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SOLUTION MANUAL FOR CHEMISTRY THE MOLECULAR NATURE OF MATTER AND CHANGE 3CE MARTIN SILBERBERG, PATRICIA AMATEIS, RASHMI VENKATESWARAN, LYDIA CHEN.

Solution Manual For Chemistry The Molecular Nature of Matter and Change 3CE Martin Silberberg, Patricia Amateis, Rashmi Venkateswaran, Lydia Chen Chapter 1-25

CHAPTER 1 KEYS TO THE STUDY OF CHEMISTRY END–OF–CHAPTER PROBLEMS 1.1

Plan: If only the form of the particles has changed and not the composition of the particles, a physical change has taken place; if particles of a different composition result, a chemical change has taken place. Solution: a) The result in C represents a chemical change as the substances in A (red spheres) and B (blue spheres) have reacted to become a different substance (particles consisting of one red and one blue sphere) represented in C. There are molecules in C composed of the atoms from A and B. b) The result in D represents a chemical change as again the atoms in A and B have reacted to form molecules of a new substance. c) The change from C to D is a physical change. The substance is the same in both C and D (molecules consisting of one red sphere and one blue sphere) but is in the gas phase in C and in the liquid phase in D. d) The sample has the same chemical properties in both C and D since it is the same substance but has different physical properties.

1.2

Plan: Apply the definitions of the states of matter to a container. Next, apply these definitions to the examples. Gas molecules fill the entire container; the volume of a gas is the volume of the container. Solids and liquids have a definite volume. The volume of the container does not affect the volume of a solid or liquid. Solution: a) The helium fills the volume of the entire balloon. The addition or removal of helium will change the volume of a balloon. Helium is a gas. b) At room temperature, the mercury does not completely fill the thermometer. The surface of the liquid mercury indicates the temperature. c) The soup completely fills the bottom of the bowl, and it has a definite surface. The soup is a liquid, though it is possible that solid particles of food will be present.

1.3

Plan: Apply the definitions of the states of matter to a container. Next, apply these definitions to the examples. Gas molecules fill the entire container; the volume of a gas is the volume of the container. Solids and liquids have a definite volume. The volume of the container does not affect the volume of a solid or liquid. Solution: a) The air fills the volume of the room. Air is a gas. b) The vitamin tablets do not necessarily fill the entire bottle. The volume of the tablets is determined by the number of tablets in the bottle, not by the volume of the bottle. The tablets are solid. c) The sugar has a definite volume determined by the amount of sugar, not by the volume of the container. The sugar is a solid.

1.4

Plan: Define the terms and apply these definitions to the examples. Solution: Physical property – A characteristic shown by a substance itself, without interacting with or changing into other substances. Chemical property – A characteristic of a substance that appears as it interacts with, or transforms into, other substances. a) The change in color (yellow–green and silvery to white), and the change in physical state (gas and metal to crystals) are examples of physical properties. The change in the physical properties indicates that a chemical change occurred. Thus, the interaction between chlorine gas and sodium metal producing sodium chloride is an example of a chemical property.

b) The sand and the iron are still present. Neither sand nor iron became something else. Colors along with magnetism are physical properties. No chemical changes took place, so there are no chemical properties to observe. 1.5

Plan: Define the terms and apply these definitions to the examples. Solution: Physical change – A change in which the physical form (or state) of a substance, but not its composition, is altered. Chemical change – A change in which a substance is converted into a different substance with different composition and properties. a) The changes in the physical form are physical changes. The physical changes indicate that there is also a chemical change. Magnesium chloride has been converted to magnesium and chlorine. b) The changes in color and form are physical changes. The physical changes indicate that there is also a chemical change. Iron has been converted to a different substance, rust.

1.6

Plan: Apply the definitions of chemical and physical changes to the examples. Solution: a) Not a chemical change, but a physical change — simply cooling returns the soup to its original form. b) There is a chemical change — cooling the toast will not ―un–toast‖ the bread. c) Even though the wood is now in smaller pieces, it is still wood. There has been no change in composition, thus this is a physical change, and not a chemical change. d) This is a chemical change converting the wood (and air) into different substances with different compositions. The wood cannot be ―unburned.‖

1.7

Plan: If there is a physical change, in which the composition of the substance has not been altered, the process can be reversed by a change in temperature. If there is a chemical change, in which the composition of the substance has been altered, the process cannot be reversed by changing the temperature. Solution: a) and c) can be reversed with temperature; the dew can evaporate and the ice cream can be refrozen. b) and d) involve chemical changes and cannot be reversed by changing the temperature since a chemical change has taken place.

1.8

Plan: A system has a higher potential energy before the energy is released (used). Solution: a) The exhaust is lower in energy than the fuel by an amount of energy equal to that released as the fuel burns. The fuel has a higher potential energy. b) Wood, like the fuel, is higher in energy by the amount released as the wood burns.

1.9

Plan: Kinetic energy is energy due to the motion of an object. Solution: a) The sled sliding down the hill has higher kinetic energy than the unmoving sled. b) The water falling over the dam (moving) has more kinetic energy than the water held by the dam.

1.10

Alchemical: chemical methods – distillation, extraction; chemical apparatus Medical: mineral drugs Technological: metallurgy, pottery, glass

1.11

Combustion released the otherwise undetectable phlogiston. The more phlogiston a substance contained; the more easily it burned. Once all the phlogiston was gone, the substance was no longer combustible.

1.12

The mass of the reactants and products are easily observable quantities. The explanation of combustion must include an explanation of all observable quantities. Their explanation of the mass gain required phlogiston to have a negative mass.

1.13

Lavoisier measured the total mass of the reactants and products, not just the mass of the solids. The total mass of the reactants and products remained constant. His measurements showed that a gas was involved in the reaction. He called this gas oxygen (one of his key discoveries).

1.14

Observations are the first step in the scientific approach. The first observation is that the toast has not popped out of the toaster. The next step is a hypothesis (tentative explanation) to explain the observation. The hypothesis is that the spring mechanism is stuck. Next, there will be a test of the hypothesis. In this case, the test is an additional observation — the bread is unchanged. This observation leads to a new hypothesis — the toaster is unplugged. This hypothesis leads to additional tests — seeing if the toaster is plugged in, and if it works when plugged into a different outlet. The final test on the toaster leads to a new hypothesis — there is a problem with the power in the kitchen. This hypothesis leads to the final test concerning the light in the kitchen.

1.15

A quantitative observation is easier to characterize and reproduce. A qualitative observation may be subjective and open to interpretation. a) This is qualitative. When has the sun completely risen? b) The astronaut‘s mass may be measured; thus, this is quantitative. c) This is qualitative. Measuring the fraction of the ice above or below the surface would make this a quantitative measurement. d) The depth is known (measured) so this is quantitative.

1.16

A well-designed experiment must have the following essential features: 1) There must be two variables that are expected to be related. 2) There must be a way to control all the variables, so that only one at a time may be changed. 3) The results must be reproducible.

1.17

A model begins as a simplified version of the observed phenomena, designed to account for the observed effects, explain how they take place, and to make predictions of experiments yet to be done. The model is improved by further experiments. It should be flexible enough to allow for modifications as additional experimental results are gathered.

1.18

The unit you begin with (kilometres) must be in the denominator to cancel. The unit desired (centimetres) must be in the numerator. The kilometres will cancel leaving centimetres. If the conversion is inverted the answer would be in units of kilometres squared per centimetre.

1.19

1 m 2

100 cm 2 1000 m 2 ; to convert from m2 to cm2, use 100 cm 2 b) To convert from km2 to m2, use 1 km 2 1 m 2 c) This problem requires two conversion factors: one for distance (km to m) and one for time (h to s). It does not matter which conversion is done first and alternate methods may be used. To convert distance, km to m, use:  1000 m  3   = 10 m/km  1 km  To convert time, h to s, use: 1h  1 h  1 min      60 min  60 s  3600 s Therefore, the complete conversion factor is: 1 mh  1000 m  1 h      km  3600 s  3.6 km  s

Do the units cancel when you start with units of km/h? d) To convert from kg/m3 to g/cm3 requires two conversion factors: To convert mass, kg to g:  1000 g  3 g    10 1 kg kg   

To convert volume from cm3 to m3 use, 

1 m 3

 100 cm  

3   =106 m . cm3 

3 

 3 g   6 m3  g  m3 3 10 10  10 The complete conversion is:    cm3  kg  cm3  kg  Do the units cancel when you start with units of kg/m3? 1.20

Plan: Review the table of conversions in the chapter or inside the back cover of the book. Write the conversion factor so that the unit initially given will cancel, leaving the desired unit. Solution: a) This problem requires two conversion factors: one for distance and one for time. It does not matter which conversion is done first. Alternate methods may be used. To convert distance, cm to mm, use:  10 mm   1 cm 

To convert time, s to min, use:  1 min   60 s 

The complete conversion is:  10 mm   1 min   1 mm  min  1 cm   60 s 

6 cm  s

100 cm  1 m 3

b) To convert from m3 to cm3, use

c) This problem requires two conversion factors: one for distance and one for time squared. It does not matter which conversion is done first. Alternate methods may be used. To convert distance, m to km, use:  1 km  -3   = 10 km/m 1000 m   To convert time, s2 to h2, use: 2

 60 min   60 s  = 1.296 x 107 s2/1 h2      1 h   1 min 

 103 km  1.296 107 s 2  1.296  1010 km  s 2  Therefore, the complete conversion factor is  .     1 h2 m  h2  1 m   Do the units cancel when you start with a measurement of m/s2? d) This problem requires two conversion factors: one for volume and one for time. It does not matter which conversion is done first. Alternate methods may be used. To convert volume, mL to L, use: 

1L    1000 mL 

To convert time, s to min, use:  60 s   1 min  1 L  60 s  6 L s  1 min   100 mL  min 1000 mL   

The complete conversion factor is: 

1.21

Plan: Review the definitions of extensive and intensive properties. Solution: An extensive property depends on the amount of material present. An intensive property is the same regardless of how much material is present. a) Mass is an extensive property. Changing the amount of material will change the mass. b) Density is an intensive property. Changing the amount of material changes both the mass and the volume, but the ratio (density) remains fixed. c) Volume is an extensive property. Changing the amount of material will change the size (volume). d) The melting point is an intensive property. The melting point depends on the substance, not on the amount of substance.

1.22

Plan: Review the definitions of mass and weight. Solution: Mass is the quantity of material present, while weight is the interaction of gravity on mass. An object has a definite mass regardless of its location; its weight will vary with location. The lower gravitational attraction on the Moon will make an object appear to have approximately one-sixth its Earth weight. The object has the same mass on the Moon and on Earth. mass Plan: Density = . An increase in mass or a decrease in volume will increase the density. A volume decrease in density will result if the mass is decreased or the volume increased. Solution: a) Density increases. The mass of the chlorine gas is not changed, but its volume is smaller. b) Density remains the same. Neither the mass nor the volume of the solid has changed. c) Density decreases. Water is one of the few substances that expands on freezing. The mass is constant, but the volume increases. d) Density increases. Iron, like most materials, contracts on cooling; thus the volume decreases while the mass does not change. e) Density remains the same. The water does not alter either the mass or the volume of the diamond.

1.23

1.24

Plan: Review the definitions of heat and temperature. The two temperature values must be compared using one temperature scale, either Celsius or Fahrenheit. Solution: Heat is the energy that flows between objects at different temperatures while temperature is the measure of how hot or cold a substance is relative to another substance. Heat is an extensive property while temperature is an intensive property. It takes more heat to boil a gallon of water than to boil a teaspoon of water. However, both water samples boil at the same temperature. Convert 65°C to K: T (in K) = T (in °C) + 273.15 = (65°C) + 273.15 = 338 K A temperature of 65°C is 338 K. Heat will flow from the hot water (65°C or 338 K) to the cooler water (65 K). The 65°C water contains more heat than the cooler water.

1.25

When we have a set of ratios, the units will cancel out as they are multiplicative. For example, m=d/V; if we express mass in kg and density in kg/m3, it would give us the identical volume (but in different units) than if we used mass in g and density in g/cm3. In the first case, the volume will have units of m3 and in the second it will have units of cm3; however, the actual volume will be the same (if you convert one to the other). When temperature is one of the variables, however, the conversion between Celsius and Kelvin is an additive conversion, not multiplicative. Hence, in the equation PV=nRT, we must have the units for T match the units for R (which contains the temperature unit to be cancelled). This temperature, with only one or two exceptions, will be a temperature in kelvin.

1.26

Plan: Use conversion factors from the inside back cover: 1 pm = 10–12 m; 10–9 m = 1 nm. Solution:  1012 m   1 nm  Radius (nm) = 1430 pm    9  = 1.43 nm  1 pm   10 m 

1.27

1.28

1.29

1.30

Plan: Use conversion factors from the inside back cover: 10 –12 m = 1 pm; 10-9 m = 1 nm. Solution:  1 pm  2.22x1010 m  12   2.22  10 2 pm  10 m  Radius (Å) =  1 nm  2.22x1010 m  9   0.222 nm  10 m 









Plan: Use conversion factors: 1 m = 10-9 nm Solution:  109 nm  11 Length (nm) = 100. m     10 nm 1 m   Plan: Use the conversion factor 1 km = 106 mm to convert km to height in mm. Solution:  106 mm  Height (mm) =  0.00196 km    =1960 mm  1 km  Plan: Use conversion factors (1 cm)2 = (0.01 m)2; (1000 m)2 = (1 km)2 to express the area in km2. To calculate the cost of the patch, use the conversion factor: (2.54 cm) 2 = (1 in)2. Solution:  0.01 m 2  

a) Area (km2) = 20.7 cm 2  





1 km



2



–9



   101 cmmm    1$3.25  = $6.73  10 mm 



2 b) Cost = 20.7 cm 

1.31



   2.07x10 km =  1 cm    1000 m 





Plan: Use conversion factors (1 mm)2 = (10–3 m)2; (0.01 m)2 = (1 cm)2; Solution: 2   103 m   2  7.903  103 m 2 a) Area (m2) = 7903 mm  2   1 mm    









45 s  2  3 3 b) Time (s) = 7903 mm  2   = 2.634333x10 = 2.6x10 s 135 mm  



1.32

Plan: Use conversion factor 1 g = 1 paper clip. Solution: total mass (g) =  mass per clip  number of clips  Number of Clips =

1.33

Total mass  g  mass per clip



3.56×103 g  3.56×103 clips 1 g/clip

Plan: Use conversion factor 1000 kg = 1 metric ton. Solution:  1 kg   1 T  21 15 Mass (T) = 2.36 x10 g    3  = 2.36x10 T 1000 g 10 kg   



1.34



Plan: Mass in g is converted to kg in part a) with the conversion factor 1000 g = 1 kg; mass in g is converted to mg

in part b) with the conversion factors 1000 mg = 1 g. Volume in cm3 is converted to m3 with the conversion factor (1 cm)3 = (0.01 m)3 and to mm3 with the conversion factors (10 mm)3 = (1 cm)3. The conversions may be performed in any order. Solution: 

  1 kg  3 3   = 5.52x10 kg/m  cm   0.01 m    1000 g   1 cm 3   1000 mg  3  b) Density (mg/mm3) =  5.52 g     = 5.52 mg/mm  cm3   10 mm 3   1 g 

a) Density (kg/m3) =  5.52 g   

1 cm 

1.35

3 

Plan: Length in m is converted to km in part a) with the conversion factor 1000 m = 1 km; length in m is converted to mi in part b) with the conversion factors 1000 m = 1 km; 1 km = 0.62 mi. Time is converted using the conversion factors 60 s = 1 min; 60 min = 1 h. The conversions may be performed in any order. Solution:

 2.998 x108 m   60 s   60 min   1 km  9 9 a) Velocity (km/h) =       3  = 1.07928x10 = 1.079x10 km/h  1s    1 min   1 h   10 m   2.998 x108 m   60 s  100 cm  12 b) Velocity (cm/min) =      = 1.799x10 cm/min 1s    1 min  1m  1.36

Plan: Use the conversion factors (1 μm)3 = (1x10–6 m)3; (1x10–3 m)3 = (1 mm)3 to convert to mm3. To convert to L, use the conversion factors (1 μm) 3 = (1x10–6 m)3; (1x10–2 m)3 = (1 cm)3; 1 cm3 = 1 mL; 1 mL = 1x10–3 L. Solution:





 1x106 m 3    3   1 mm   = 2.56x10–9 mm3/cell 3 3      cell   1 μm    1x103 m     3    6 3  1x10 m   1 cm 3   1 mL   1x103 L   b) Volume (L) = 105 cells  2.56 μm    3 3  3    cell       1 μm    1x102 m   1 cm   1 mL       

3 

a) Volume (mm3) =  2.56 μm  



= 2.56 x 10 1.37





–10

L = 1 x 10

–10









L (because of sig figs in question)

Plan: For part a), convert from mL to L (1 mL = 1x10–3 L) and then to m3 (1 L = 10–3 m3). For part b), convert from mm3 to L using the following conversion factors: (10 mm)3 = (1 cm)3, 1 mL = 1 cm3 and 1 mL = 10–3 L. Solution:  103 L  103 m3  –4 3 a) Volume (m3) = 946.4 mL    1 L  = 9.464x10 m 1 mL   

 (1 cm)3   1mL   103 L  3 4 b) Volume (L) = 835 mm  3    1 cm3   1 mL   8.35x10 L (10 mm)    



