampi-Gampi Torinoko ................................................766

Stonehenge HP 90 lb.......................................................766

Bienfang 360 766

Japanese Tissue 766

When Using Delicate Papers...........................................766

Sizing Paper 767

Shrinking .......... 767

Alternative SizingOptions ..............................................768

Old Dickie's Instant Sizing .............................................768

Arrowroot Sizing..............................................................768

Bernie's RG-4-A Gesso-Gelatin Size ..........769

Gesso-Acrylic Medium Sizing for Porous

Substrates 769

Acrylic Matte Medium &Water ......................................769

Gum Arabic-Dichromate Sizing.....................................769

Gum Arabic-Dichromate Sizing Option #1 769

Gum Arabic-Dichromate Sizing Option #2 770

Sodium Metabisulphite Clearing Bath............................770

Chrome Alum Hardening Option Carbon....................... 770

Ingredients ......................................................................770

Beer, Sodium Silicate, and Corn Starch Hardener for Glass or Ceramics ................................................. 771

Ingredients 771

Perfect Glass CleaningWorkflow.....................................771

Gelatin-Glyoxal Hardening for Glass & Ceramics .........771

Whiting Glass-Cleaning Formula and Workflow 771

Super-Clean Last Step with Bon Ami 772

Amino Silane Surface Preparation .. ......... ... .... 772

Amino Silane Surface Preparation for Emulsions or Sensitizers on Glass .................................................... 772

A-1100 Amino Silane from Bostick & Sullivan 773

Ingredients 773

Laser Transfer On Ceramic: Monika Ozog's

Workflow ................................................... ..................... 774

Table Setup ...................................................................... 774

Laser Transfer on Ceramic Workflow ............................. 774

How To Use Mason Stain 775

A Simple Decal ImageTransferWork:flow on Cer mic.... 775

Galina Manikova's Van Dyke on Porcelain Workflow ... 776

Preparing the Porcelain Form......................................... 776

Hardened Gelatin First Coat ........................................... 776

Applying the Gelatin Van Dyke Sensitizer to Porcelain.......................................................................... 777

& Expectations

Literacy: Revolution, Arts, & Mirrors 782

A!!t«Pl�tS: Appendix -A Chemical Safety

Considerations, Definitions, Information, SmallVolume

Conversions and Formulas

Gum Arabic CAS# 9000-01-5 ........................................ 831

Hydrogen Peroxide (3%) CAS# 7722-84-1 .................... 831

Hydrogen Peroxide (28%-33%) 831

Hydrogen Tetrachloroaurate(III) Trihydrate

CAS# 27988-77-8 ............................................................832

Kodak Hypo Clearing Bath........................ 832

Lead Acetate CAS# 301-04-2 832

Lithium Palladium Chloride/Lithium Chloropalladite ..832

Chemicals & Material Safety Data Sheets (I\·1SDS) ........ 820

A Few Basic Chemistry Definitions. ..... ..... ............ ..... 820

HowChemicals canAffect the Body ... ..... 822

Protecting Yourself: Be Prepared....................................822

Mercuric Chloride CAS# 7487-94-7...............................832

Methyl Alcohol (Wood Spirit) CAS# 67-56-1.................832

MuriaticAcid (Hydrochloric Acid)

CAS # 7647-01-0 ...........................................832

FirstAid . 822

FirstAidfor Ingestion ofAcids and Alkalis .......822

FirstAid for Skin Contact 823

Seek Emergency Medical Assistance If: ..........................823

Poison Control Telephone: 1-800-222-1222 ..................823

Chemist!)' & Safety . . 823

Dichromates: Safetyand Disposal 824

Chemical Abstract Service Registry (CAS) 825

Chemicals 825

Acetic Acid CAS# 64-19-7...............................................825

Alcohol (Everclear) ..........................................................825

Alum (Ammonium Alum, Ammonia Aluminum sulphate) CAS# 7784-26-1 ............................................. 825

Ammonia CAS# 7664-41-7 ..................................825

Ammonium Carbonate CAS # 506-87-6 825

Ammonium Chloride (Sal-Ammoniac)

CAS# 12125-02-9.............................................................826

Ammonium Citrate CAS# 12125-02-9 ...........................826

Ammonium Dichromate (also Bichromate)