1.38



Plan: The mass of the mercury in the vial is the mass of the vial filled with mercury minus the mass of the empty vial. Use the density of mercury and the mass of the mercury in the vial to find the volume of mercury and thus the volume of the vial. Once the volume of the vial is known, that volume is used in part b. The density of water is used to find the mass of the given volume of water. Add the mass of water to the mass of the empty vial. Solution: a) Mass (g) of mercury = mass of vial and mercury – mass of vial = 185.56 g – 55.32 g = 130.24 g

 1 cm3  3 Volume (cm3) of mercury = volume of vial = 130.24 g   = 9.626016 = 9.626 cm 13.53 g   b) Volume (cm3) of water = volume of vial = 9.626016 cm3



 1 cm 

Mass (g) of water = 9.626016 cm3  0.997 g  = 9.59714 g water 3 Mass (g) of vial filled with water = mass of vial + mass of water = 55.32 g + 9.59714 g = 64.91714 = 64.92 g 1.39

Plan: The mass of the water in the flask is the mass of the flask and water minus the mass of the empty flask. Use the density of water and the mass of the water in the flask to find the volume of water and thus the volume of the flask. Once the volume of the flask is known, that volume is used in part b. The density of chloroform is used to find the mass of the given volume of chloroform. Add the mass of the chloroform to the mass of the empty flask. Solution: a) Mass (g) of water = mass of flask and water – mass of flask = 489.1 g – 241.3 g = 247.8 g  1 cm3  3 Volume (cm3) of water = volume of flask = 247.8 g   = 247.8 = 248 cm  1.00 g  b) Volume (cm3) of chloroform = volume of flask = 247.8 cm3



 cm

Mass (g) of chloroform = 247.8 cm3  1.48 g  = 366.744 g chloroform 3 

Mass (g) of flask and chloroform = mass of flask + mass of chloroform = 241.3 g + 366.744 g = 608.044 g = 608 g 1.40

Plan: Calculate the volume of the cube using the relationship Volume = (length of side) 3. The length of side in mm must be converted to cm so that volume will have units of cm3. Divide the mass of the cube by the volume to find density. Solution:  103 m   1 cm  Side length (cm) = 15.6 mm    2  = 1.56 cm (convert to cm to match density unit)  1 mm   10 m  Al cube volume (cm3) = (length of side)3 = (1.56 cm)3 = 3.7964 cm3 mass 10.25 g Density (g/cm3 )   = 2.69993 = 2.70 g/cm3 3 volume 3.7964 cm

1.41

Plan: Use the relationship c = 2πr to find the radius of the sphere and the relationship V = 4/3πr3 to find the volume of the sphere. The volume in mm3 must be converted to cm3. Divide the mass of the sphere by the volume to find density. Solution: c = 2πr c 32.5 mm = Radius (mm) = = 5.17254 mm 2 2 4 Volume (mm3) =  r 3 =  4   (5.17254 mm)3 = 579.6958 mm3 3 3 3



Volume (cm ) = 579.6958 mm

Density (g/cm3 ) 

 103 m   1 cm 3 3    2  = 0.5796958 cm   1 mm   10 m 



mass 4.20 g  = 7.24518 = 7.25 g/cm3 volume 0.5796958 cm3

1.42

Plan: Use the equations given in the text for converting between the three temperature scales. Solution: a) T (in K) = T (in °C) + 273.15 = 18°C + 273.15 = 291.15 = 291 K b) T (in K) = T (in °C) + 273.15 = –164°C + 273.15 = 109.15 = 109 K c) T (in °C) = T (in K) – 273.15 = 0 K – 273.15 = –273.15 = –273°C

1.43

Plan: Use the equations given in the text for converting between the three temperature scales. Solution: a) T (in K) = T (in °C) + 273.15 = 37C + 273.15 = 310.15 = 310 K b) T (in K) = T (in °C) + 273.15 = 3410°C + 273 = 3683 K c) T (in C) = T (in K) –273.15 = 6.1x103 K – 273 = 5.827x103 = 5.8 x 103°C

1.44

Plan: Find the volume occupied by each metal by taking the difference between the volume of water and metal and the initial volume of the water (25.0 mL). Divide the mass of the metal by the volume of the metal to calculate density. Use the density value of each metal to identify the metal. Solution: Cylinder A: volume of metal = [volume of water + metal] – [volume of water] volume of metal = 28.2 mL – 25.0 mL = 3.2 mL mass 25.0 g = Density = = 7.81254 = 7.8 g/mL volume 3.2 mL Cylinder A contains iron. Cylinder B: volume of metal = [volume of water + metal] – [volume of water] volume of metal = 27.8 mL – 25.0 mL = 2.8 mL mass 25.0 g = Density = = 8.92857 = 8.9 g/mL volume 2.8 mL Cylinder B contains nickel. Cylinder C: volume of metal = [volume of water + metal] – [volume of water] volume of metal = 28.5 mL – 25.0 mL = 3.5 mL mass 25.0 g = Density = = 7.14286 = 7.1 g/mL volume 3.5 mL Cylinder C contains zinc.

1.45

Plan: Use 1 nm = 10–9 m to convert wavelength in nm to m. To convert wavelength in pm to nm, use 1000 pm = 1 nm. Solution:  109 m  –7 a) Wavelength (m) = 247 nm   = 2.47x10 m  1 nm 

 1 nm   = 6.76 nm  1000 pm 

b) Wavelength (nm) =  6760 pm   1.46

Plan: The liquid with the larger density will occupy the bottom of the beaker, while the liquid with the smaller density volume will be on top of the more dense liquid. Solution: a) Liquid A is more dense than water; liquids B and C are less dense than water. b) Density of liquid B could be 0.94 g/mL. Liquid B is more dense than C so its density must be greater than 0.88 g/mL. Liquid B is less dense than water so its density must be less than 1.0 g/mL.

1.47

Plan: Calculate the volume of the cylinder in cm3 by using the equation for the volume of a cylinder. The diameter of the cylinder must be halved to find the radius. Convert the volume in cm 3 to dm3 by using the conversion factors (1 cm)3 = (10–2 m)3 and (10–1 m)3 = (1 dm)3. Solution: Radius = diameter/2 = 0.85 cm/2 = 0.425 cm Volume (cm3) = πr2h = π(0.425 cm)2(9.5 cm) = 5.3907766 cm3 3

 102 m   1 dm  Volume (dm3) = 5.3907766 cm3  = 5.39078x10–3 = 5.4x10–3 dm3  1 cm   101 m     



1.48



Plan: Use the percent of copper in the ore to find the mass of copper in 5.01 kg of ore. Convert the mass in kg to mass in g. The density of copper is used to find the volume of that mass of copper. Use the volume equation for a cylinder to calculate the height of the cylinder (the length of wire); the diameter of the wire is used to find the radius which must be expressed in units of cm. Length of wire in cm must be converted to m. Solution: Mass (kg) of copper =  5.01 kg Covellite   66%  = 3.3066 kg copper  100% 

 1000 g  3  = 3.3066 x10 g 1 kg  

Mass (g) of copper =  3.3066 kg  

 cm3 Cu  3 3 Volume (cm3) of copper = 3.3066x10 g Cu   = 369.453 cm Cu 8.95 g Cu   2 V = r h





1 cm  –3 Radius (cm) =  0.1601 mm    = 8.005x10 cm 

 10 mm 

Height (length) in cm =

 r2

369.453 cm3

   8.005 x10 cm  3

= 1.835 x 106 cm

 102 m  6 4 4 Length (m) = 1.835x10 cm   = 1.835x10 = 1.84x10 m 1 cm  





1.49

An exact number is defined to have a certain value (exactly). There is no uncertainty in an exact number. An exact number is considered to have an infinite number of significant figures and, therefore, does not limit the digits in the calculation.

1.50

Random error of a measurement is decreased by (1) taking the average of more measurements. More measurements allow a more precise estimate of the true value of the measurement. Calibrating the instrument will allow greater accuracy but not necessarily greater precision.

1.51

a) If the number is an exact count then there are an infinite number of significant figures. If it is not an exact count, there are only 5 significant figures. b) Other things, such as number of tickets sold, could have been counted instead. c) A value of 15,000 to two significant figures is 1.5x10 4. Values would range from 14,501 to 15,499. Both of these values round to 1.5x10 4.

1.52

Plan: Review the rules for significant zeros. Solution: a) No significant zeros (leading zeros are not significant) b) No significant zeros (leading zeros are not significant) c) 0.0410 (terminal zeros to the right of the decimal point are significant) d) 4.0100x104 (zeros between nonzero digits are significant; terminal zeros to the right of the decimal point are significant)

1.53

Plan: Review the rules for significant zeros. Solution: a) 5.08 (zeros between nonzero digits are significant) b) 508 (zeros between nonzero digits are significant) c) 5.080x103 (zeros between nonzero digits are significant; terminal zeros to the right of the decimal point are significant) d) 0.05080 (leading zeros are not significant; zeros between nonzero digits are significant; terminal zeros to the right of the decimal point are significant)

1.54

Plan: Review the rules for rounding. Solution: (significant figures are underlined) a) 0.0003554: the extra digits are 54 at the end of the number. When the digit to be removed is 5 and that 5 is followed by nonzero numbers, the last digit kept is increased by 1: 0.00036 b) 35.8348: the extra digits are 48. Since the digit to be removed (4) is less than 5, the last digit kept is unchanged: 35.83 c) 22.4555: the extra digits are 555. When the digit to be removed is 5 and that 5 is followed by nonzero numbers, the last digit kept is increased by 1: 22.5

1.55

Plan: Review the rules for rounding. Solution: (significant figures are underlined) a) 231.554: the extra digits are 54 at the end of the number. When the digit to be removed is 5 and that 5 is followed by nonzero numbers, the last digit kept is increased by 1: 231.6 b) 0.00845: the extra digit is 5 at the end of the number. When the digit to be removed is 5 and that 5 is not followed by nonzero numbers, the last digit kept remains unchanged if it is even and increased by 1 if it is odd: 0.0084 c) 144,000: the extra digits are 4000 at the end of the number. When the digit to be removed (4) is less than 5, the last digit kept remains unchanged: 140,000 (or 1.4x105)

1.56

Plan: Review the rules for rounding. Solution: 19 rounds to 20: the digit to be removed (9) is greater than 5 so the digit kept is increased by 1. 155 rounds to 160: the digit to be removed is 5 and the digit to be kept is an odd number, so that digit kept is increased by 1. 8.3 rounds to 8: the digit to be removed (3) is less than 5 so the digit kept remains unchanged. 3.2 rounds to 3: the digit to be removed (2) is less than 5 so the digit kept remains unchanged. 2.9 rounds to 3: the digit to be removed (9) is greater than 5 so the digit kept is increased by 1. 4.7 rounds to 5: the digit to be removed (7) is greater than 5 so the digit kept is increased by 1.

 20 x 160 x 8    = 568.89 = 6x102 3 x 3 x 5   Since there are numbers in the calculation with only one significant figure, the answer can be reported only to one significant figure. (Note that the answer is 560 using the original numbers.) 1.57

Plan: Review the rules for rounding. Solution: 10.8 rounds to 11: the digit to be removed (8) is greater than 5 so the digit kept is increased by 1. 6.18 rounds to 6.2: the digit to be removed (8) is greater than 5 so the digit kept is increased by 1. 2.381 rounds to 2.38: the digit to be removed (1) is less than 5 so the digit kept remains unchanged. 24.3 rounds to 24: the digit to be removed (3) is less than 5 so the digit kept remains unchanged. 1.8 rounds to 2: the digit to be removed (8) is greater than 5 so the digit kept is increased by 1. 19.5 rounds to 20: the digit to be removed is 5 and the digit to be kept is an odd number, so that digit kept is increased by 1.

 11 x 6.2 x 2.38    = 0.1691 = 0.2  24 x 2 x 20  Since there is a number in the calculation with only one significant figure, the answer can be reported only to Silberberg, Amateis, Venkateswaran, Chen, Chemistry: The Molecular Nature of Matter and Change, 3rd Canadian Edition Page 1-11 Instructor‘s Solution Manual © Copyright 2021 McGraw-Hill Ryerson Ltd.

one significant figure. (Note that the answer is 0.19 with original number of significant figures.) 1.58

Plan: Use a calculator to obtain an initial value. Use the rules for significant figures and rounding to get the final answer. Solution: a)

 2.795 m  310 m  = 133.71 = 130 m (maximum of 2 significant figures allowed since 310 has 2 sf) 6.48 m

b) V =  4   17.282 mm 3 = 21,620.74 = 21,621 mm3 (maximum of 5 significant figures allowed) 3

c) 1.110 cm + 17.3 cm + 108.2 cm + 316 cm = 442.61 = 443 cm (no digits allowed to the right of the decimal since 316 has no digits to the right of the decimal point) 1.59

Plan: Use a calculator to obtain an initial value. Use the rules for significant figures and rounding to get the final answer. Solution: a)

2.420 g  15.6 g = 3.7542 = 3.8 (maximum of 2 significant figures allowed since one of the original 4.8 g

numbers in the calculation has only 2 significant figures) b)

7.87 mL = 1.0274 = 1.0 (After the subtraction, the denominator has 2 significant figures; only one 16.1 mL  8.44 mL

digit is allowed to the right of the decimal in the value in the denominator since 16.1 has only one digit to the right of the decimal.) c) V = π(6.23 cm)2(4.630 cm) = 564.556 = 565 cm3 (maximum of 3 significant figures allowed since one of the original numbers in the calculation has only 3 significant figures) 1.60

Plan: Review the procedure for changing a number to scientific notation. There can be only 1 nonzero digit to the left of the decimal point in correct scientific notation. Moving the decimal point to the left results in a positive exponent while moving the decimal point to the right results in a negative exponent. Solution: a) 1.310000x105 (Note that all zeros are significant.) b) 4.7x10–4 (No zeros are significant.) c) 2.10006x105 d) 2.1605x103

1.61

Plan: Review the procedure for changing a number to scientific notation. There can be only 1 nonzero digit to the left of the decimal point in correct scientific notation. Moving the decimal point to the left results in a positive exponent while moving the decimal point to the right results in a negative exponent. Solution: a) 2.820x102 (Note that the zero is significant.) b) 3.80x10–2 (Note the one significant zero.) c) 4.2708x103 d) 5.82009x104

1.62

Plan: Review the examples for changing a number from scientific notation to standard notation. If the exponent is positive, move the decimal back to the right; if the exponent is negative, move the decimal point back to the left. Solution: a) 5550 (Do not use terminal decimal point since the zero is not significant.) b) 10070. (Use terminal decimal point since final zero is significant.) c) 0.000000885 d) 0.003004

1.63

Solution: a) 6500. b) 0.0000346 c) 750 d) 188.56

(Use terminal decimal point since the final zero is significant.) (Do not use terminal decimal point since the zero is not significant.)

1.64

Plan: In most cases, this involves a simple addition or subtraction of values from the exponents. There can be only 1 nonzero digit to the left of the decimal point in correct scientific notation. Solution: a) 8.025x104 (The decimal point must be moved an additional 2 places to the left: 10 2 x 102 = 104) –3 b) 1.0098x10 (The decimal point must be moved an additional 3 places to the left: 10 3 x 10–6 = 10–3) –11 c) 7.7x10 (The decimal point must be moved an additional 2 places to the right: 10–2 x 10–9 = 10–11)

1.65

Plan: In most cases, this involves a simple addition or subtraction of values from the exponents. There can be only 1 nonzero digit to the left of the decimal point in correct scientific notation. Remember: when we multiply powers of ten, we add the exponents. Solution: a) 1.43x102 (The decimal point must be moved an additional 1 place to the left: 10 1 x 101 = 102) b) 8.51 (The decimal point must be moved an additional 2 places to the left: 102 x 10–2 = 100) c) 7.5 (The decimal point must be moved an additional 3 places to the left: 10 3 x 10–3 = 100)

1.66

Plan: Calculate a temporary answer by simply entering the numbers into a calculator. Then you will need to round the value to the appropriate number of significant figures. Cancel units as you would cancel numbers, and place the remaining units after your numerical answer. Solution: a)

6.626 x10

34

  2.9979 x10 m/s  = 4.062185x10 J 8

–19

489 x109 m 4.06x10–19 J (489x10–9 m limits the answer to 3 significant figures; units of m and s cancel)

6.022 x 10 molecules/mol 1.23 x 10 g  = 1.6078x10 molecules b) 23

46.07 g/mol 1.61x1024 molecules (1.23x102 g limits answer to 3 significant figures; units of mol and g cancel)





 2

c) 6.022 x 1023 atoms/mol 2.18 x 1018 J/atom  1  1  = 1.82333x105 J/mol 2 2 5

1.82x10 J/mol (2.18x10 1.67

–18

3 

J/atom limits answer to 3 significant figures; unit of atoms cancels)

4.32 x107 g

= 1.3909 = 1.39 g/cm3 3 4 2  3.1416  1.95x10 cm 3 (4.32x107 g limits the answer to 3 significant figures) a)





1.84x10 g  44.7 m/s  = 1.8382x10 = 1.84x10 g·m /s b) 2

(1.84x102 g limits the answer to 3 significant figures)

1.07 x10 mol / L   3.8 x 10 mol / L  = 1.9248 x 10 = 1.9 x 10 L /mol c) 8.35 x10 mol / L  1.48 x 10 mol / L  4

3

5

2

(3.8x10–3 mol/L limits the answer to 2 significant figures; mol3/L3 in the numerator cancels mol5/L5 in the denominator to leave mol2/L2 in the denominator or units of L2/mol2) 1.68

Plan: Exact numbers are those which have no uncertainty. Unit definitions and number counts of items in a group are examples of exact numbers. Solution: a) The height of Horseshoe Falls is a measured quantity. This is not an exact number. b) The number of planets in the solar system is a number count. This is an exact number. c) The number of students in a classroom is an exact number. We cannot have ½ a student. d) The number of millimeters in a meter is a definition of the prefix ―milli–.‖ This is an exact number.