CAS# 7789-09-5 ............... ........................826

Ammonium Ferric Oxalate CAS# 14221-47-7... ........826 ..._,

Ammonium Hydroxide (30% Ammonia)

g; CAS#1336-21-6 ............................................................ 8 8 26 6 !:;:)

8

Ammonium Thiocyanate CAS # 1762-95-4 2

Ammonium Thiosulphate (Rapid Fixer)

r:: CAS# 1183-18-8 ...............................................................827

;;;

Borax (Sodium Tetraborate) CAS# 1303-96-4 ...............827

Boric Acid CAS# 10043-35-3 827

Cesium Chloropalladite 827

ChromeAlum (Potassium Sulphate)

CAS# 7778-99-0 827

Citric Acid (2-hydroxypropane) CAS# 77-92-9 ..............827

Collodion USP CAS# 99994-22-6 ..................................828

i Copper Chloride CAS # 10125-13-0 ...............................828

° Copper Nitrate CAS# 10402-29-6..................................828

g Copper Sulphate CAS# 7758-98-7 .................................828

� EDTA Disodium EDTA (Disodium Salt Dihydrate)

25 CAS# 6381-92-6 829

n Tetrasodium EDTA (Tetrasodium Salt Dihydrate)

-c CAS# 10378-23-1 829

5 Ferric Ammonium Citrate CAS# 1185-57-5 829

iii Ferric Citrate CAS # 2338-05-8 829

� Ferric Oxalate (Ferric Ammonium Oxalate)

(;; CAS # 2944-67-4 830

Nitric Acid CAS# 7679-37-2 ...............833

OxalicAcid (Ethanedioic Acid)

CAS# 144-62-7 833

Palladium Chloride CAS# 7647-10-1..............................833

Potassium Bromide CAS# 7758-02-3 ..............833

Potassium Chloroplatinite CAS# 10025-99-7 833

Potassium Cyanide CAS# 151-50-8 834

Potassium Dichromate CAS# 7778-50-9 ................. 834

Potassium Ferricyanide CAS# 13746-66-2 ....................834

Potassium Iodide CAS# 7681-11-0 .................................835

Potassium Metabisulphite CAS# 16731-55-8..................835

Potassium Oxalate CAS# 583-52-8................................835

Potassium SodiumTartrate (Rochelle Salt) CAS# 304-59-6 .......................... 835

CAS# 87-66-1 835 Silver Nitrate CAS# 7161-88-8 .......................................835

Sodium Acetate CAS# 127-09-3 .....................................836

Sodium Bisulphate CAS# 7681-38-1..............................836

Sodium Bisulphite CAS# 7631-90-5 .........836

Sodium Carbonate (Anhydrous) CAS# 497-19-8 836

Sodium Chloride (Kosher Salt) CAS # 7647-14-5 836

Sodium Citrate (Tri-Sodium Citrate) CAS# 68-04-2 836

Sodium Gold Chloride CAS# 13874-02-7 ......................837

Sodium Potassium Tartrate CAS# 304-59-6 .................837

Sodium Metabisulphite (Sodium Pyrosulphite)

CAS # 7681-57-4..............................................................837

Sodium Selenite CAS# 10102-18-8 837

Sodium Sulphite CAS# 7757-83-7 837

Sodium Tetraborate CAS# 1303-96-4............................837

Sodium Tetrachloroaurate(III) Dihydrate

CAS # 13874-02-7............................................................ 837

Sodium Thiosulphate (Hypo/Fixer) CAS# 7772-98-7...837

Sodium Tungstate CAS# 53125-86-3.............................838

Sulphamic Acid CAS# 5329-14-6 ................................838

Tannie Acid CAS# 1401-55-4 838

Tartaric Acid CAS# 87-69-4 838

Thymol (Phenol, 5-methyl-2-[1-methylethyl])

CAS # 89-83-8 .................................................................838

3,3' Thiodipropanoic Acid CAS# 111-17-1 ......................838

Tri-Sodium Phosphate CAS# 7601-54-9........................838

Tween 20 CAS# 9005-64-5............................................839

Vinegar.............................................................................839

ASimpleTestfor Residual Hypo/Fixer..........................839

i Ferrous Sulphate CAS# 7782-63-0 ........................... 830

;:; Formalin/Formaldehyde CAS# 50-00-0 830

° Fumed Silica 830

trj

8 Gallic Acid CAS # 149-91-7 831

..._, Glyoxal CAS# 107-22-2 831

� Gold Chloride CAS# 16903-35-8 831

ASimpleTest for Residual Silver Using

Sodium Sulphide ............ ............................................... 839

Reader Responsibility......................................................839

Small Volume Conversion Table .............. . .................. 839

Appendix -B Selected Bibliography: Alternative Processes

Appendix - F Resources, Workshops & Internet Sites: Chemistry, Paper, Lab Gear, References, and the Book Artist's Web

l«Pt.X

To access the above Online Appendices, please follow the steps below:

1. Open your browser and go to http://www.cengage.brain.com

2. Typethe author, title, or ISBN ofthis book in the Search window. (The ISBN is listed on the back cover.)

3. Click on the book title inthe list ofsearch results.

4. When the book's main page is displayed, click the Access button under the Free Materials tab.

5. Once the Book Companion Site opens, you may download each ofthe Appendices, by clicking on the Appendix name.

This section ofthe book is always in progress. Long after the manuscript and image fileshavebeen sent to thepublisherfor production, people are still commenting and contributing and for the last three editions thesebookshavebeen an evolutionenjoyed by artists and scholars ofthe medium.

I can't imagine successfully completing a project of this magnitude without the generous collaboration, knowledge, and wisdom of my family, friends, fellow artists, and students especially my students. With that in mind I'll happily use this space to express my thanks for the pleasure ofyour company on this journey through the three editions ... each one a very different book and meriting an ever increasing gratitude forthe patience and advice ofmy friends.

To begin, I'll make a deep bow of gratitude to my wonderful core group of proofreaders and fact checkers. They are, by unanimous consensus, the very best in the world with language, science, chemistry, history, and alternative process photography and I am honored to call them friends and to be in

their company. I am ever grateful for their time and for setting me straight when my writing and research needed adjusting and a proverbial kick in the seat of the pants. Thank you, in loose order ... Mike Ware, Keith Carter, Luis Gonzalez Palma, Susan Bright, Lyle Rexer, Alex Timmermans, Dan Estabrook, Richard Cynan Jones, Alan Greene, Roy Flukinger, Sandy King, Monika Ozog, Danielle Ezzo, Lindsay Rogers, Tommy Matthews, Lisa Elmaleh, Sam Hiser, Bob Crowley, Mark Osterman, France Scully Osterman, Denise Ross, Bob Szabo, Niles Lund, Ben Sloat, Michelle Pritzl, Jon Coffer, S. Gayle Stevens, Jody Ake, Gordon Mark, Bob Kiss, Howard Effner, Dick Sullivan, MadelynWillis, DanaSullivan, Mary Dorsey Wanless, Malin Sjoberg, Will Dunniway, Jon Cone, Mike Webb, Wolfgang Moersch, Kelly Wrage, Katie O'Brien, Will Dunniway, Zoe Zimmerman, Galina Manikova, WlodekWitek, and xtine Burrough. I want to give special thanks to my former MFA candidate and current colleague, Amanda King, for line editing every single page of the first draft. My very special thanks to my friend Fionnbharr 6 Suilleabhain for his generosity of time and incredible line-editing skills. Finn managed to edit all 1200 pages of the original manuscript while packing and moving to Mozambique!

Special thanks to two of my favorite MFA graduates, Jessica Somers for her work on the Dick Sullivan's Athenatype, and Cotton Miller for his research and advice on the Inkjet Photopolymer Gravure and Gumoil. My gratitude to Tony Gonzalez for his significant contribution to the details involved in his personal gum bichromate and digital negative production techniques. Also to Richard Cynan Jones for his time vetting the maddening calotype maze. Thanks to Joe Boylefor his great illustrations. Thank you to my friend of over 30 years, Dick Sullivan, for your contributions with the carbon, fumed silica, and Athenatype techniques andforletting me play in your carbon facility in Santa Fe. Thanks to Reid Callanan at the Santa Fe Photography Workshops for providing a great crew and workshop opportunity for so

Christopher James, Writing is Difficult, 2007 (Courtesy of the Artist/Author)

much ofmy student testing. A special thanks to Mark Osterman for the great solo contribution of his dry plate emulsion research in the alternative negative chapter.