1.69

Plan: Exact numbers are those which have no uncertainty. Unit definitions and number counts of items in a group are examples of exact numbers. Solution: a) The speed of light is a measured quantity. It is not an exact number. b) The density of mercury is a measured quantity. It is not an exact number. c) The number of seconds in an hour is based on the definitions of minutes and hours. This is an exact number. d) The number of provinces and territories is a counted value. These are exact numbers.

1.70

Plan: Observe the figure, and estimate a reading the best you can. Solution: The scale markings are 0.2 cm apart. The end of the metal strip falls between the mark for 7.4 cm and 7.6 cm. If we assume that one can divide the space between markings into half, the uncertainty is one-half the separation between the marks. Thus, since the end of the metal strip falls between 7.4 and 7.6 we can report its length as 7.5 ± 0. 1 cm.

1.71

Plan: You are given the density values for five solvents. Use the mass and volume given to calculate the density of the solvent in the cleaner and compare that value to the density values given to identify the solvent. Use the uncertainties in the mass and volume to recalculate the density. Solution: mass 11.775 g  a) Density (g/mL)  = 0.7850 g/mL. The closest value is isopropanol. volume 15.00 mL b) Ethanol is denser than isopropanol. Recalculating the density using the maximum mass = (11.775 + 0.003) g with the minimum volume = (15.00 – 0.02) mL, gives mass 11.778 g Density (g/mL)   = 0.7862 g/mL. This result is still clearly not ethanol. volume 14.98 mL Yes, the equipment is precise enough.

1.72

Plan: Calculate the average of each data set. Remember that accuracy refers to how close a measurement is to the actual or true value while precision refers to how close multiple measurements are to each other. Solution: 8.72 g  8.74 g  8.70 g a) Iavg = = 8.7200 = 8.72 g 3 8.56 g  8.77 g  8.83 g IIavg = = 8.7200 = 8.72 g 3 8.50 g  8.48 g  8.51 g IIIavg = = 8.4967 = 8.50 g 3 8.41 g  8.72 g  8.55 g IVavg = = 8.5600 = 8.56 g 3 Sets I and II are most accurate since their average value, 8.72 g, is closest to the true value, 8.72 g. b) To get an idea of precision, calculate the range of each set of values: largest value – smallest value. A small range is an indication of good precision since the values are close to each other. Irange = 8.74 g – 8.70 g = 0.04 g

IIrange = 8.83 g – 8.56 g = 0.27 g IIIrange = 8.51 g – 8.48 g = 0.03 g IVrange = 8.72 g – 8.41 g = 0.31 g Set III is the most precise (smallest range), but is the least accurate (the average is the farthest from the actual value). c) Set I has the best combination of high accuracy (average value = actual value) and high precision (relatively small range). d) Set IV has both low accuracy (average value differs from actual value) and low precision (has the largest range).

1.74

Plan: If it is necessary to force something to happen, the potential energy will be higher. Solution: a) b)

Potential Energy

Plan: Remember that accuracy refers to how close a measurement is to the actual or true value; since the bull‘seye represents the actual value, the darts that are closest to the bull‘s-eye are the most accurate. Precision refers to how close multiple measurements are to each other; darts that are positioned close to each other on the target have high precision. Solution: a) Experiments II and IV — the averages appear to be near each other. b) Experiments III and IV — the darts are closely grouped. c) Experiment IV and perhaps Experiment II — the average is in or near the bull‘s-eye. d) Experiment III — the darts are close together, but not near the bull‘s-eye.

Potential Energy

1.73

+ + +

a) The balls on the relaxed spring have a lower potential energy and are more stable. The balls on the compressed spring have a higher potential energy, because the balls will move once the spring is released. This configuration is less stable. b) The two + charges apart from each other have a lower potential energy and are more stable. The two + charges near each other have a higher potential energy, because they repel one another. This arrangement is less stable.

1.75

Plan: A physical change is one in which the physical form (or state) of a substance, but not its composition, is altered. A chemical change is one in which a substance is converted into a different substance with different composition and properties. Solution: a) Bonds have been broken in three yellow diatomic molecules. Bonds have been broken in three red diatomic molecules. The six resulting yellow atoms have reacted with three of the red atoms to form three molecules of a new substance. The remaining three red atoms have reacted with three blue atoms to form a new diatomic substance. b) There has been one physical change as the blue atoms at 273 K in the liquid phase are now in the gas phase at 473 K.

1.76

Plan: Use the concentrations of bromine given. Solution: Mass bromine in Dead Sea 0.50 g/L = = 7.7 / 1 Mass bromine in seawater 0.065 g/L

1.77

Plan: The swimming pool is a rectangle so the volume of the water can be calculated by multiplying the three dimensions of length, width, and the depth of the water in the pool. The depth in cm must be converted to units of m before calculating the volume. The density of water is used to find the mass of this volume of water. Solution:  102 m  a) Depth of water (m) = 146cm    = 1.46 m  1 cm  Volume (m3) = length x width x depth =  50.0 m  25.0 m 1.46 m  = 1825 m3 b) Using the density of water = 1.0 g/mL.  (100 cm)3   1 mL  1.0 g   1 kg  3 6 6 Mass (kg) = 1825m      1000 g  = 1.825x10 = 1.8x10 kg 3 3  mL 1 m 1 cm     



1.78



Plan: In each case, calculate the overall density of the ball and contents and compare to the density of air. The volume of the ball in cm3 is converted to units of L to find the density of the ball itself in g/L. The densities of the ball and the gas in the ball are additive because the volume of the ball and the volume of the gas are the same. Solution: a) Density of evacuated ball: the mass is only that of the sphere itself: 3 L 3  1 mL   10 Volume of ball (L) = 560 cm    = 0.560 = 0.56 L 3    1 cm  1 mL  mass 0.12 g  Density of evacuated ball = = 0.21 g/L volume 0.560 L The evacuated ball will float because its density is less than that of air. b) density of CO2 = 1.830 g/L; mass of CO2 = dV = (1.830 g/L)(0.56 L) = 1.02 g plus mass of ball gives total mass = 1.02 g + 0.12 g = 1.14 g; d = m/V = 1.14 g/0.56 L = 2.04 g/L; more than air; will sink c) density of H2 = 0.0899 g/L; mass of H2 = dV =(0.0899 g/L)(0.56 L) = 0.050 g plus mass of ball gives total mass = 0.050 g + 0.12 g = 0.17 g; d = m/V = 0.17 g/0.56 L = 0.30 g/L; less than air; will float d) using a similar calculation, density of ball + O2 = 1.54 g/L; more than air; will sink. e) using a similar calculation, density of ball + N2 = 1.38 g/L; more than air; will sink





 0.560 L   1.189 g  f) To sink, the total mass of the ball and gas must be    1 L   0.66584 g    For the evacuated ball: 0.66584 – 0.12 g = 0.54585 = 0.55 g. More than 0.55 g would have to be added to make the ball sink. For ball filled with hydrogen:

Mass of hydrogen in the ball = 0.56 L  0.0899 g   0.0503 g 



Mass of hydrogen and ball = 0.0503 g + 0.12 g = 0.17 g 0.66584 – 0.17 g = 0.4958 = 0.50 g. More than 0.50 g would have to be added to make the ball sink. 1.79

Plan: Convert the cross-sectional area of 1.0 μm2 to mm2 and then use the tensile strength of grunerite to find the mass that can be held up by a strand of grunerite with that cross-sectional area. Calculate the area of aluminum and steel that can match that mass. Solution:









 1x106 m 2    2   1 mm   = 1.0x10–6 mm2 2 2    3  1 μm    1x10 m    

Cross-sectional area (mm2) = 1.0 μm2  





Calculate the mass that can be held up by grunerite with a cross-sectional area of 1.0x10–6 mm2:  3.5x102 kg  1x106 mm2   3.5 104 kg  1 mm 2    Calculate the area of aluminum required to match a mass of 3.5x10 –4 kg:

 



2  1 cm 2   10 mm      1.9444x10 5 = 1.9x10–5 mm2 3.5 x104 kg   2   1.8x103 kg      1 cm  



Calculate the area of steel required to match a mass of 3.5 x 10 –4 kg:

 1.80

2  1 cm 2   10 mm      1.0000x105 = 1.0x10–5 mm2 3.5x104 kg   2   3.5x103 kg   1 cm     



Plan: Convert the surface area to m2 and then use the surface area and the depth to determine the volume of the oceans (area x depth = volume) in m3. The volume is then converted from cubic metres to litres, and finally to the mass of gold using the density of gold in g/L. Once the mass of the gold is known, its density is used to find the volume of that amount of gold. The mass of gold is converted to troy oz and the price of gold per troy oz gives the total price. Solution:  1000 m 2  14 2  = 3.63x10 m  1 km 2   

a) Area of ocean (m2) = 3.63x108 km 2  





Volume of ocean (m3) = (area)(depth) = (3.63x1014 m2)(3800 m) = 1.3794x1018 m3 1 L   5.8 x 109 g  18 3  12 12 Mass of gold (g) = 1.3794 x 10 m  3 3    = 8.00052x10 = 8.0x10 g L 10 m    b) Use the density of gold to convert mass of gold to volume of gold:





3 



3 

 19.3 g  1 cm   = 4.14535x10 = 4.1x10 m 



Volume of gold (m3) = 8.00052 x 1012 g  1 cm     



0.01 m



tr. oz.  $1611.46    131.1   = 4.14551x10 = $4.1x10 g  1 tr. oz. 

12 c) Value of gold = 8.00052 x 10 g 

1.81

Plan: The mass of zinc in the sample of yellow zinc in part a) is found from the percent of zinc in the sample. The mass of copper is found by subtracting the mass of zinc from the total mass of yellow zinc. In part b), subtract the mass percent of zinc from 100 to find the mass percent of copper. Solution:



 34% zinc  = 62.9 g Zn  100% yellow zinc 

a) Mass of zinc in the 34% zinc sample = 185 g yellow zinc 



 37% zinc  = 68.45 g Zn  100% yellow zinc 

Mass of zinc in the 37% zinc sample = 185 g yellow zinc 

Mass copper = total mass – mass zinc Mass copper (34% zinc sample) = 185 g – 62.9 g = 122.1 = 122 g Mass copper (37% zinc sample) = 185 g – 68.45 g = 116.55 = 117 g 117 to 122 g copper b) The 34% zinc sample contains 100 – 34 = 66% copper. The 37% zinc sample contains 100 – 37 = 63% copper.

 34% zinc   = 23.95 = 24 g  66% copper 

Mass of zinc = 46.5 g copper 

 37% zinc   = 27.31 = 27 g  63% copper 

Mass of zinc = 46.5 g copper  24 to 27 g zinc 1.82

Plan: Use the equations for temperature conversion given in the chapter. The mass of nitrogen is conserved when the gas is liquefied; the mass of the nitrogen gas equals the mass of the liquid nitrogen. Use the density of nitrogen gas to find the mass of the nitrogen; then use the density of liquid nitrogen to find the volume of that mass of liquid nitrogen. Solution: a) T (in °C) = T (in K) – 273.15 = 77.36 K – 273.15 = –195.79°C b) Mass of liquid nitrogen = mass of gaseous nitrogen = 895.0 L  4.566 g  = 4086.57 g N2 



 1L   = 5.0514 = 5.05 L  809 g 

Volume of liquid N2 = 4086.57 g  1.83

Plan: For part a), convert km to m and h to s. For part b), time is converted from h to min and length stays in km. For part c), use the average speed in km/h to find the time necessary to cover the given distance. Solution:

 9.4 km  1000 m   1 h   = 2.611 = 2.6 m/s    h  1 km   3600 s 

a) Speed (m/s) = 

b) Distance (km) =  98 min   1 h

 9.4 km  = 15.353 = 15 km    60 min  h 

c) Time (h) = 14.5 km   1 h

 = 1.5426 = 1.5 h   9.4 km 

If she starts running at 11:15 am, 1.5 hours later the time is 12:45 pm. 1.84

Plan: A physical change is one in which the physical form (or state) of a substance, but not its composition, is altered. A chemical change is one in which a substance is converted into a different substance with different composition and properties. A physical property is a characteristic shown by a substance itself, without interacting with or changing into other substances. A chemical property is a characteristic of a substance that appears as it interacts with, or transforms into, other substances.

Solution: a) Scene A shows a physical change. The substance changes from a solid to a gas but a new substance is not formed. b) Scene B shows a chemical change. Two diatomic elements form from a diatomic compound. c) Both Scenes A and B result in different physical properties. Physical and chemical changes result in different physical properties. d) Scene B is a chemical change; therefore, it results in different chemical properties. e) Scene A results in a change in state. The substance changes from a solid to a gas. 1.85

Plan: In visualizing the problem, the two scales can be set next to each other. Solution: There are 50 divisions between the freezing point and boiling point of benzene on the °X scale and 74.6 divisions (80.1oC – 5.5oC) on the °C scale. So °X =  50X  °C  74.6C 

This does not account for the offset of 5.5 divisions in the °C scale from the zero point on the °X scale. So °X =  50X  (°C – 5.5°C)  74.6C 

Check: Plug in 80.1°C and see if result agrees with expected value of 50°X. So °X =  50X  (80.1°C – 5.5°C) = 50°X  74.6C 

Use this formula to find the freezing and boiling points of water on the °X scale. fpwater °X =  50X  (0.00°C – 5.5°C) = –3.68°X = –3.7°X  74.6C 

bpwater °X =  50X  (100.0°C – 5.5°C) = 63.3°X  74.6C 

1.86

Plan: Determine the total mass of Earth‘s crust in metric tonnes (t) by finding the volume of crust (surface area x depth) in km3 and then in cm3 and then using the density to find the mass of this volume, using conversions from the inside back cover. The mass of each individual element comes from the concentration of that element multiplied by the mass of the crust. Solution:





Volume of crust (km3) = area x depth = 5.10x108 km 2  35 km  = 1.785x1010 km3  1000 m 3  



Mass of crust (t) = 1.785 x 10





1 cm



 2.8 g   1 kg  1 t  19 cm3    = 4.998x10 t   1 cm3   1000 g  1000 kg 





Mass of oxygen (g) = 4.998 x 10

Mass of silicon (g) = 4.998 x 10

 4.55 x 105 g oxygen  t   = 2.2741x1025 = 2.3x1025 g oxygen  1 t  



 2.72 x 105 g silicon  25 25 t   = 1.3595x10 = 1.4x10 g silicon  1 t  



 1 x 104 g element  t    1t   = 4.998x1015 = 5x1015 g each of ruthenium and rhodium Plan: Find the total number of washers from the fact that each washer has an outer diameter of 1 cm and the sheet is 24.0 cm x 12.0 cm. Calculate the area of the outer circle and subtract the area of the inner circle to get the surface area of the washer. Multiply the surface area of the washer by the thickness to get the volume of the washer. The



Mass of ruthenium = mass of rhodium = 4.998 x 10

1.87



   = 1.785x10 cm   1 km     0.01 m 



Volume of crust (cm3) = 1.785 x 1010 km3 



total volume of the washers is the number of washers times the volume per washer. We can find the total volume of the sheet of zinc by multiplying the length x width x height. The volume of the zinc left is the total volume of zinc minus the total volume of the washers. Once we know the volume of zinc left, the mass of zinc left is the volume times the density. Solution: We can get 24 washers along the edge that is 24.0 cm and 12 washers along the edge that is 12.0 cm. No.TOT = 24 x 12 = 288 washers

Aouter circle   r 2  (3.141)(0.5 cm) 2  0.79 cm 2

Ainner circle   r 2  (3.141)(0.25 cm) 2  0.20 cm 2 Awasher  Aouter circle  Ainner circle  0.79 cm 2  0.20 cm 2  0.59 cm 2

Vwasher  A  h  (0.59 cm 2 )(0.5 cm)=0.29 cm3 VTot, washers  Vwasher  No. of washers=(0.29 cm3 )(288)  84.8 cm3 VZn sheet  l  w  h  (24.0 cm)(12.0 cm)(0.5 cm)  144.0 cm3 VZn left over  VZn sheet  VTot, washers  144.0 cm3  84.8 cm3  59.2 cm3 m Zn left over  VZn left over  d Zn  (59.2 cm3 )(7.049

g )  417 g cm3

The volume of Zn remaining is 59.2 cm3 and the mass remaining is 417 g. 1.88

Plan: Use the inner diameter of the tube and the length to find the volume of the inside of the tube. Use the density of mercury and volume to find the mass of mercury in the tube. Use the mass of mercury, set equal to the mass of ethanol, and the density of ethanol to find the volume of ethanol. Use the volume of ethanol, the inner diameter of the new tube, and the equation for the volume of a cylinder to find the length of the tube. Solution:

1.03 cm 2 Vtube interior   r 2l  (3.141)( ) (25 cm) = 20.8 cm3 2 kg 1000 g 1 m3 mHg  Vtube interior  d Hg  (20.8 cm3 )(13534 3 )( )( )  281.9 g  280 g (2sf) m 1 kg 102 cm 3

mHg  methanol Vethanol 

ltube 

methanol  d ethanol

282 g  357 cm3 3 kg 1000 g 1m (789.00 3 )( )( 6 ) m 1 kg 10 cm 3

Vethanol 357 cm3   640 cm 0.84 cm 2  r2 (3.141)( ) 2

The length of the tube would need to be 640 cm. NOTE: in part a), the answer was given to 2 sf, but in part b), the more precise answer was used to continue the calculation. Rounding too soon will lead to large rounding errors. 1.89 Plan: We will use what we know of sand and gold to determine the answer to part a. In part b), we can use the density and the volume of gold to find its mass. In part c), we use the fact that the masses have to be the same to

keep the trap from springing and then the density and mass to find the volume of sand needed. We will use all these answers to respond to part d). Solution: a)

Sand is lighter than gold. In this question just looking at the numbers also tells us that sand is much less dense than gold. That means an object that is the same approximate size (volume), cannot have the same mass. Therefore, the premise (the idea) is not scientifically reasonable.

mAu  d Au  VAu  (19.3

g )(53.5 cm3 )  1.03 103 g =1.03 kg 3 cm

The mass of the gold statue would be 1.03 kg. c)

msand  dsand

VAu  Vsand 

1.03 kg  6.45 102 cm3  645 mL 3 kg 1m (1600 3 )( 6 ) m 10 cm3

The volume of sand having a mass equal to that of the gold statue would be 645 mL. d) This is consistent. There is no way that a bag of sand the same approximate size as the idol would have had a mass that was sufficient to keep from setting off the booby trap. (Incidentally, it did not work in the movie either!) 1.90

Plan: Find the volume of 2.59 g of Pb using the density. Then find the mass of Cu using V and d. Solution: VPb = VPb 

mPb 2.5109g   0.228cm3 d Pb 11.342 g cm3

VCu = VPb = 0.228 cm3

mCu = dCu VCu = (8.96 g/cm3)(0.228 cm3) = 2.05 g 1.91

Plan: Find the volume of 4.16 g of Hg using the density. Then find the mass of ethanol using V and d. Solution:

VHg 

mHg d Hg



4.16g  0.307cm 3 g 13.56 cm 3

Vethanol = VHg = 0.307 cm3

Methanol = dethanol Vethanol = (0.7892 g/cm3)(0.307 cm3) = 0.242 g 1.92

Plan: Use the diameter of the shot to find the radius; use the radius to find the volume; use density of Al and volume to find the mass of each shot; find the number of shot using mass of shot and the mass of the soldier. Convert units along the way. Solution: rshot = diameter/2 =

(

)(

) = 0.236 cm

(

Vshot =

1.93

)

mshot = d V = (2.7 )( mkg = (mshot ) (number of shot)

10-2 cm3) = 0.15 g

number of shot =

= 1.2 x 106 shot

accept 1 million as nearest whole number

Plan: Use mass and density to find volume; use volume of the sphere to find radius; use radius to find diameter Solution: -

√

√ (

)

= 8.5 x 10-2 cm

Diameter = 2 r = 2 (8.5 x 10-2 cm) = 0.17 cm

CHAPTER 2 THE COMPONENTS OF MATTER TOOL OF THE LABORATORY BOXED READING PROBLEMS B2.1

Plan: There is one peak for each type of Cl atom and peaks for the Cl 2 molecule. The m/e ratio equals the mass divided by 1+. Solution: a) There is one peak for the 35Cl atom and another peak for the 37Cl atom. There are three peaks for the three possible Cl2 molecules: 35Cl35Cl (both atoms are mass 35), 37Cl37Cl (both atoms are mass 37), and 35Cl37Cl (one atom is mass 35 and one is mass 37). So the mass of chlorine will have 5 peaks. b) Peak m/e ratio 35 Cl 35 lightest particle 37 Cl 37 35 35 Cl Cl 70 (35 + 35) 35 37 Cl Cl 72 (35 + 37) 37 37 Cl Cl 74 (35 + 37) heaviest particle

B2.2

Plan: Each peak in the mass spectrum of carbon represents a different isotope of carbon. The heights of the peaks correspond to the natural abundances of the isotopes. Solution: Carbon has three naturally occurring isotopes: 12C, 13C, and 14C. 12C has an abundance of 98.89% and would have the tallest peak in the mass spectrum as the most abundant isotope. 13C has an abundance of 1.11% and thus would have a significantly shorter peak; the shortest peak in the mass spectrum would correspond to the least abundant isotope, 14C, the abundance of which is less than 0.01%. Peak Y, as the tallest peak, has a m/e ratio of 12 (12C); X, the shortest peak, has a m/e ratio of 14(14C). Peak Z corresponds to 13C with a m/e ratio of 13.

B2.3

Plan: Review the discussion on separations. Solution: a) Salt dissolves in water and pepper does not. Procedure: add water to mixture and filter to remove solid pepper. Evaporate water to recover solid salt. b) The water/soot mixture can be filtered; the water will flow through the filter paper, leaving the soot collected on the filter paper. c) Allow the mixture to warm up, and then pour off the melted ice (water); or, add water, and the glass will sink and the ice will float. d) Heat the mixture; the alcohol will boil off (distill), while the sugar will remain behind. e) The spinach leaves can be extracted with a solvent that dissolves the pigments. Chromatography can be used to separate one pigment from the other.

END–OF–CHAPTER PROBLEMS 2.1

Plan: Refer to the definitions of an element and a compound. Solution: Unlike compounds, elements cannot be broken down by chemical changes into simpler materials. Compounds contain different types of atoms; there is only one type of atom in an element.

2.2

Plan: Refer to the definitions of a compound and a mixture. Solution: 1) A compound has constant composition but a mixture has variable composition. 2) A compound has distinctly different properties than its component elements; the components in a mixture retain their individual properties.

2.3

Plan: Recall that a substance has a fixed composition. Solution: a) The fixed mass ratio means it has constant composition, thus, it is a pure substance (compound). b) All the atoms are identical, thus, it is a pure substance (element). c) The composition can vary, thus, this is an impure substance (a mixture). d) The specific arrangement of different atoms means it has constant composition, thus, it is a pure substance (compound).

2.4

Plan: Remember that an element contains only one kind of atom while a compound contains at least two different elements (two kinds of atoms) in a fixed ratio. A mixture contains at least two different substances in a composition that can vary. Solution: a) The presence of more than one element (calcium and chlorine) makes this pure substance a compound. b) There are only atoms from one element, sulfur, so this pure substance is an element. c) This is a combination of two compounds and has a varying composition, so this is a mixture. d) The presence of more than one type of atom means it cannot be an element. The specific, not variable, arrangement means it is a compound.

2.5

Some elements, such as the noble gases (He, Ne, Ar, etc.) occur as individual atoms. Many other elements, such as O2, N2, S8, P4, C60 etc. which are also known as elementary substances, occur as molecules. Metals often form networks or arrays.

2.6

Compounds contain atoms from two or more elements, thus the smallest unit must contain at least a pair of atoms in a molecule.

2.7

Mixtures have variable composition; therefore, the amounts may vary. Compounds, as pure substances, have constant composition so their composition cannot vary.

2.8

The tap water must be a mixture, since it consists of some unknown (and almost certainly variable) amount of dissolved substance in solution in the water.

2.9

Plan: Recall that an element contains only one kind of atom; the atoms in an element may occur as molecules. A compound contains two kinds of atoms (different elements). Solution: a) This scene has 3 atoms of an element, 2 molecules of one compound (with one atom each of two different elements), and 2 molecules of a second compound (with 2 atoms of one element and one atom of a second element). b) This scene has 2 atoms of one element, 2 molecules of a diatomic element, and 2 molecules of a compound (with one atom each of two different elements). c) This scene has 2 molecules composed of 3 atoms of one element and 3 diatomic molecules of the same element.

2.10

Plan: Recall that a mixture is composed of two or more substances physically mixed, with a composition that can vary. Solution: The street sample is a mixture. The mass of vitamin C per gram of drug sample can vary. Therefore, if several samples of the drug have the same mass of vitamin C per gram of sample, this is an indication that the samples all have a common source. Samples of the street drugs with varying amounts of vitamin C per gram of sample have different sources. The constant mass ratio of the components indicates mixtures that have the same composition by accident, not of necessity.

2.11

Separation techniques allow mixtures (with varying composition) to be separated into the pure substance components which can then be analyzed by some method. Only when there is a reliable way of determining the composition of a sample, can you determine if the composition is constant.

2.12

Plan: Restate the three laws in your own words. Solution: a) The law of mass conservation applies to all substances — elements, compounds, and mixtures. Matter can neither be created nor destroyed, whether it is an element, compound, or mixture. b) The law of definite composition applies to compounds only, because it refers to a constant, or definite, composition of elements within a compound. c) The law of multiple proportions applies to compounds only, because it refers to the combination of elements to form compounds.

2.13

In ordinary chemical reactions (i.e., those that do not involve nuclear transformations), mass is conserved and the law of mass conservation is still valid.

2.14

Plan: Review the three laws: law of mass conservation, law of definite composition, and law of multiple proportions. Solution: a) Law of Definite Composition — The compound potassium chloride, KCl, is composed of the same elements and same fraction by mass, regardless of its source (Chile or Poland). b) Law of Mass Conservation — The mass of the substances inside the glass bulb did not change during the chemical reaction (formation of magnesium oxide from magnesium and oxygen). c) Law of Multiple Proportions — Two elements, O and As, can combine to form two different compounds that have different proportions of As present.

2.15

Plan: The law of multiple proportions states that two elements can form two different compounds in which the proportions of the elements are different. Solution: Scene B illustrates the law of multiple proportions for compounds of chlorine and oxygen. The law of multiple proportions refers to the different compounds that two elements can form that have different proportions of the elements. Scene B shows that chlorine and oxygen can form both Cl 2O, dichlorine monoxide, and ClO2, chlorine dioxide.

2.16

Plan: Review the definition of percent by mass. Solution: a) No, the mass percent of each element in a compound is fixed. The percentage of Na in the compound NaCl is 39.34% (22.99 u/58.44 u), whether the sample is 0.5000 g or 50.00 g. b) Yes, the mass of each element in a compound depends on the mass of the compound. A 0.5000 g sample of NaCl contains 0.1967 g of Na (39.34% of 0.5000 g), whereas a 50.00 g sample of NaCl contains 19.67 g of Na (39.34% of 50.00 g).

2.17

Generally no, the composition of a compound is determined by the elements used, not their amounts. If too much of one element is used, the excess will remain as unreacted element when the reaction is over.

2.18

Plan: Review the mass laws: law of mass conservation, law of definite composition, and law of multiple proportions. For each experiment, compare the mass values before and after each reaction and examine the ratios of the mass of white compound to the mass of colourless gas. Solution: Experiment 1: mass before reaction = 1.00 g; mass after reaction = 0.64 g + 0.36 g = 1.00 g Experiment 2: mass before reaction = 3.25 g; mass after reaction = 2.08 g + 1.17 g = 3.25 g Both experiments demonstrate the law of mass conservation since the total mass before reaction equals the total mass after reaction. Experiment 1: mass white compound/mass colourless gas = 0.64 g/0.36 g = 1.78 Experiment 2: mass white compound/mass colourless gas = 2.08 g/1.17 g = 1.78 Both Experiments 1 and 2 demonstrate the law of definite composition since the compound has the same composition by mass in each experiment.

2.19

Plan: Review the mass laws: law of mass conservation, law of definite composition, and law of multiple proportions. For each experiment, compare the mass values before and after each reaction and examine the ratios of the mass of reacted copper to the mass of reacted iodine. Solution: Experiment 1: mass before reaction = 1.27 g + 3.50 g = 4.77 g; mass after reaction = 3.81 g + 0.96 g = 4.77 g Experiment 2: mass before reaction = 2.55 g + 3.50 g = 6.05 g; mass after reaction = 5.25 g + 0.80 g = 6.05 g Both experiments demonstrate the law of mass conversation since the total mass before reaction equals the total mass after reaction. Experiment 1: mass of reacted copper = 1.27 g; mass of reacted iodine = 3.50 g – 0.96 g = 2.54 g Mass reacted copper/mass reacted iodine = 1.27 g/2.54 g = 0.50 Experiment 2: mass of reacted copper = 2.55 g – 0.80 g = 1.75 g; mass of reacted iodine = 3.50 g Mass reacted copper/mass reacted iodine = 1.75 g/3.50 g = 0.50 Both Experiments 1 and 2 demonstrate the law of definite composition since the compound has the same composition by mass in each experiment.

2.20

Plan: Fluorite is a mineral containing only calcium and fluorine. The difference between the mass of fluorite and the mass of calcium gives the mass of fluorine. Mass fraction is calculated by dividing the mass of element by the mass of compound (fluorite) and mass percent is obtained by multiplying the mass fraction by 100. Solution: a) Mass (g) of fluorine = mass of fluorite – mass of calcium = 2.76 g – 1.42 g = 1.34 g fluorine mass Ca 1.42 g Ca = b) Mass fraction of Ca = = 0.51449 = 0.514 mass fluorite 2.76 g fluorite mass F 1.34 g F = = 0.48551 = 0.486 mass fluorite 2.76 g fluorite c) Mass percent of Ca = 0.51449 x 100 %= 51.449 %= 51.4% Mass percent of F = 0.48551 x 100 %= 48.551 %= 48.6% Mass fraction of F =

2.21

Plan: Galena is a mineral containing only lead and sulfur. The difference between the mass of galena and the mass of lead gives the mass of sulfur. Mass fraction is calculated by dividing the mass of element by the mass of compound (galena) and mass percent is obtained by multiplying the mass fraction by 100. Solution: a) Mass (g) of sulfur = mass of galena – mass of lead = 2.34 g – 2.03 g = 0.31 g sulfur mass Pb 2.03 g Pb = b) Mass fraction of Pb = = 0.8675214 = 0.868 mass galena 2.34 g galena mass S 0.31 g S = = 0.1324786 = 0.13 mass galena 2.34 g galena c) Mass percent of Pb = (0.8675214)(100%) = 86.752 %= 86.8% Mass percent of S = (0.1324786)(100%) = 13.248 %= 13% Mass fraction of S =

2.22

Plan: Dividing the mass of magnesium by the mass of the oxide gives the ratio. Multiply the mass of the second sample of magnesium oxide by this ratio to determine the mass of magnesium. Solution: a) If 1.25 g of MgO contains 0.754 g of Mg, then the mass ratio (or fraction) of magnesium in the oxide mass Mg 0.754 g Mg = compound is = 0.6032 = 0.603. mass MgO 1.25 g MgO

 0.6032 g Mg  b) Mass (g) of magnesium =  534 g MgO    = 322.109 g = 322 g magnesium  1 g MgO 

2.23

Plan: Dividing the mass of zinc by the mass of the sulfide gives the ratio. Multiply the mass of the second sample of zinc sulfide by this ratio to determine the mass of zinc. Solution: a) If 2.54 g of ZnS contains 1.70 g of Zn, then the mass ratio (or fraction) of zinc in the sulfide compound is mass Zn 1.70 g Zn = = 0.66929 = 0.669. mass ZnS 2.54 g ZnS

 0.66929 kg Zn  b) Mass (kg) of zinc =  3.82 kg ZnS    = 2.5567 kg= 2.56 kg zinc  1 kg ZnS  2.24

Plan: Since copper is a metal and sulfur is a nonmetal, the sample contains 88.39 g Cu and 44.61 g S. Calculate the mass fraction of each element in the sample by dividing the mass of element by the total mass of compound. Multiply the mass of the second sample of compound in grams by the mass fraction of each element to find the mass of each element in that sample. Solution: Mass (g) of compound = 88.39 g copper + 44.61 g sulfur = 133.00 g compound  88.39 g copper  Mass fraction of copper =   = 0.664586  133.00 g compound 

 103 g compound   0.664586 g copper  Mass (g) of copper =  5264 kg compound    1 kg compound   1 g compound     = 3.49838 x 106 g= 3.498 x 106 g copper  44.61 g sulfur  Mass fraction of sulfur =   = 0.335414  133.00 g compound 

 103 g compound   0.335414 g sulfur  Mass (g) of sulfur =  5264 kg compound    1 kg compound   1 g compound     = 1.76562 x 106 g= 1.766 x 106 g sulfur 2.25

Plan: Since cesium is a metal and iodine is a nonmetal, the sample contains 63.94 g Cs and 61.06 g I. Calculate the mass fraction of each element in the sample by dividing the mass of element by the total mass of compound. Multiply the mass of the second sample of compound by the mass fraction of each element to find the mass of each element in that sample. Solution: Mass of compound = 63.94 g cesium + 61.06 g iodine = 125.00 g compound  63.94 g cesium  Mass fraction of cesium =   = 0.51152  125.00 g compound 

 0.51152 g cesium  Mass (g) of cesium =  38.77 g compound    = 19.83163 g= 19.83 g cesium  1 g compound   61.06 g iodine  Mass fraction of iodine =   = 0.48848  125.00 g compound   0.48848 g iodine  Mass (g) of iodine =  38.77 g compound    = 18.9384 g= 18.94 g iodine  1 g compound  2.26

Plan: The law of multiple proportions states that if two elements form two different compounds, the relative amounts of the elements in the two compounds form a whole-number ratio. To illustrate the law we must calculate the mass of one element to one gram of the other element for each compound and then compare this mass for the two compounds. The law states that the ratio of the two masses should be a small whole-number ratio such as 1:2, 3:2, 4:3, etc.