Anyonewho has ever created a book, even halfthis size, knows how important it is to have your editor, production team, and publisherbelieving inwhatyou are creating. I was luckywith thefirst and second editions, and am lucky again. Thank you Jim Gish, my editor for all of the books, for your gift of autonomy that was appreciatedeverysingle day it has been a wonderful 12 years and I look forward to working with you again. Thank you to Larry Main, Andrew Crouth, Nicole Calisi, Sandy Clark, Sarah Timm, Meaghan Tomaso, MarisaTaylor, Jennifer Feltri-George, Becky DiCaprio, AnneMajusiak (a superb picture researcher ifyou need one), and Tom Schin whothoughtthis subject was a good idea to invest in a book 12 years ago and for asking all ofthe right questions.

THE BOOK ARTIST'S WEB SITES

AMargaret Adams

Paul Adams

JodyAke

Bina Altera

Christina Z Anderson

DickArentz

B

Jo Babcock

Elena Baca

Christine Baczek

Jonathan Bailey

Craig Barber

Emily Barton

Peter Baryshnikov

Cynthia Batmanis

Matt Belanger

Laura Bennett

Jayne Hinds Bidaut

Diana Bloomfield

Joe Boyle

Thanks aswellgo to RoyFlukinger and Linda Briscoe Meyer at The Ransom Center / U. ofTexas-Austin for their friendship and outstanding help in tracking down images intheircollection. As well, SteveVallario when he was at Pictorico / Mitsubishi Imaging, Kat Kiernan at the Kiernan Gallery, Tess at Houk Gallery, Gagoshian Gallery, Pace-MacGill Gallery, and to all of the museum research assistants who I asked questions ofover the years.

Adeeplyfeltthankyoutoalloftheartists,myfriends, who allowed me to reproduce their excellent work in this book ... your generosity, support, and enthusiasm wereoutstandingandperfect on everylevelimaginable. Have I forgotten anyone? Oh yeah! Most importantly, I thank mywife, Rebecca, forputting upwithme, for her perpetually zany sense ofhumor, love, support, andpositivestateofbeing. Itwas awonderful experience creatingthisbook inthe Dublin, NH studiowithyouand Cypress thankyoualways foreverything.

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Will Dunniway

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Barbara Eberhard

Christine Elfman

Lisa Elmaleh

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Carol Golemboski

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H

James Hajicek

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Quinn Jacobson

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Elizabeth Jameson

Catherine Jansen

Richard Cynan Jones

SandyJohanson

JR

K

Paul Karabanis

Anselm Keifer

Michael Kenna

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Amanda King

Sandy King

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Bob Kiss

Charlene Knowlton

Michael Kolster

Lesley Krane

EV Krebs

http://www.carolgolemboski.com http://www.tonygonzalezartist.com http://www.bryandavidgriffith.com

http://www.alchemy-studio.net http://www.annhamiltonstudio.com http://www.brentonhamiltonstudio.net http://www.cigharvey.com http://www.kristenhatgi.com http://www.tomhawkinsphotographs.com http://www.danherrerastudio.com http://www.davidhilliard.com http://www.cameraabsurda.blogspot.com http://www.travishocutt.com http://www.aspenhochhalter.net/home.html http://www.triciahoffman.com http://www.gracehuang.com

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http://www.paulkarabinis.com http://www.gagosian.com/artists/anselm-kiefer http://www.michaelkenna.net http://www davidmichaelkennedy.com http://www angelinakidd.com http://www.amandabking.com http://www.sandykingphotography.com http://www.hands-on-pictures.com

http://www.bobkiss.com

http://www.cvknowlton.com

http://www.michaelkolster.com http://www.lesleykrane.com https://www.flickr.com/photos/evkphotography/

William Larson

Jonathan Laurence

Rosemary LeBeau

Liz Lee

Tasha Lewis

Peter Liepke

Peter Lindstrom

Carmen Lizardo

Steven Livick

Cary Loving

Niles Lund

Deb Luster

M

Martha Madigan

Ronnie Maher

Pradip Malde

Galina Manikova

Sally Mann

Nancy Marshall

Tommy Matthews

Scott McMahon

Cotton Miller

Daniel Baird Miller

Wolfgang Moersch

Beth Moon

PhillipeMoroux

Colleen Mullins

N

Sarah Nesbitt

Bea Nettles

0

Elizabeth Opalenik

Mark Osterman

France ScullyOsterman

p

Brian Palm

Luis Gonzalez Palma

TomPersinger

Olivia Parker

Doug Prince

http://william-larson.com

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http://www.tashalewis.info/aboutwork.html

http://www.peterliepke.com

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http://www.gonzalezpalma.com

http://www.tompersinger.com

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http://www.douglasprince.com

Michelle Pritzl

Christina Pumo

David Puntel

R

Molly Rapp

Eric Renner

Holly Roberts

Michele Robins

Mike Robinson

Lindsay Rogers

Ernestine Ruben

Marilyn Ruseckas

Natalie Rzucidlo

s

Francis Schanberger

W.H Shilling

Mark Sink

Malin Sjoberg

Ben Sloat

Carol Panero Smith

Laurie Snyder

Leah Sobsey

Jess Somers

LucySoutter

Jerry Spagnoli

Carol Panaro-Smith

Nancy Spencer

KeliyAnderson-Staley

Rachel Brace Stille

Linda Sterner

Joni Sternbach

Jane Alden Stevens

S. Gayle Stevens

Craig Stevens

Jerome Sturm

Dick Sullivan

Bob Szabo

TDonna Hamil Talman

KeithTaylor

Alex Timmermans

V. Elizabeth Turk

http://www.michellerogerspritzl.com

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http://www.keithtaylorphoto.com/website

http://www.collodion-art.blogspot.com

http://www.velizabethturk.com

Jerry Uelsmann

v

RogerVail

SarahVan Keuren

Alan Vlach

w

Sam Wang

Mary Dorsey Wanless

Mike Ware

Chris Weyant

BradyWilks

ShoshannahWhite

Lisa Wiltse

Kelly Wrage

z

Patty Kennedy Zafred

Zoe Zimmerman

DUBLIN STU DIO WORK SHOPS

Web Site: www.christopherjames-studio.com

http://www.uelsmann.net

http://www.rogervail com

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http://www.zoezimmerman.com

Web Site email: christopher@christopherjames-studio.com

Studio email: dublinstudio@earthlink.net

If you are seeking a personal and customized workshop experience, where you decide on the number of days you would like, the type ofprocess, or processes, that you wish to work with, and the specific scope ofwhat you would personallylike to learn while working with me, (without the crowding that comes with a larger workshop experience), consider exploring this opportunity by taking a customized and private 1 to 3 person workshop with me in my Dublin, NH studio. Dublinis in the southwest corner ofthe state, near NewYork, Massachusetts, and Vermont, and has been an artist's colony and summer destination for travelers for well over a century. Located near The MacDowell Colony, Dublin features a perfect New England environment, great hiking on Mt. Monadnock, a deep-water swimming lake, and outstanding diversity in dining and local B & B and motel lodging. Manchester International Airport is 45 minutes away and Boston is an hour and 40 minutes by car.

ThinkingWhileWriting:March2014

Six months ago, mywife, Rebecca, sent me an email (which was odd considering she was laying next to me in bed) after reading a new reader's Amazon review for the 2nd edition of my book The generous reviewer had written, "... James' book revives the discussion about "Imperfection" andits artistic merit. Every alternative print is unique and oftenimperfect. FortheancientGreeks, perfectionwas aprimerequisiteforhigh art andbeauty,andthis concept wasrevivedduringthe Renaissance in art andin architecture. The question iswhether artists today"want"toachieve perfection.Theverybeautyofalternative processes isitsimperfectionandunpredictability, andthereinliesthebeauty ofsuch images.Andeachimage isuniqueand irreproducible. Thereis alsothegreatappealofahaptic (referringtothe sense oftouch) approachthatis missing indigitalphotographyandinso manyotherhightechnologyfields."

Rebecca, who is inclinedtosee all things withintheir relationshipstothe naturalworld, wrote, "The beautyof alternative process IS the imperfection ofthese images and our desire for ittodaystems fromtheculturalerosion ofour connections to nature."

This example of a dialogue, in which a discussion of syntax instigates a philosophical conversation about important things that are lost, or missing, is ofhuge interest to me and especially true when considering the hand-made alternativephotographic image and our emotional connections to the unique and imperfectbeautyof those processes andtheirartifacts.