Solution: Compound 1:

47.5 mass % S = 0.90476 = 0.905 52.5 mass % Cl

Compound 2:

31.1 mass % S = 0.451379 = 0.451 68.9 mass % Cl

0.905 = 2.0067 = 2.00:1.00 0.451 Thus, the ratio of the mass of sulfur per gram of chlorine in the two compounds is a small whole-number ratio of 2:1, which agrees with the law of multiple proportions. Ratio:

2.27

63.3 mass % Xe = 1.7248 = 1.72 36.7 mass % F

3.46 = 2.0116 = 2.01:1.00 1.72 Thus, the ratio of the mass of xenon per gram of fluorine in the two compounds is a small whole-number ratio of 2:1, which agrees with the law of multiple proportions.

Ratio:

2.28

Plan: Calculate the mass percent of calcium in dolomite by dividing the mass of calcium by the mass of the sample and multiply by 100. Compare this mass percent to that in fluorite. The compound with the larger mass percent of calcium is the richer source of calcium. Solution: Mass percent calcium =

1.70 g calcium x 100% = 21.767 %= 21.8% Ca 7.81 g dolomite

Fluorite (51.4%) is the richer source of calcium. 2.29

Plan: Determine the mass percent of sulfur in each sample by dividing the grams of sulfur in the sample by the total mass of the sample and multiplying by 100. The coal type with the smallest mass percent of sulfur has the smallest environmental impact. Solution:  11.3 g sulfur  Mass % in Coal A =   100%  = 2.9894 %= 2.99% S (by mass)  378 g sample 

 19.0 g sulfur  Mass % in Coal B =   100%  = 3.8384 %= 3.84% S (by mass)  495 g sample   20.6 g sulfur  Mass % in Coal C =   100%  = 3.0519 %= 3.05% S (by mass)  675 g sample  Coal A has the smallest environmental impact. 2.30

We now know that atoms of one element may change into atoms of another element. We also know that atoms of an element can have different masses (isotopes). Finally, we know that atoms are divisible into smaller particles. Based on the best available information in 1805, Dalton was correct. This model is still useful, since its essence (even if not its exact details) remains true today.

2.31

Plan: This question is based on the law of definite composition. If the compound contains the same types of atoms, they should combine in the same way to give the same mass percentages of each of the elements. Solution: Potassium nitrate is a compound composed of three elements — potassium, nitrogen, and oxygen — in a specific ratio. If the ratio of these elements changed, then the compound would be changed to a different compound, for example, to potassium nitrite, with different physical and chemical properties. Dalton postulated that atoms of an element are identical, regardless of whether that element is found in India or Italy. Dalton also postulated that compounds result from the chemical combination of specific ratios of different elements. Thus, Dalton‘s theory explains why potassium nitrate, a compound comprised of three different elements in a specific ratio, has the same chemical composition regardless of where it is mined or how it is synthesized.

2.32

Plan: Review the discussion of the experiments in this chapter. Solution: Millikan determined the minimum charge on an oil drop and that the minimum charge was equal to the charge on one electron. Using Thomson‘s value for the mass/charge ratio of the electron and the determined value for the charge on one electron, Millikan calculated the mass of an electron (charge/(charge/mass)) to be 9.109x10 –28 g.

2.33

Plan: The charges on the oil droplets should be whole-number multiples of a minimum charge. Determine that minimum charge by dividing the charges by small integers to find the common factor. Solution: –3.204x10–19 C/2 = –1.602x10–19 C –4.806x10–19 C/3 = –1.602x10–19 C –8.010x10–19 C/5 = –1.602x10–19 C –1.442x10–18 C/9 = –1.602x10–19 C The value –1.602x10–19 C is the common factor and is the charge for the electron.

2.34

Thomson‘s ―plum pudding‖ model described the atom as a ―blob‖ of positive charge with tiny electrons embedded in it. The electrons could be easily removed from the atoms when a current was applied and ejected as a stream of ―cathode rays.‖

2.35

Rutherford and co-workers expected that the alpha particles would pass through the foil essentially unaffected, or perhaps slightly deflected or slowed down. The observed results (most passing through straight, a few deflected, a very few at large angles) were partially consistent with expectations, but the large-angle scattering could not be explained by Thomson‘s model. The change was that Rutherford envisioned a small (but massive) positively charged nucleus in the atom, capable of deflecting the alpha particles as observed.

2.36

Plan: Re-examine the definitions of atomic number and the mass number. Solution: The atomic number is the number of protons in the nucleus of an atom. When the atomic number changes, the identity of the element also changes. The mass number is the total number of protons and neutrons in the nucleus of an atom. Since the identity of an element is based on the number of protons and not the number of neutrons, the mass number can vary (by a change in number of neutrons) without changing the identity of the element.

2.37

Plan: Recall that the mass number is the sum of protons and neutrons while the atomic number is the number of protons. Solution: Mass number (protons plus neutrons) – atomic number (protons) = number of neutrons (c).

2.38

The actual masses of the protons, neutrons, and electrons are not whole numbers so their sum is not a whole number.

2.39

Solution: Isotope 36 Ar 38 Ar 40 Ar

Mass Number 36 38 40

# of Protons 18 18 18

# of Neutrons 18 20 22

# of Electrons 18 18 18

2.40

Plan: The superscript is the mass number, the sum of the number of protons and neutrons. Consult the periodic table to get the atomic number (the number of protons). The mass number – the number of protons = the number of neutrons. For atoms, the number of protons and electrons are equal. Solution: Isotope Mass Number # of Protons # of Neutrons # of Electrons 35 Cl 35 17 18 17 37 Cl 37 17 20 17

2.41

are isotopes of oxygen, and 168 O has 16 – 8 = 8 neutrons whereas 178 O has 17 – 8 = 9 neutrons. Same Z value 41 b) 40 18 Ar and 19 K have the same number of neutrons (Ar: 40 – 18 = 22; K: 41 – 19 = 22) but different numbers of protons and electrons (Ar = 18 protons and 18 electrons; K = 19 protons and 19 electrons). Same N value 60 Co and 60 c) 27 28 Ni have different numbers of protons, neutrons, and electrons. Co: 27 protons, 27 electrons, and 60 – 27 = 33 neutrons; Ni: 28 protons, 28 electrons and 60 – 28 = 32 neutrons. However, both have a mass number of 60. Same A value 2.42

Plan: The superscript is the mass number (A), the sum of the number of protons and neutrons; the subscript is the atomic number (Z, number of protons). The mass number – the number of protons = the number of neutrons. For atoms, the number of protons = the number of electrons. Solution: a) ) 31 H and 23 He have different numbers of protons, neutrons, and electrons. H: 1 proton, 1 electron, and 3 – 1 = 2 neutrons; He: 2 protons, 2 electrons, and 3 – 2 = 1 neutron. However, both have a mass number of 3. Same A value b) 146 C and 157 N have the same number of neutrons (C: 14 – 6 = 8; N: 15 – 7 = 8) but different numbers of protons and electrons (C = 6 protons and 6 electrons; N = 7 protons and 7 electrons). Same N value c) 199 F and 189 F have the same number of protons and electrons (9), but different numbers of neutrons. 19 18 19 18 9 F and 9 F are isotopes of oxygen, and 9 F has 19 – 9 = 10 neutrons whereas 9 F has 18 – 9 = 9 neutrons.

Same Z value 2.43

Plan: Combine the particles in the nucleus (protons + neutrons) to give the mass number (superscript, A). The number of protons gives the atomic number (subscript, Z) and identifies the element. Solution: a) A = 18 + 20 = 38; Z = 18; 38 18 Ar b) A = 25 + 30 = 55; Z = 25; 55 25 Mn c) A = 47 + 62 = 109; Z = 47; 109 47 Ag

2.44

Plan: Combine the particles in the nucleus (protons + neutrons) to give the mass number (superscript, A). The number of protons gives the atomic number (subscript, Z) and identifies the element. Solution: a) A = 6 + 7 = 13; Z = 6; 136 C b) A = 40 + 50 = 90; Z = 40; 90 40 Zr 61 Ni c) A = 28 + 33 = 61; Z = 28; 28

2.45

Plan: Determine the number of each type of particle. The superscript is the mass number (A) and the subscript is the atomic number (Z, number of protons). The mass number – the number of protons = the number of neutrons. For atoms, the number of protons = the number of electrons. The protons and neutrons are in the nucleus of the atom. Solution: a) 49 b) 79 c) 115 B 34 Se 22Ti 22 protons 34 protons 5 protons 22 electrons 34 electrons 5 electrons 49 – 22 = 27 neutrons 79 – 34 = 45 neutrons 11 – 5 = 6 neutrons

2.46

Plan: Determine the number of each type of particle. The superscript is the mass number (A) and the subscript is the atomic number (Z, number of protons). The mass number – the number of protons = the number of neutrons. For atoms, the number of protons = the number of electrons. The protons and neutrons are in the nucleus of the atom. Solution: a) 207 b) 94 Be c) 75 82 Pb 33 As 82 protons 4 protons 33 protons 82 electrons 4 electrons 33 electrons 207 – 82 = 125 neutrons 9 – 4 = 5 neutrons 75 – 33 = 42 neutrons

2.47

82e

4e

33e

82p+ 125n0

4p+ 5n0

33p+ 42n0

Plan: To calculate the atomic mass of an element, take a weighted average based on the natural abundance of the isotopes: (isotopic mass of isotope 1 x fractional abundance) + (isotopic mass of isotope 2 x fractional abundance). Solution:  60.11%   39.89%    70.9247 u   Atomic mass of gallium =  68.9256 u     = 69.7230 u= 69.72 u  100%   100% 

2.48

Plan: To calculate the atomic mass of an element, take a weighted average based on the natural abundance of the isotopes: (isotopic mass of isotope 1 x fractional abundance) + (isotopic mass of isotope 2 x fractional abundance) + (isotopic mass of isotope 3 x fractional abundance). Solution:  78.99%   10.00%   11.01%  Atomic mass of Mg =  23.9850 u      24.9858 u   100%    25.9826 u   100%  100%       = 24.3050 u= 24.31 u

2.49

Plan: To find the percent abundance of each Cl isotope, let x equal the fractional abundance of 35Cl and (1 – x) equal the fractional abundance of 37Cl since the sum of the fractional abundances must equal 1. Remember that atomic mass = (isotopic mass of 35Cl x fractional abundance) + (isotopic mass of 37Cl x fractional abundance). Solution: Atomic mass = (isotopic mass of 35Cl x fractional abundance) + (isotopic mass of 37Cl x fractional abundance) 35.4527 u = 34.9689 u(x) + 36.9659 u(1 – x) 35.4527 u = 34.9689 u(x) + 36.9659 u – 36.9659 u(x) 35.4527 u = 36.9659 u – 1.9970 u(x) 1.9970 u(x) = 1.5132 u x = 0.75774 and 1 – x = 1 – 0.75774 = 0.24226 % abundance 35Cl = 75.774% % abundance 37Cl = 24.226%

2.50

Plan: To find the percent abundance of each Cu isotope, let x equal the fractional abundance of 63Cu and (1 – x) equal the fractional abundance of 65Cu since the sum of the fractional abundances must equal 1. Remember that atomic mass = (isotopic mass of 63Cu x fractional abundance) + (isotopic mass of 65Cu x fractional abundance). Solution: Atomic mass = (isotopic mass of 63Cu x fractional abundance) + (isotopic mass of 65Cu x fractional abundance) 63.546 u = 62.9396 u(x) + 64.9278 u(1 – x) 63.546 u = 62.9396 u(x) + 64.9278 u – 64.9278 u(x) 63.546 u = 64.9278 u – 1.9882 u(x) 1.9882 u(x) = 1.3818 u x = 0.69500 and 1 – x = 1 – 0.69500 = 0.30500 % abundance 63Cu = 69.50% % abundance 65Cu = 30.50%

2.51

Iodine has more protons in its nucleus (higher Z), but iodine atoms must have, on average, fewer neutrons than Te atoms and thus a lower atomic mass.

2.52

Plan: Review the section in the chapter on the periodic table. Solution: a) In the modern periodic table, the elements are arranged in order of increasing atomic number. b) Elements in a column or group (or family) have similar chemical properties, not those in the same period or row. c) Elements can be classified as metals, metalloids, or nonmetals.

2.53

The metalloids lie along the ―staircase‖ line, with properties intermediate between metals and nonmetals.

2.54

Plan: Review the section on the classification of elements as metals, nonmetals, or metalloids. Solution: To the left of the ―staircase‖ are the metals, which are generally hard, shiny, malleable, ductile, good conductors of heat and electricity, and form positive ions by losing electrons. To the right of the ―staircase‖ are the nonmetals, which are generally soft or gaseous, brittle, dull, poor conductors of heat and electricity, and form negative ions by gaining electrons.

2.55

Plan: Review the properties of these two columns in the periodic table. Solution: The alkali metals (Group 1) are metals and readily lose one electron to form cations whereas the halogens (Group 17) are nonmetals and readily gain one electron to form anions.

2.56

Plan: Locate each element on the periodic table. The Z value is the atomic number of the element. Metals are to the left of the ―staircase,‖ nonmetals are to the right of the ―staircase,‖ and the metalloids are the elements that lie along the ―staircase‖ line. Solution:

Element Name Germanium Phosphorus Helium Lithium Molybdenum

2.57

Element Symbol Ge P He Li Mo

Group Number 14 15 18 1 6

Element Type Metalloid non-metal non-metal metal metal

Element Name Arsenic Calcium Bromine Potassium aluminum

Element Symbol As Ca Br K Al

Group Number 15 2 17 1 13

Element Type Metalloid metal non-metal metal metal

2.58

Plan: Review the section in the chapter on the periodic table. Remember that alkaline earth metals are in Group 2, the halogens are in Group 17, and the metalloids are the elements that lie along the ―staircase‖ line; periods are horizontal rows. Solution: a) The symbol and atomic number of the heaviest alkaline earth metal are Ra and 88. b) The symbol and atomic number of the lightest metalloid in Group 14 are Si and 14. c) The symbol and atomic mass of the coinage metal whose atoms have the fewest electrons are Cu and 63.55 u. d) The symbol and atomic mass of the halogen in Period 4 are Br and 79.90 u.

2.59

Plan: Review the section in the chapter on the periodic table. Remember that the noble gases are in Group 18, the alkali metals are in Group 1, and the transition elements are the groups of elements located between Groups 2 and 13; periods are horizontal rows and metals are located to the left of the ―staircase‖ line. Solution: a) The symbol and atomic number of the heaviest nonradioactive noble gas are Xe and 54, respectively. b) The symbol and group number of the Period 5 transition element whose atoms have the fewest protons are Y and 3. c) The symbol and atomic number of the first group 16 element displaying a metallic nature are Po and 84. d) The symbol and number of protons of the Period 4 alkali metal atom are K and 19.

2.60

Plan: Review the section of the chapter on the formation of ionic compounds. Solution: Reactive metals and nometals will form ionic bonds, in which one or more electrons are transferred from the metal atom to the nonmetal atom to form a cation and an anion, respectively. The oppositely charged ions attract, forming the ionic bond.

2.61

Plan: Review the section of the chapter on the formation of covalent compounds. Solution:

Two nonmetals will form covalent bonds, in which the atoms share two or more electrons. 2.62

The total positive charge of the cations is balanced by the total negative charge of the anions.

2.63

Plan: Assign charges to each of the ions. Since the sizes are similar, there are no differences due to the sizes. Solution: Coulomb‘s law states the energy of attraction in an ionic bond is directly proportional to the product of charges and inversely proportional to the distance between charges. The product of charges in MgO (+2 x –2 = –4) is greater than the product of charges in LiF (+1 x –1 = –1). Thus, MgO has stronger ionic bonding.

2.64

There are no molecules; BaF2 is an ionic compound consisting of Ba2+ and F– ions.

2.65

There are no ions present; P and O are both nonmetals, and they will bond covalently to form P 4O6 molecules.

2.66

Plan: Locate these groups on the periodic table and assign charges to the ions that would form. Solution: The monatomic ions of Group 1 have a +1 charge (e.g., Li+, Na+, and K+) whereas the monatomic ions of Group 17 have a –1 charge (e.g., F–, Cl–, and Br –). Elements gain or lose electrons to form ions with the same number of electrons as the nearest noble gas. For example, Na loses one electron to form a cation with the same number of electrons as Ne. The halogen F gains one electron to form an anion with the same number of electrons as Ne.

2.67

Plan: A metal and a nonmetal will form an ionic compound. Locate these elements on the periodic table and predict their charges. Solution: Magnesium chloride (MgCl2) is an ionic compound formed from a metal (magnesium) and a nonmetal (chlorine). Magnesium atoms transfer electrons to chlorine atoms. Each magnesium atom loses two electrons to form a Mg 2+ ion and the same number of electrons (10) as the noble gas neon. Each chlorine atom gains one electron to form a Cl– ion and the same number of electrons (18) as the noble gas argon. The Mg 2+ and Cl– ions attract each other to form an ionic compound with the ratio of one Mg2+ ion to two Cl– ions. The total number of electrons lost by the magnesium atoms equals the total number of electrons gained by the chlorine atoms.