Sixmonths afterRebecca'sbedtime email, Iwas doing some researchoncriticalthinkerswhohadbeen engaged with the brand new medium ofphotography during the mid 1800s. I spent a few hours considering their unique experienceswiththis amazing invention as theywere not only seeing the first images from the new medium, they were having dinner withthe people who were makingthem. I began to make some notes onwhat I had been reading and thinking ... and as I wrote, working on the laptop in my Dublin, NH studio at the end ofsummer, this exposition began to take shape and turned into this piece that I am offeringtoyou now.

The more perfectlyyou render an imperfect thing, the more inevitable the imperfections ofthat thing must be acknowledged. Inthecaseofphotography, wheretheprimaryintentionwas to reflecttheperfection ofnature, itis a feeble endeavor. One ofthe big questions on the table inthe mid-18oos, being discussed by athletic and agile intellectssuchas LadyElizabeth Eastlake, SirWilliamNewton, andPeter HenryEmerson, waswhetherthe imperfections ofphotographywere actuallycloserto our aestheticfeelings for artbecausethe imperfections represented ourpersonalexperienceswith nature,ratherthannature itself in a manner similartorepresentational painting.

In 1857, Lady Elizabeth Eastlake surmised that beyond mere light and appearance, which are the perfect scientific abilities of the medium, are found the beautiful conditions of photography that reflect the viewer's imagination and personal life references. From this vantage, when greater precision and detail are addedto the image (she used the word superadded) the eyewill miss the personal truths that function as thevisual connective and emotional tissue between theviewer and the work

SirWilliam Newton created a great scandal within the Royal Photographic Society by uttering aloud his personal opinionthatpicturestaken slightlyout offocus,withuncertainand ill-defined forms, were more artistically beautiful than perfect still life reflections in the manner ofa 17th century Dutch painting; those lovely and warm renderings of dead game, hanging root vegetables, and bowls of fruit of what was on the tables owned by the painter or painter's patron atthe time.

Newton essentially offered the conflicting proposition that the worse photography performed its assigned job, the more successful it was at representing the ideals of art. Newton's hypothesis, along the lines of

Emerson's great torment over whether photography could be enjoyed as an art or a science, created one ofthe first photo-critical firestorms. Sir Newton's argument was met with alazy response that the possibility ofcapital "A" Art inthe midstofallthis perfect science was heresy. Asimple example ofhowto see this conflictis to compare a reproductionofasaint named St. Matthewon a museum greetingcardrackto oneonaplasterpanel paintedinfull-blown mysterybyCaravaggio. Emersoninsistedthatphotographyrankedasthelowestofalltheartsbecausetheindividualityofthe artist had no room within the science to showitself. Hewas wrongofcourse. When the contextual mystery is missing, so toois the human experience and its connectiontolife ... which is always a mystery.

IfI may, thereisanequivalentreferenceinthemammothcolorphotographicprintsthataresocurrentlyinvogue ingraduate schools, museums, and "cutting-edge" galleries. These humungous images strip the human experience away and amplifythe premise that photographic science and reproduction technologyis capable ofenhancing and shockingyouraestheticexperiencebyshowingyou a pimple as large as a manholecover ... big deal.

Let'sbegin ...

From its inception, photography has never been a single, identifiable, technology or process. Throughout its evolution, the medium has been a slowly moving glacier ofchange, adaptation, and obsolescence followed closely by another metaphorical glacier influenced by the heat of science, industry, technology, aesthetics, and cultural. I think of these separate entities as I do the boulders I find in the woods near my studio evidence of the glacier's melting. Each of these transformations, the great majority of them overlapping, has ushered in an ever-greater democratization of photographic image making and resulting public adoption and adaptation. Each of these cycles have had the same family name regardless ofhow odd the offspring appeared and they have always shared the genus, in a philosophical sense, a class ofthings that share common characteristics, and DNAof photography... thatofmaking marks withlight.

In 1829, inaletterto NicephoreNiepce,LouisDaguerrewrotethewellknownsentimentthathewas burning with desire to seeNiepce'sexperimentsfromnature. Notagreatdealhas changedsincethatsentimentwasexpressedexcept forthe wayin whichthe desire to make and look at photographs is satiated. In the midst ofour current photographic and digital revolution there is the unlimited potential ofintegrating it all under the proverbial big-tent of alternative photographicpractice andpossiblymaking this the mostexcitingtime in the photographicarts in over acentury.

Photography was set free from the yoke of representation several decades ago. It is unnecessary, and ultimately counter-productive, for an artist using the language of photography to be required to choose one style of image making over another. The most constructive strategy is to take the parts that work for you, from every discipline that interests you, and to incorporate them into your photographic vision and workflow. I love that I can make pictures on my iPhone and send them to you. I feel very differently about my wet collodion ferrotypes and ambrotypes. Mypersonal investment in learning to make them gracefullywas quite different. As a result, the investment oftime bestows a greater value andmeaning upon them for me.

When I make awetcollodion plate, I makeit forever. When I make a picture with myiPhone, I makeitforthe moment. Philosophically, it is the difference between making your Eggplant Parmesan with a hand-made sauce that has been simmering for 24 hours and buying you a frozen version ofthe same meal that I'll heat in a microwave oven. They are both Eggplant Parmesan, but they are both not Eggplant Parmesan. One youwilltalk about each time you visit, the other youwill easily forget.

The invention ofphotography, and its ultimate mass democraticization, as represented in the inexpensive and easily procured tintype and ambrotype, changed the role ofthe painter in society. For the first time, it was not a requirement to bewealthyor powerful, as an individual or institution, to commission a painter to depict a likeness ofoneself ... or of one's theologyor position. Facedwith this reality, painters were excused from the obligation of representingthewaya subjectactuallylooked andwere compelledto explore theway it felt, whatthesubjectmight represent metaphorically,howtheartist'sperspectives couldbediscussedconceptuallyandfigurativelyratherthan objectively, in harmonywiththe unique impressions thatthe artist expressed with her paint.

Where a photograph's task once was to relentlessly recreate perfection, often more perfect thanthe human eye could ever hope to experience, with the exception ofthe accidental artifact, it lacked the elementofgesture that a painter, facedwiththe task ofpleasing the vanityofothers, could inject in a representational painting. My grandfather, Alexander James, a gifted painter and studio partner of John Singer Sargent, used to solve the problem when painting pot-boiler (because theykept the soup-pot full) portraits of admirals, andwealthypatrons, with a bold stroke ofred or green as a highlight on an ear, edge ofa nose, or on the arch ofan eyebrow his personal tip ofthe hatto the artistwithin.

This simplicity ofgesture, so prevalent inthe earliest days ofthe medium, became an identifiable strength that was associated with the adventure that reflected the beginning of photography. This would continue into the early 1900s inthehands ofphotographic artists using commerciallyproducedflexiblefilm andsilvergelatin paper. Often, theemotionalreflectionofthatspontaneitywastheresultofamovementunfrozen, orchemical aberration,fortuitous accident, or post-print manipulation ... enchantingqualities found in most hand-made alternativeprocesswork.

From this perspective, as digital imaging absorbs the roles ofphotography and adopts the attributes and qualities of photographic representation, is it possible to tell the difference between the original analog and the new digital? Wasn't thatthe point? Is photography nowfreeto become, as painting did, something entirelynew?

I believe it is.

In 1859, Charles Baudelairewrote, "Ifphotographyis allowedtosupplement art insomeofitsfunctions,itwill soon have supplanted or corrupted it altogether." I wonder ifhe ever consideredthe implications ofbeingwrong? And whatwould he think about the state ofthe mediumtoday?

I am inclined to believe, especially in an academic sense, that photography may no longer need to insist that it be curated and studied as an exclusive medium. It's entirelypossible that its greatest opportunity lies in being integratedwith, andlayering itsinfluences upon, all ofthearts... and notbeingsubjecttothevisual theologiesthat fracture the discipline into "schools" ofdisciples who think and see what is often simply nothing more than a new set ofparty clothesforthe Emperor.

Regardless, many are still in a defensive crouch about "their" medium and concerned with many of the same issuesthatpermeatedthrough the salons ofthemid-late 1800s andthe Photo Secessionists ... where criticaljudgmentwasevaluatedbytheexpectedperfectionofprocessandnotbyitsartisticexpressionorthebeautifulconditions ofimperfection thatrevealthe artist's, andtheviewer's, personallife references andimagination.