2.68

Plan: A metal and a nonmetal will form an ionic compound. Locate these elements on the periodic table and predict their charges. Solution: Potassium sulfide (K2S) is an ionic compound formed from a metal (potassium) and a nonmetal (sulfur). Potassium atoms transfer electrons to sulfur atoms. Each potassium atom loses one electron to form an ion with +1 charge and the same number of electrons (18) as the noble gas argon. Each sulfur atom gains two electrons to form an ion with a –2 charge and the same number of electrons (18) as the noble gas argon. The oppositely charged ions, K+ and S2–, attract each other to form an ionic compound with the ratio of two K + ions to one S2– ion. The total number of electrons lost by the potassium atoms equals the total number of electrons gained by the sulfur atoms.

2.69

Plan: Recall that ionic bonds occur between metals and nonmetals, whereas covalent bonds occur between nonmetals. Solution: KNO3 shows both ionic and covalent bonding, covalent bonding between the N and O in NO 3– and ionic bonding between the NO3– and the K+.

2.70

Plan: Locate these elements on the periodic table and predict what ions they will form. For cations (metals), ion charge = group number; for anions (nonmetals), ion charge = group number minus 18 . Solution: Potassium (K) is in Group 1 and forms the K+ ion. Iodine (I) is in Group17 and forms the I– ion (17 –18 = –1).

2.71

Plan: Locate these elements on the periodic table and predict what ions they will form. For cations (metals), ion charge = group number; for anions (nonmetals), ion charge = group number minus 18 .

Solution: Barium in Group 2 forms a +2 ion: Ba2+. Selenium in Group 16 forms a –2 ion: Se2– (16 –18 = –2). 2.72

Plan: Use the number of protons (atomic number) to identify the element. Add the number of protons and neutrons together to get the mass number. Locate the element on the periodic table and assign its group and period number. Solution: a) Oxygen (atomic number = 8) mass number = 8p + 9n = 17 Group 16 Period 2 b) Fluorine (atomic number = 9) mass number = 9p + 10n = 19 Group 17 Period 2 c) Calcium (atomic number = 20) mass number = 20p + 20n = 40 Group 2 Period 4

2.73

Plan: Use the number of protons (atomic number) to identify the element. Add the number of protons and neutrons together to get the mass number. Locate the element on the periodic table and assign its group and period number. Solution: a) Bromine (atomic number = 35) mass number = 35p + 44n = 79 Group 17 Period 4 b) Nitrogen (atomic number = 7) mass number = 7p + 8n = 15 Group 15 Period 2 c) Rubidium (atomic number = 37) mass number = 37p + 48n = 85 Group 1 Period 5

2.74

Plan: Determine the charges of the ions based on their position on the periodic table. For cations (metals), ion charge = group number; for anions (nonmetals), ion charge = group number minus 18. Next, determine the ratio of the charges to get the ratio of the ions. Solution: Lithium [Group 1] forms the Li + ion; oxygen [Group 16] forms the O2– ion (16 -18 = –2). The ionic compound that forms from the combination of these two ions must be electrically neutral, so two Li + ions combine with one O2– ion to form the compound Li2O. There are twice as many Li+ ions as O2– ions in a sample of Li2O.  1 O2 ion  Number of O2– ions = (8.4x1021 Li  ions)  = 4.2x1021 O2– ions  2 Li  ions   

2.75

Plan: Determine the charges of the ions based on their position on the periodic table. For cations (metals), ion charge = group number; for anions (nonmetals), ion charge = group number minus 18. Next, determine the ratio of the charges to get the ratio of the ions. Solution: Ca [Group 2] forms Ca2+ and I [Group 17] forms I– ions (17 -18 = –1). The ionic compound that forms from the combination of these two ions must be electrically neutral, so one Ca 2+ ion combines with two I– ions to form the compound CaI2. There are twice as many I– ions as Ca2+ ions in a sample of CaI2.  2 I  ions  Number of I– ions = (7.4x1021 Ca 2 ions)  = 1.48x1022 ions= 1.5x1022 I– ions  1 Ca 2 ion   

2.76

Plan: The key is the size of the two alkali metal ions. The charges on the sodium and potassium ions are the same as both are in Group 1, so there will be no difference due to the charge. The chloride ions are the same in size and charge, so there will be no difference due to the chloride ion. Solution: Coulomb‘s law states that the energy of attraction in an ionic bond is directly proportional to the product of charges and inversely proportional to the distance between charges. The product of the charges is the same in both compounds because both sodium and potassium ions have a +1 charge. Attraction increases as distance decreases, so the ion with the smaller radius, Na+, will form a stronger ionic interaction (NaCl).

2.77

Plan: The key is the charge of the two metal ions. The sizes of the lithium and magnesium ions are about the same (magnesium is slightly smaller), so there will be little difference due to ion size. The oxide ions are the same in size and charge, so there will be no difference due to the oxide ion. Solution:

Coulomb‘s law states the energy of attraction in an ionic bond is directly proportional to the product of charges and inversely proportional to the distance between charges. The product of charges in MgO (+2 x –2 = –4) is greater than the product of charges in Li2O (+1 x –2 = –2). Thus, MgO has stronger ionic bonding. 2.78

Plan: Review the definition of molecular formula. Solution: The subscripts in the formula, MgF2, give the number of ions in a formula unit of the ionic compound. The subscripts indicate that there are two F– ions for every one Mg2+ ion. Using this information and the mass of each element, we could calculate the percent mass of each element.

2.79

Plan: Review the definitions of molecular and structural formulas. Solution: Both the structural and molecular formulas show the actual numbers of the atoms of the molecule; in addition, the structural formula shows the arrangement of the atoms (i.e., how the atoms are connected to each other).

2.80

Plan: Review the concepts of atoms and molecules. Solution: The mixture is similar to the sample of hydrogen peroxide in that both contain 20 billion oxygen atoms and 20 billion hydrogen atoms since both O2 and H2O2 contain 2 oxygen atoms per molecule and both H2 and H2O2 contain 2 hydrogen atoms per molecule. They differ in that they contain different types of molecules: H 2O2 molecules in the hydrogen peroxide sample and H2 and O2 molecules in the mixture. In addition, the mixture contains 20 billion molecules (10 billion H2 molecules + 10 billion O2 molecules) while the hydrogen peroxide sample contains 10 billion molecules.

2.81

Plan: Review the rules for naming compounds. Solution: Roman numerals are used when naming ionic compounds that contain a metal that can form more than one ion. This is generally true for the transition metals, but it can be true for some non-transition metals as well (e.g., Sn).

2.82

Plan: Review the rules for naming compounds. Solution: Greek prefixes are used only in naming covalent compounds.

2.83

Molecular formulas cannot be written for ionic compounds since they only have ions and there are no molecules.

2.84

Plan: Locate each of the individual elements on the periodic table, and assign charges to each of the ions. For main group cations (metals), ion charge = group number; for anions (nonmetals), ion charge = group number minus 18. Find the smallest number of each ion that gives a neutral compound. To name ionic compounds with metals that form only one ion, name the metal, followed by the nonmetal name with an -ide suffix. Solution: a) Sodium is a metal that forms a +1 (Group 1) ion and nitrogen is a nonmetal that forms a –3 ion (Group 15, 15-18 = –3). +3 –3 +1 –3 +1 Na N Na3N The compound is Na3N, sodium nitride. b) Oxygen is a nonmetal that forms a –2 ion (Group 16, 16 -18 = –2) and strontium is a metal that forms a +2 ion (Group 2). +2 –2 Sr O The compound is SrO, strontium oxide. c) Aluminum is a metal that forms a +3 ion (Group 3) and chlorine is a nonmetal that forms a –1 ion (Group 17, 17-18 = –1). +3 –3 +3 –1 +3 –1 Al Cl AlCl 3 The compound is AlCl3, aluminum chloride.

2.85

Plan: Locate each of the individual elements on the periodic table, and assign charges to each of the ions.

For main group cations (metals), ion charge = group number; for anions (nonmetals), ion charge = group number minus 18. Find the smallest number of each ion that gives a neutral compound. To name ionic compounds with metals that form only one ion, name the metal, followed by the nonmetal name with an -ide suffix. Solution: a) Cesium is a metal that forms a +1 (Group 1) ion and bromine is a nonmetal that forms a –1 ion (Group 17, 17 -18 = –1). +1 –1 Cs Br The compound is CsBr, cesium bromide. b) Sulfur is a nonmetal that forms a –2 ion (Group 16, 16-18 = –2) and barium is a metal that forms a +2 ion (Group 2). +2 –2 Ba S The compound is BaS, barium sulfide. c) Fluorine is a nonmetal that forms a –1 ion (Group 17, 17-18 = –1) and calcium is a metal that forms a +2 ion (Group 2). –2 +2 –1 +2 –1 Ca F CaF2 The compound is CaF2, calcium fluoride. 2.86

Plan: Based on the atomic numbers (the subscripts) locate the elements on the periodic table. Once the atomic numbers are located, identify the element and based on its position, assign a charge. For cations (metals), ion charge = group number; for anions (nonmetals), ion charge = group number minus 18. Find the smallest number of each ion that gives a neutral compound. To name ionic compounds with metals that form only one ion, name the metal, followed by the nonmetal name with an -ide suffix. Solution: a) 12L is the element Mg (Z = 12). Magnesium [Group 2] forms the Mg2+ ion. 9M is the element F (Z = 9). Fluorine [Group 17] forms the F– ion (17-18 = –1). The compound formed by the combination of these two elements is MgF2, magnesium fluoride. b) 30L is the element Zn (Z = 30). Zinc forms the Zn2+ ion (see Table 2.3). 16M is the element S (Z = 16). Sulfur [Group 16] will form the S2– ion (16-18 = –2). The compound formed by the combination of these two elements is ZnS, zinc sulfide. c) 17L is the element Cl (Z = 17). Chlorine [Group 17] forms the Cl– ion (17-18 = –1). 38M is the element Sr (Z = 38). Strontium [Group 2] forms the Sr 2+ ion. The compound formed by the combination of these two elements is SrCl2, strontium chloride.

2.87

Plan: Based on the atomic numbers (the subscripts) locate the elements on the periodic table. Once the atomic numbers are located, identify the element and based on its position, assign a charge. For (metals), ion charge = group number; for anions (nonmetals), ion charge = group number minus 18. Find the smallest number of each ion that gives a neutral compound. To name ionic compounds with metals that form only one ion, name the metal, followed by the nonmetal name with an -ide suffix. Solution: a) 37Q is the element Rb (Z = 37). Rubidium [Group 1] forms the Rb + ion. 35R is the element Br (Z = 35). Bromine [Group 17] forms the Br– ion (17-18 = –1). The compound formed by the combination of these two elements is RbBr, rubidium bromide. b) 8Q is the O (Z = 8). Oxygen [Group 16] will form the O2– ion (16 –-18 = –2). 13R is the element Al (Z = 13). Aluminum [Group13) forms the Al3+ ion. The compound formed by the combination of these two elements is Al2O3, aluminum oxide. c) 20Q is the element Ca (Z = 20). Calcium [Group 2] forms the Ca2+ ion. 53R is the element I (Z = 53). Iodine [Group 17] forms the I– ion (17 –18 = –1). The compound formed by the combination of these two elements is CaI2, calcium iodide.

2.88

b) FeBr3 = iron(III) bromide (common name is ferric bromide); the charge on the iron ion is +3 to match the –3 charge of 3 Br– ions. The +3 charge of the Fe is indicated by (III). c) cuprous bromide = CuBr (cuprous is +1 copper ion, cupric is +2 copper ion). +3 –2 d) Mn2O3 = manganese(III) oxide Use (III) to indicate the +3 ionic charge of Mn: Mn2O3 +6 –6 2.89 Plan: Review the rules for nomenclature covered in the chapter. For ionic compounds containing polyatomic ions, name the metal, followed by the name of the polyatomic ion. Hydrates, compounds with a specific number of water molecules associated with them, are named with a prefix before the word hydrate to indicate the number of water molecules. Solution: a) Na2HPO4 = sodium hydrogen phosphate Sodium [Group 1] forms the Na+ ion; HPO42– is the hydrogen phosphate ion. b) potassium carbonate dihydrate = K2CO3•2H2O Potassium [Group 1] forms the K+ ion; carbonate is the CO32– ion. Two K+ ions are required to match the –2 charge of the carbonate ion. Dihydrate indicates two water molecules (―waters of hydration‖) that are written after a centered dot. c) NaNO2 = sodium nitrite Sodium [Group 1] forms the Na + ion; NO2– is the nitrite polyatomic ion. d) ammonium perchlorate = NH4ClO4 Ammonium is the polyatomic ion NH4+ and perchlorate is the polyatomic ion ClO4–. One NH4+ is required for every one ClO4– ion. 2.90

Plan: Review the rules for nomenclature covered in the chapter. For ionic compounds, name the metal, followed by the nonmetal name with an -ide suffix. For metals, like many transition metals, that can form more than one ion each with a different charge, the ionic charge of the metal ion is indicated by a Roman numeral within parentheses immediately following the metal‘s name. Hydrates, compounds with a specific number of water molecules associated with them, are named with a prefix before the word hydrate to indicate the number of water molecules. Solution: a) cobalt(II) oxide Cobalt forms more than one monatomic ion so the ionic charge must be indicated with a Roman numeral. Since the Co is paired with one O2– ion, the charge of Co is +2. b) Hg2Cl2 The Roman numeral I indicates that mercury has an ionic charge of +1; mercury is an unusual case in which the +1 ion formed is Hg22+, not Hg+. c) lead(II) acetate trihydrate The C2H3O2– ion has a –1 charge (see Table 2.5); since there are two of these ions, the lead ion has a +2 charge which must be indicated with the Roman numeral II. The •3H2O indicates a hydrate in which the number of H2O molecules is indicated by the prefix tri-. +3 –2 d) Cr2O3 ―chromic‖ denotes a +3 charge (see Table 2.4), oxygen has a –2 charge: CrO → Cr2O3 +6 –6

2.91

Plan: Review the rules for nomenclature covered in the chapter. For ionic compounds containing polyatomic ions, name the metal, followed by the name of the polyatomic ion. For metals, like many transition metals, that can form more than one ion each with a different charge, the ionic charge of the metal ion is indicated by a Roman numeral within parentheses immediately following the metal‘s name. Solution: a) tin(IV) sulfite Tin forms more than one monatomic ion so the ionic charge must be indicated with a Roman numeral. Each SO32– polyatomic ion has a charge of –2, so the ionic charge of tin is +4. b) K2Cr2O7 Dichromate is the polyatomic ion Cr2O72–; two K+ ions are required for a neutral compound. c) iron(II) carbonate Iron forms more than one monatomic ion so the ionic charge must be indicated with a Roman numeral. The CO32– polyatomic ion has a charge of –2, so the ionic charge of iron is +2. d) Cu(NO3)2 The Roman numeral II indicates that copper has an ionic charge of +2; two NO 3– polyatomic ions are required for a neutral compound.

2.92

Plan: Review the rules for nomenclature covered in the chapter. For metals, like many transition metals, that can form more than one ion each with a different charge, the ionic charge of the metal ion is indicated by a Roman numeral within parentheses immediately following the metal‘s name. Compounds must be neutral. Solution: a) Barium [Group 2] forms Ba2+ and oxygen [Group 16] forms O2– (16 -18 = –2) so the neutral compound forms from one Ba2+ ion and one O2– ion. Correct formula is BaO. b) Iron(II) indicates Fe2+ and nitrate is NO3– so the neutral compound forms from one iron(II) ion and two nitrate ions. Correct formula is Fe(NO3)2.

c) Mn is the symbol for manganese. Mg is the correct symbol for magnesium. Correct formula is MgS. Sulfide is the S2– ion and sulfite is the SO32– ion. 2.93

Plan: Review the rules for nomenclature covered in the chapter. For metals, like many transition metals, that can form more than one ion each with a different charge, the ionic charge of the metal ion is indicated by a Roman numeral within parentheses immediately following the metal‘s name. Compounds must be neutral. Solution: a) copper(I) iodide Cu is copper, not cobalt; since iodide is I–, this must be copper(I). b) iron(III) hydrogen sulfate HSO4– is hydrogen sulfate, and this must be iron(III) to be neutral. c) magnesium dichromate Mg forms Mg2+ and Cr2O72– is named dichromate ion.

2.94

Plan: Acids donate H+ ion to the solution, so the acid is a combination of H + and a negatively charged ion. Binary acids (H plus one other nonmetal) are named hydro- + nonmetal root + -ic acid. Oxoacids (H + an oxoanion) are named by changing the suffix of the oxoanion: -ate becomes -ic acid and -ite becomes -ous acid. Solution: a) Hydrogen sulfate is HSO4–, so its source acid is H2SO4. Name of acid is sulfuric acid (-ate becomes -ic acid). b) HIO3, iodic acid IO3– is the iodate ion: -ate becomes -ic acid. c) Cyanide is CN– ; its source acid is HCN hydrocyanic acid (binary acid). d) H2S, hydrosulfuric acid (binary acid).

2.95

Plan: Acids donate H+ ion to the solution, so the acid is a combination of H + and a negatively charged ion. Binary acids (H plus one other nonmetal) are named hydro- + nonmetal root + -ic acid. Oxoacids (H + an oxoanion) are named by changing the suffix of the oxoanion: -ate becomes -ic acid and -ite becomes -ous acid. Solution: a) Perchlorate is ClO4–, so the source acid is HClO4. Name of acid is perchloric acid (-ate becomes -ic acid). b) nitric acid, HNO3 NO3– is the nitrate ion: -ate becomes -ic acid. c) Bromite is BrO2–, so the source acid is HBrO2. Name of acid is bromous acid (-ite becomes -ous acid). d) hydrofluoric acid, HF (binary acid)

2.96

Plan: Use the formulas of the polyatomic ions. Recall that oxoacids are named by changing the suffix of the oxoanion: -ate becomes -ic acid and -ite becomes -ous acid. Compounds must be neutral. Solution: a) ammonium ion = NH4+ ammonia = NH3 b) magnesium sulfide = MgS magnesium sulfite = MgSO3 magnesium sulfate = MgSO4 Sulfide = S2–; sulfite = SO32–; sulfate = SO42–. c) hydrochloric acid = HCl chloric acid = HClO3 chlorous acid = HClO2 Binary acids (H plus one other nonmetal) are named hydro- + nonmetal root + -ic acid. Chloric indicates the polyatomic ion ClO3– while chlorous indicates the polyatomic ion ClO2–. d) cuprous bromide = CuBr cupric bromide = CuBr2 The suffix -ous indicates the lower charge, +1, while the suffix -ic indicates the higher charge, +2.

2.97

Plan: Use the formulas of the polyatomic ions. For metals, like many transition metals, that can form more than one ion each with a different charge, the ionic charge of the metal ion is indicated by a Roman numeral within parentheses immediately following the metal‘s name. Compounds must be neutral. Solution: a) lead(II) oxide = PbO lead(IV) oxide = PbO2 Lead(II) indicates Pb2+ while lead(IV) indicates Pb4+. b) lithium nitride = Li3N lithium nitrite = LiNO2 lithium nitrate = LiNO3 Nitride = N3–; nitrite = NO2–; nitrate = NO3–. c) strontium hydride = SrH2 strontium hydroxide = Sr(OH)2 Hydride = H–; hydroxide = OH–. d) magnesium oxide = MgO manganese(II) oxide = MnO

2.98

Plan: This compound is composed of two nonmetals. The element with the lower group number is named first. Greek numerical prefixes are used to indicate the number of atoms of each element in the compound. Solution:

disulfur tetrafluoride

S2F4

Di- indicates two S atoms and tetra- indicates four F atoms.

2.99

Plan: This compound is composed of two nonmetals. When a compound contains oxygen and a halogen, the halogen is named first. Greek numerical prefixes are used to indicate the number of atoms of each element in the compound. Solution: dichlorine monoxide Cl2O Di- indicates two Cl atoms and mono- indicates one O atom.

2.100

Plan: Review the nomenclature rules in the chapter. For ionic compounds, name the metal, followed by the nonmetal name with an -ide suffix. For metals, like many transition metals, that can form more than one ion each with a different charge, the ionic charge of the metal ion is indicated by a Roman numeral within parentheses immediately following the metal‘s name. Binary acids (H plus one other nonmetal) are named hydro- + nonmetal root + -ic acid. Solution: a) Calcium(II) dichloride, CaCl2: The name becomes calcium chloride because calcium does not require ―(II)‖ since it only forms +2 ions. Prefixes like di- are only used in naming covalent compounds between nonmetal elements. b) Copper(II) oxide, Cu2O: The charge on the oxide ion is O2–, which makes each copper a Cu+. The name becomes copper(I) oxide to match the charge on the copper. c) Stannous fluoride, SnF4: Stannous refers to Sn2+, but the tin in this compound is Sn4+ due to the charge on the fluoride ion. The tin(IV) ion is the stannic ion; this gives the name stannic fluoride or tin(IV) fluoride. d) Hydrogen chloride acid, HCl: Binary acids consist of the root name of the nonmetal (chlor in this case) with a hydro- prefix and an -ic suffix. The word acid is also needed. This gives the name hydrochloric acid.

2.101

Plan: Review the nomenclature rules in the chapter. For ionic compounds, name the metal, followed by the nonmetal name with an -ide suffix. For metals, like many transition metals, that can form more than one ion each with a different charge, the ionic charge of the metal ion is indicated by a Roman numeral within parentheses immediately following the metal‘s name. Oxoacids (H + an oxoanion) are named by changing the suffix of the oxoanion: -ate becomes -ic acid and -ite becomes -ous acid. Greek numerical prefixes are used to indicate the number of atoms of each element in a compound composed of two nonmetals. Solution: a) Iron(III) oxide, Fe3O4: Iron(III) is Fe3+, which combines with O2– to give Fe2O3. b) Chloric acid, HCl: HCl is hydrochloric acid. Chloric acid includes oxygen, and has the formula HClO3. c) Mercuric oxide, Hg2O: The compound shown is mercurous oxide. Mercuric oxide contains Hg 2+, which combines with O2– to give HgO. d) Dichlorine heptoxide, Cl2O6: Heptoxide refers to seven, not six, oxygen atoms. The formula should be Cl2O7.

2.102

Plan: Break down each formula to the individual elements and count the number of atoms of each element by observing the subscripts. The molecular (formula) mass is the sum of the atomic masses of all of the atoms. Solution: a) There are 12 atoms of oxygen in Al2(SO4)3. The molecular mass is: Al = 2(26.98 u) = 53.96 u S = 3(32.07 u) = 96.21 u O = 12(16.00 u) = 192.0 u 342.2 u b) There are 9 atoms of hydrogen in (NH4)2HPO4. The molecular mass is: N = 2(14.01 u) = 28.02 u H = 9(1.008 u) = 9.072 u P = 1(30.97u) = 30.97 u O = 4(16.00 u) = 64.00 u 132.06 u c) There are 8 atoms of oxygen in Cu3(OH)2(CO3)2. The molecular mass is: Cu = 3(63.55 u) = 190.6 u O = 8(16.00 u) = 128.0 u H = 2(1.008 u) = 2.016 u C = 2(12.01 u) = 24.02 u

2.103

344.6 u Plan: Break down each formula to the individual elements and count the number of atoms of each element by observing the subscripts. The molecular (formula) mass is the sum of the atomic masses of all of the atoms. Solution: a) There are 9 atoms of hydrogen in C6H5COONH4. The molecular mass is: C = 7(12.01 u) = 84.07 u H = 9(1.008 u) = 9.072 u O = 2(16.00 u) = 32.00 u N = 1(14.01 u) = 14.01 u 139.15 u b) There are 2 atoms of nitrogen in N2H6SO4. The molecular mass is: N = 2(14.01 u) = 28.02 u H = 6(1.008 u) = 6.048 u S = 1(32.07 u) = 32.07 u O = 4(16.00 u) = 64.00 u 130.14 u c) There are 12 atoms of oxygen in Pb4SO4(CO3)2(OH)2. The molecular mass is: Pb = 4(207.2 u) = 828.8 u S = 1(32.07 u) = 32.07 u O = 12(16.00 u) = 192.00 u C = 2(12.01 u) = 24.02 u H = 2(1.008 u) = 2.016 u 1078.9 u

2.104

Plan: Review the rules for nomenclature covered in the chapter. For ionic compounds containing polyatomic ions, name the metal, followed by the name of the polyatomic ion. The molecular (formula) mass is the sum of the atomic masses of all of the atoms. Solution: a) (NH4)2SO4 ammonium is NH4+ and sulfate is SO42– N = 2(14.01 u) = 28.02 u H = 8(1.008 u) = 8.064 u S = 1(32.07 u) = 32.07 u O = 4(16.00 u) = 64.00 u 132.15 u b) NaH2PO4 sodium is Na+ and dihydrogen phosphate is H2PO4– Na = 1(22.99 u) = 22.99 u H = 2(1.008 u) = 2.016 u P = 1(30.97 u) = 30.97 u O = 4(16.00 u) = 64.00 u 119.98 u c) KHCO3 potassium is K+ and bicarbonate is HCO3– K = 1(39.10 u) = 39.10 u H = 1(1.008 u) = 1.008 u C = 1(12.01 u) = 12.01 u O = 3(16.00 u) = 48.00 u 100.12 u

2.105

b) NH4ClO4 N H Cl O

= = = =

c) Mg(NO2)2•3H2O Mg = N = H = O =

ammonium is NH4+ and perchlorate is ClO4– 1(14.01 u) = 14.01 u 4(1.008 u) = 4.032 u 1(35.45 u) = 35.45 u 4(16.00 u) = 64.00 u 117.49 u magnesium is Mg2+, nitrite is NO2–, and trihydrate is 3H2O 1(24.31 u) = 24.31 u 2(14.01 u) = 28.02 u 6(1.008 u) = 6.048 u 7(16.00 u) = 112.00 u 170.38 u

2.106

Plan: Convert the names to the appropriate chemical formulas. The molecular (formula) mass is the sum of the masses of each atom times its atomic mass. Solution: a) dinitrogen pentoxide N2O5 (di- = 2 and penta- = 5) N = 2(14.01 u) = 28.02 u O = 5(16.00 u) = 80.00 u 108.02 u b) lead(II) nitrate Pb(NO 3)2 (lead(II) is Pb2+ and nitrate is NO3–) Pb = 1(207.2 u) = 207.2 u N = 2(14.01 u) = 28.02 u O = 6(16.00 u) = 96.00 u 331.2 u c) calcium peroxide CaO2 (calcium is Ca2+ and peroxide is O22–) Ca = 1(40.08 u) = 40.08 u O = 2(16.00 u) = 32.00 u 72.08 u

2.107

Plan: Convert the names to the appropriate chemical formulas. The molecular (formula) mass is the sum of the masses of each atom times its atomic mass. Solution: a) iron(II) acetate tetrahydrate Fe(C2H3O2)2 •4H2O (iron(II) is Fe2+, acetate is C2H3O2–, and tetrahydrate is 4H2O) Fe = 1(55.85 u) = 55.85 u C = 4(12.01 u) = 48.04 u H = 14(1.008 u) = 14.112 u O = 8(16.00 u) = 128.00 u 246.00 u b) sulfur tetrachloride SCl4 (tetra- = 4) S = 1 (32.07 u) = 32.07 u Cl = 4(35.45 u) = 141.80 u 173.87 u c) potassium permanganate KMnO4 (potassium is K+ and permanganate is MnO4–) K = 1(39.10 u) = 39.10 u Mn = 1(54.94 u) = 54.94 u O = 4(16.00 u) = 64.00 u 158.04 u

2.108

Solution: a) Formula is SO3. Name is sulfur trioxide (the prefix triindicates 3 oxygen atoms). S = 1(32.07 u) = 32.07 u O = 3(16.00 u) = 48.00 u 80.07 u b) Formula is C3H8. Since it contains only carbon and hydrogen it is a hydrocarbon and with three carbons its name is propane. C = 3(12.01 u) = 36.03 u H = 8(1.008 u) = 8.064 u 44.09 u 2.109

Plan: Use the chemical symbols and count the atoms of each type to give a molecular formula. Use the nomenclature rules in the chapter to derive the name. The molecular (formula) mass is the sum of the masses of each atom times its atomic mass. Solution: a) Formula is N2O. Name is dinitrogen monoxide (the prefix diindicates 2 nitrogen atoms and mono- indicates 1 oxygen atom). N = 2(14.01 u) = 28.02 u O = 1(16.00 u) = 16.00 u 44.02 u b) Formula is C2H6. Since it contains only carbon and hydrogen it is a hydrocarbon and with three carbons its name is ethane. C = 2(12.01 u) = 24.02 u H = 6(1.008 u) = 6.048 u 30.07 u

2.110

Plan: Review the nomenclature rules in the chapter. For ionic compounds, name the metal, followed by the nonmetal name with an -ide suffix. For ionic compounds containing polyatomic ions, name the metal, followed by the name of the polyatomic ion. For metals, like many transition metals, that can form more than one ion each with a different charge, the ionic charge of the metal ion is indicated by a Roman numeral within parentheses immediately following the metal‘s name. Oxoacids (H + an oxoanion) are named by changing the suffix of the oxoanion: -ate becomes -ic acid and -ite becomes -ous acid. Greek numerical prefixes are used to indicate the number of atoms of each element in a compound composed of two nonmetals. Solution: a) blue vitriol CuSO4•5H2O copper(II) sulfate pentahydrate SO42– = sulfate; II is used to indicate the 2+ charge of Cu; penta- is used to indicate the 5 waters of hydration. b) slaked lime Ca(OH)2 calcium hydroxide The anion OH– is hydroxide. c) oil of vitriol H2SO4 sulfuric acid SO42– is the sulfate ion; since this is an acid, -ate becomes -ic acid. d) washing soda Na2CO3 sodium carbonate CO32– is the carbonate ion. e) muriatic acid HCl hydrochloric acid Binary acids (H plus one other nonmetal) are named hydro- + nonmetal root + -ic acid. f) Epsom salts MgSO4•7H2O magnesium sulfate heptahydrate SO42– = sulfate; hepta- is used to indicate the 7 waters of hydration. g) chalk CaCO3 calcium carbonate CO32– is the carbonate ion. h) dry ice CO2 carbon dioxide The prefix diindicates 2 oxygen atoms; since there is only one carbon atom, no prefix is used. i) baking soda NaHCO3 sodium hydrogen carbonate HCO3– is the hydrogen carbonate ion. j) lye NaOH sodium hydroxide The anion OH– is hydroxide.

2.111

Plan: Use the chemical symbols and count the atoms of each type to give a molecular formula. Use the nomenclature rules in the chapter to derive the name. The molecular (formula) mass is the sum of the masses of each atom times its atomic mass. Solution: a) Each molecule has 2 blue spheres and 1 red sphere so the molecular formula is N2O. This compound is composed of two nonmetals. The element with the lower group number is named first. Greek numerical prefixes are used to indicate the number of atoms of each element in the compound. The prefix diindicates 2 nitrogen atoms and mono- indicates 1 oxygen atom. The name is dinitrogen monoxide. N = 2(14.01 u) = 28.02u O = 1(16.00 u) = 16.00 u 44.02 u b) Each molecule has 2 green spheres and 1 red sphere so the molecular formula is Cl2O. This compound is composed of two nonmetals. When a compound contains oxygen and a halogen, the halogen is named first. Greek numerical prefixes are used to indicate the number of atoms of each element in the compound. The prefix diindicates 2 chlorine atoms and mono- indicates 1 oxygen atom. The name is dichlorine monoxide. Cl = 2(35.45 u) = 70.90 u O = 1(16.00 u) = 16.00 u 86.90 u

2.112

Plan: Review the discussion on separations. Solution: Separating the components of a mixture requires physical methods only; that is, no chemical changes (no changes in composition) take place and the components maintain their chemical identities and properties throughout. Separating the components of a compound requires a chemical change (change in composition).

2.113

Plan: Review the definitions of homogeneous and heterogeneous. Solution: A homogeneous mixture is uniform in its macroscopic, observable properties; a heterogeneous mixture shows obvious differences in properties (density, colour, state, etc.) from one part of the mixture to another.

2.114

A solution (such as salt or sugar dissolved in water) is a homogeneous mixture.

2.115

Plan: Review the definitions of homogeneous and heterogeneous. The key is that a homogeneous mixture has a uniform composition while a heterogeneous mixture does not. A mixture consists of two or more substances physically mixed together while a compound is a pure substance. Solution: a) Distilled water is a compound that consists of H2O molecules only. b) Gasoline is a homogeneous mixture of hydrocarbon compounds of uniform composition that can be separated by physical means (distillation). c) Beach sand is a heterogeneous mixture of different size particles of minerals and broken bits of shells. d) Wine is a homogeneous mixture of water, alcohol, and other compounds that can be separated by physical means (distillation). e) Air is a homogeneous mixture of different gases, mainly N2, O2, and Ar.

2.116

Plan: Review the definitions of homogeneous and heterogeneous. The key is that a homogeneous mixture has a uniform composition while a heterogeneous mixture does not. A mixture consists of two or more substances physically mixed together while a compound is a pure substance. Solution: a) Orange juice is a heterogeneous mixture of water, juice, and bits of orange pulp. b) Vegetable soup is a heterogeneous mixture of water, broth, and vegetables. c) Cement is a heterogeneous mixture of various substances. d) Calcium sulfate is a compound of calcium, sulfur, and oxygen in a fixed proportion. e) Tea is a homogeneous mixture.

2.117

Plan: Review the discussion on separations. Solution: a) Filtration — separating the mixture on the basis of differences in particle size. The water moves through the holes in the colander but the larger pasta cannot. b) Extraction — The coloured impurities are extracted into a solvent that is rinsed away from the raw sugar (or chromatography). A sugar solution is passed through a column in which the impurities stick to the stationary phase and the sugar moves through the column in the mobile phase.

2.118

Analysis time can be shortened by operating the column at a higher temperature or by increasing the rate of flow of the gaseous mobile phase.