To me, photography is unquestionably evolving into a medium that will soon require a new definition. From an alternativeprocess perspective, one that I believe is the spear tip inthis newadventure,theflexibility of these processes present a perfect marriage partner to almost all ofthe arts that are willing to see what will happen iftheytakethe proverbial plunge. To the upcoming generations ofphotographic artists, schooledwith the pixilated imagery and battery-dependent tools of digital imaging, using one's hands to make an image is a persuasive argument simply because it is almost always imperfect ... and as a result, a profound and precise reflection ofus all.

AbouttheThirdEdition

Ifyou take a momentto considerthethings thatyoudobest, youwill come to the reasonable conclusion thatyour unique talents are ones that you taughtyourself. This is thetruth ofhowthe animal kingdom learns ... it is called play. It is play that has guided my teaching. It is play that delights the mind and propels the process ofteaching yourselfjustfor thejoy ofit. Andthatjoy is the philosophy ofthis book.

This thirdedition ofThe Book ofAlternative Photographic Processes represents a significant part ofmy evolution as anartistandauthor ... andas a teacherand mentor ofartists. Forthe lastfourdecades I've been modifying, editing, andaddingto, thisbodyofaltprocessknowledgeandlongbeforethepublicationofthefirstedition,in2001,

most ofthe ideas in this book were photocopied and handed out to my students as working notes. One day, as I was waiting for my next seminar to begin, Tom Schin, from Delmar Thompson, unexpectedly dropped in to my office at The Art Institute of Boston, introduced himself, and asked me if I thought I had a book in those notes. I said, "yes, I did" which validated one ofthe prime tenets of my teaching ... that you had better be ready when you get lucky.

The writing has a greatly expanded historical and personal narrative now and aside from the hundreds of reproductions and illustrations, the three editions represent what "we" have learned together; pertinent and peculiar observations, techniques, anecdotes, and a solid dose of interesting, and often irreverent, history to give perspective on where it all came from.

There are also a lot historical rumors, to enhance the connections between the processes and the people that were "burning with desire" about them. The writing represents the philosophy of how I teach alternative processes, always encouraging my students to be confident in their craft but never at the expense of their inspiration or ideas. I encourage perfect imperfection and playing with ideas about how photography can be integrated with all forms of visual expression and communication. To paraphrase Mark Twain ... it hardly matters when your technique is great if your imagination is out of focus.

As always, I've organized this book to equally meet the needs of several different audiences. For teachers, the book is designed to be flexible and compatible with individual teaching styles. I have done my best to make the contents interesting, clear, and accessible to high school and college-age students, as well as professional artists. As well, a significant percentage of the illustrations in this book were created by students and their teachers, and the images are easily integrated with historical archetypes This comparative collection "sets the bar" and demystifies the critical and historical judgments of what is good, and what is not so good.

For the student, this edition is designed to be fun and to work as a comprehensive, inspirational and technical resource, addressing historical and interdisciplinary connections from the beginnings of photography to its present. The word "student" applies to all ofus and encourages the embrace ofserendipity and accident as a way to avoid the cliche. Far too often, alternative process work is all about someone's ability to get a decent print instead of showing that the process has been used to illuminate a great and creative concept. It is my intention, through the illustrations, to celebrate the art instead ofthe surface.

This third edition is a resource for photographers and artists of all abilities, in any medium, where marking with light is in play. It is increasingly clear that nearly all graphic disciplines, and media, can be accommodated by the integration of alternative processes. In essence, much ofthe book documents the marriage of 19th and 20th century handcraft, science, and romanticism, with 21st-century technologies and critical theory.

New to this edition a major re-write ofthe last two editions, with significantly extended chapters packed with new imagery and information, condensed chapters that mirror changes in the genre, and many more interesting historical characters and stories to make the learning real. I've made every effort to avoid a "this is the onlyway it can be done" pedagogical model and I've written thetext asthoughyou were working right nextto me andwe are in the midst ofa conversation. Ifyou are old enough, we are having our second beer and laughing about how much fun this is.

Thefirst thing I tell my students when I meetthem for a class, seminar, or workshop is, "Ilove this shit." The next time we meet, it is what they tell me! Success in alternative processes blossoms from a willingness to enjoy image making for the pleasure of the process rather than the product. We play. We learn to hunger for the accidental and consider quirky outcomes as opportunities for greater self-expression! Much ofwhat the reader discovers will emerge as a result ofplay and ifyou don't embrace the concept ofplay you probablywon't learn a lot about anything in life Enjoy!

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