2.119

Plan: Use the equation for the volume of a sphere in part a) to find the volume of the nucleus and the volume of the atom. Calculate the fraction of the atom volume that is occupied by the nucleus. For part b), calculate the total mass of the two electrons; subtract the electron mass from the mass of the atom to find the mass of the nucleus. Then calculate the fraction of the atom‘s mass contributed by the mass of the nucleus. Solution: 3 4 4 a) Volume (m3) of nucleus =  r 3 =  2.5x1015 m = 6.54498x10–44 m3 3 3 3 4 4 3 3 Volume (m ) of atom =  r =  3.1x1011 m = 1.24788x10–31 m3 3 3





volume of Nucleus 6.54498x1044 m3 = = 5.2449x10–13 = 5.2x10–13 volume of Atom 1.24788x1031 m3 b) Mass of nucleus = mass of atom – mass of electrons = 6.64648x10–24 g – 2(9.10939x10–28 g) = 6.64466x10–24 g Fraction of volume =

Fraction of mass =

 

 

6.64466 x1024 g mass of Nucleus = = 0.99972617 = 0.999726 mass of Atom 6.64648 x1024 g

As expected, the volume of the nucleus relative to the volume of the atom is small while its relative mass is large. 2.120

Plan: Use Coulomb‘s law which states that the energy of attraction in an ionic bond is directly proportional to the product of charges and inversely proportional to the distance between charges. Choose the largest ionic charges and smallest radii for the strongest ionic bonding and the smallest ionic charges and largest radii for the weakest ionic bonding. Solution: Strongest ionic bonding: MgO. Mg2+, Ba2+, and O2– have the largest charges. Attraction increases as distance decreases, so the positive ion with the smaller radius, Mg2+, will form a stronger ionic bond than the larger ion Ba2+. Weakest ionic bonding: RbI. K+, Rb+, Cl–, and I– have the smallest charges. Attraction decreases as distance increases, so the ions with the larger radii, Rb+ and I–, will form the weakest ionic bond.

2.121

Plan: Use the chemical symbols and count the atoms of each type to give a molecular formula. Use the nomenclature rules in the chapter to derive the name. These compounds are composed of two nonmetals. Greek numerical prefixes are used to indicate the number of atoms of each element in each compound. The molecular (formula) mass is the sum of the masses of each atom times its atomic mass. Solution: a) Formula is BrF3. When a compound is composed of two elements from the same group, the element with the higher period number is named first. The prefix triindicates 3 fluorine atoms. A prefix is used with the first word in the name only when more than one atom of that element is present. The name is bromine trifluoride. Br = 1(79.90 u) = 79.90 u F = 3(19.00 u) = 57.00 u 136.90 u

b) The formula is SCl2. The element with the lower group number is the first word in the name. The prefix diindicates 2 chlorine atoms. A prefix is used with the first word in the name only when more than one atom of that element is present. The name is sulfur dichloride. S = 1(32.07 u) = 32.07 u Cl = 2(35.45 u) = 70.90 u 102.97 u c) The formula is PCl3. The element with the lower group number is the first word in the name. The prefix triindicates 3 chlorine atoms. A prefix is used with the first word in the name only when more than one atom of that element is present. The name is phosphorus trichloride. P = 1(30.97 u) = 30.97 u Cl = 3(35.45 u) = 106.35 u 137.32 u d) The formula is N2O5. The element with the lower group number is the first word in the name. The prefix diindicates 2 nitrogen atoms and the prefix penta- indicates 5 oxygen atoms. Only the second element is named with the suffix -ide. The name is dinitrogen pentoxide. N = 2(14.01 u) = 28.02 u O = 5(16.00 u) = 80.00 u 108.02 u 2.122

Plan: These polyatomic ions are oxoanions composed of oxygen and another nonmetal. Oxoanions with the same number of oxygen atoms and nonmetals in the same group will have the same suffix ending. Only the nonmetal root name will change. Solution: a) SeO42– selenate ion from SO42– = sulfate ion 3– b) AsO4 arsenate ion from PO43– = phosphate ion – c) BrO2 bromite ion from ClO2– = chlorite ion d) HSeO4– hydrogen selenate ion from HSO4– = hydrogen sulfate ion 2– e) TeO3 tellurite ion from SO32– = sulfite ion

2.123

Plan: Write the formula of the compound and find the molecular mass. Determine the mass percent of nitrogen or phosphorus by dividing the mass of nitrogen or phosphorus in the compound by the molecular mass and multiplying by 100. For part b), multiply the 100. g sample of compound by the mass ratio of ammonia to compound. Solution: a) Ammonium is NH4+ and dihydrogen phosphate is H2PO4–. The formula is NH4H2PO4. N = 1(14.01 u) = 14.01 u H = 6(1.008 u) = 6.048 u P = 1(30.97 u) = 30.97 u O = 4(16.00 u) = 64.00 u 115.03 u 14.01 u N Mass percent of N = 100  = 12.18% N 115.03 u compound Mass percent of P =

30.97 u P 100  = 26.92% P 115.03 u compound

  17.03 u NH3 b) Mass (g) of ammonia (NH3) = 100. g NH 4 H 2 PO 4    = 14.80 g NH3  115.03 u NH 4 H 2 PO 4  2.124

Plan: Determine the percent oxygen in each oxide by subtracting the percent nitrogen from 100%. Express the percentage in u and divide by the atomic mass of the appropriate elements. Then divide each amount by the smaller number and convert to the simplest whole-number ratio. To find the mass of oxygen per 1.00 g of nitrogen, divide the mass percentage of oxygen by the mass percentage of nitrogen.

Solution: a) I

(100.00 – 46.69 N)% = 53.31% O  46.69 u N    = 3.3326 N  14.01 u N 

 53.31 u O    = 3.3319 O  16.00 u O 

3.3326 N 3.3319 O = 1.0002 N = 1.0000 O 3.3319 3.3319 The simplest whole-number ratio is 1:1 N:O. (100.00 – 36.85 N)% = 63.15% O  36.85 u N   63.15 u O    = 2.6303 N   = 3.9469 O  14.01 u N   16.00 u O 

III

2.6303 N 3.9469 O = 1.0000 mol N = 1.5001 O 2.6303 2.6303 The simplest whole-number ratio is 1:1.5 N:O = 2:3 N:O. (100.00 – 25.94 N)% = 74.06% O  25.94 u N   74.06 u O    = 4.6288 O   = 1.8515 N 14.01u N  16.00 u O   

1.8515 N 4.6288 O = 1.0000 N = 2.5000 O 1.8515 1.8515 The simplest whole-number ratio is 1:2.5 N:O = 2:5 N:O.  53.31 u O    = 1.1418 = 1.14 g O  46.69 u N 

 63.15 u O    = 1.7137 = 1.71 g O  36.85 u N 

III

 74.06 u O    = 2.8550 = 2.86 g O  25.94 u N 

2.125

Plan: Recall that density = mass/volume. Solution: The mass of an atom of Pb is several times that of one of Al. Thus, the density of Pb would be expected to be several times that of Al if approximately equal numbers of each atom were occupying the same volume.

2.126

Plan: Review the law of mass conservation and law of definite composition. For each experiment, compare the mass values before and after each reaction and examine the ratios of the mass of reacted sodium to the mass of reacted chlorine. Solution: In each case, the mass of the starting materials (reactants) equals the mass of the ending materials (products), so the law of mass conservation is observed. Case 1: 39.34 g + 60.66 g = 100.00 g Case 2: 39.34 g + 70.00 g = 100.00 g + 9.34 g Case 3: 50.00 g + 50.00 g = 82.43 g + 17.57 g Each reaction yields the product NaCl, not Na2Cl or NaCl2 or some other variation, so the law of definite composition is observed. In each case, the ratio of the mass of sodium to the mass of chlorine in the compound is the same. Case 1: Mass Na/mass Cl2 = 39.34 g/60.66 g = 0.6485 Case 2: Mass of reacted Cl2 = initial mass – excess mass = 70.00 g – 9.34 g = 60.66 g Cl2 Mass Na/mass Cl2 = 39.34 g/60.66 g = 0.6485 Case 3: Mass of reacted Na = initial mass – excess mass = 50.00 g – 17.57 g = 32.43 g Na Mass Na/mass Cl2 = 32.43 g/50.00 g = 0.6486

2.127

Plan: Recall the definitions of solid, liquid, gas (from Chapter 1), element, compound, and homogeneous and heterogeneous mixtures. Solution: a) Gas is the phase of matter that fills its container. A mixture must contain at least two different substances. B, F, G, and I each contain only one gas. D and E each contain a mixture; E is a mixture of two different gases while D is a mixture of a gas and a liquid of a second substance. b) An element is a substance that cannot be broken down into simpler substances. A, C, G, and I are elements. c) The solid phase has a very high resistance to flow since it has a fixed shape. A shows a solid element. d) A homogeneous mixture contains two or more substances and has only one phase. E and H are examples of this. E is a homogeneous mixture of two gases and H is a homogeneous mixture of two liquid substances. e) A liquid conforms to the container shape and forms a surface. C shows one element in the liquid phase. f) A diatomic particle is a molecule composed of two atoms. B and G contain diatomic molecules of gas. g) A compound can be broken down into simpler substances. B and F show molecules of a compound in the gas phase. h) The compound shown in F has molecules composed of two white atoms and one blue atom for a 2:1 atom ratio. i) Mixtures can be separated into the individual components by physical means. D, E, and H are each a mixture of two different substances. j) A heterogeneous mixture like D contains at least two different substances with a visible boundary between those substances. k) Compounds obey the law of definite composition. B and F depict compounds.

2.128

Plan: To find the mass percent divide the mass of each substance in mg by the amount of seawater in mg and multiply by 100. The percent of an ion is the mass of that ion divided by the total mass of ions. Solution:  1000 g   1000 mg  6 a) Mass (mg) of seawater = 1 kg     = 1x10 mg 1 kg 1 g     mass of substance  Mass % =   100%   mass of seawater 

 18,980 mg Cl  100%  = 1.898% Cl– Mass % Cl– =   1x106 mg seawater    

 10,560 mg Na   100%  = 1.056% Na+ Mass % Na+ =   1x106 mg seawater      2650 mg SO42   100%  = 0.265% SO42– Mass % SO42– =   1x106 mg seawater    

 1270 mg Mg2   100%  = 0.127% Mg2+ Mass % Mg2+ =   1x106 mg seawater      400 mg Ca 2   100%  = 0.04% Ca2+ Mass % Ca2+ =   1x106 mg seawater    

  380 mg K  100%  = 0.038% K+ Mass % K+ =   1x106 mg seawater      140 mg HCO3  100%  = 0.014% HCO3– Mass % HCO3– =   1x106 mg seawater     The mass percents do not add to 100% since the majority of seawater is H 2O.

b) Total mass of ions in 1 kg of seawater = 18,980 mg + 10,560 mg + 2650 mg + 1270 mg + 400 mg + 380 mg + 140 mg = 34,380 mg  10,560 mg Na +  % Na + =  100  = 30.71553 = 30.72%  34,380 mg total ions     c) Alkaline earth metal ions are Mg2+ and Ca2+ (Group 2 ions). Total mass % = 0.127% Mg2+ + 0.04% Ca2+ = 0.167% Alkali metal ions are Na+ and K+ (Group 1 ions). Total mass % = 1.056% Na + + 0.038% K+ = 1.094% Mass % of alkali metal ions 1.094% = = 6.6 Mass % of alkaline earth metal ions 0.167% Total mass percent for alkali metal ions is 6.6 times greater than the total mass percent for alkaline earth metal ions. Sodium ions (alkali metal ions) are dominant in seawater. d) Anions are Cl–, SO42–, and HCO3–. Total mass % = 1.898% Cl– + 0.265% SO42– + 0.014% HCO3– = 2.177% anions Cations are Na+, Mg2+, Ca2+, and K+. Total mass % = 1.056% Na+ + 0.127% Mg2+ + 0.04% Ca2+ + 0.038% K+ = 1.2610 = 1.26% cations The mass fraction of anions is larger than the mass fraction of cations. Is the solution neutral since the mass of anions exceeds the mass of cations? Yes, although the mass is larger, the number of positive charges equals the number of negative charges. 2.129

2.130

Plan: Review the mass laws in the chapter. Solution: The law of mass conservation is illustrated in this change. The first flask has six oxygen atoms and six nitrogen atoms. The same number of each type of atom is found in both of the subsequent flasks. The mass of the substances did not change. The law of definite composition is also illustrated. During both temperature changes, the same compound, N2O, was formed with the same composition. . Plan: First, count each type of atom present to produce a molecular formula. The molecular (formula) mass is the sum of the atomic masses of all of the atoms. Divide the mass of each element in the compound by the molecular mass and multiply by 100 to obtain the mass percent of each element. Solution: The molecular formula of succinic acid is C4H6O4. C = 4(12.01 u) = 48.04 u H = 6(1.008 u) = 6.048 u O = 4 (16.00 u) = 64.00 u 118.09 u  48.04 u C  %C=  100% = 40.6815 = 40.68% C  118.088 u 

 6.048 u H  %H=  100% = 5.1216 = 5.122% H  118.088 u 

 64.00 u O  %O=  100% = 54.1969 = 54.20% O  118.088 u  Check: Total = (40.68 + 5.122 + 54.20)% = 100.00% The answer checks. 2.131

Plan: The toxic level of fluoride ion for a 70-kg person is 0.2 g. Convert this mass to mg and use the concentration of fluoride ion in drinking water to find the volume of water that contains the toxic amount. Convert the volume of the reservoir to liters and use the concentration of 1mg of fluoride ion per liter of water to find the mass of sodium fluoride required. Solution: A 70-kg person would have to consume 0.2 g of F– to reach the toxic level.  1 mg F  Mass (mg) of fluoride for a toxic level = 0.2 g F  = 200 mg F–  0.001 g F   





 1 L water  Volume (L) of water = 200 mg  = 200 L= 2x102 L water  1 mg F    7 Volume (L) of reservoir = = 8.50 x 10 L The molecular mass of NaF = 22.99 u Na + 19.00 u F = 41.99 u. There are 19.00 mg of F – in every 41.99 mg of NaF.  1 mg F   41.99 mg NaF   103 g   1 kg NaF  Mass (kg) of NaF = 8.50x107 L   1 L H O   19.00 mg F   1 mg   103 g NaF  2      = 187.85 kg= 188 kg NaF



2.132



Plan: Z = the atomic number of the element. A is the mass number. To find the percent abundance of each Sb isotope, let x equal the fractional abundance of one isotope and (1 – x) equal the fractional abundance of the second isotope since the sum of the fractional abundances must equal 1. Remember that atomic mass = (isotopic mass of the first isotope x fractional abundance) + (isotopic mass of the second isotope x fractional abundance). Solution: a) Antimony is element 51so Z = 51. Isotope of mass 120.904 u has a mass number of 121: 121 51 Sb Isotope of mass 122.904 u has a mass number of 123: 123 51 Sb b) Let x = fractional abundance of antimony-121. This makes the fractional abundance of antimony-123 = 1 – x x(120.904 u) + (1 – x) (122.904 u) = 121.8 u 120.904 u(x) + 122.904 u – 122.904 u(x) = 121.8 u 2x = 1.104 x = 0.552 = 0.55 fraction of antimony-121 1 – x = 1 – 0.552 = 0.45 fraction of antimony-123

2.133

Plan: List all possible combinations of the isotopes. Determine the masses of each isotopic composition. The molecule consisting of the lower abundance isotopes (N-15 and O-18) is the least common, and the one containing only the more abundant isotopes (N-14 and O-16) will be the most common. Solution: a) b) Formula Mass (u) 15 N218O 2(15 u N) + 18 u O = 48 least common 15 N216O 2(15 u N) + 16u O = 46 14 N218O 2(14 u N) + 18 u O = 46 14 N216O 2(14 u N) + 16 u O = 44 most common 15 14 18 N N O 1(15 u N) + 1(14 u N) + 18 u O = 47 15 14 16 N N O 1(15 u N) + 1(14 u N) + 16 u O = 45

2.134

Plan: The superscript is the mass number, the sum of the number of protons and neutrons. Consult the periodic table to get the atomic number (the number of protons). The mass number – the number of protons = the number of neutrons. Divide the number of neutrons by the number of protons to obtain the N/Z ratio. For atoms, the number of protons and electrons are equal. Solution: neutrons (N) protons (Z) N/Z 144 a) 62 Sm 144 – 62 = 82 62 82/62 = 1.3 b) 56 26 Fe

56 – 26 = 30

30/26 = 1.2

c) 20 10 Ne

20 – 10 = 10

10/10 = 1.0

d) 107 47 Ag

107 – 47 = 60

60/47 = 1.3

2.135

Plan: Review the information about the periodic table in the chapter. Solution: a) Nonmetals are located in the upper-right portion of the periodic table: Black, red, green, and purple b) Metals are located in the large left portion of the periodic table: Brown and blue c) Some nonmetals, such as oxygen, chlorine, and argon, are gases: Red, green, and purple d) Most metals, such as sodium and barium are solids; carbon is a solid: Brown, blue, and black e) Nonmetals form covalent compounds; most noble gases do not form compounds: Black and red or black and green or red and green f) Nonmetals form covalent compounds; most noble gases do not form compounds: Black and red or black and green or red and green g) Metals react with nonmetals to form ionic compounds. For a compound with a formula of MX, the ionic charges of the metals and nonmetal must be equal in magnitude like Na + and Cl– or Ba2+ and O2–: Brown and green or blue and red h) Metals react with nonmetals to form ionic compounds. For a compound with a formula of MX, the ionic charges of the metals and nonmetal must be equal in magnitude like Na + and Cl– or Ba2+ and O2–: Brown and green or blue and red i) Metals react with nonmetals to form ionic compounds. For a compound with a formula of M 2X, the ionic charge of the nonmetal must be twice as large as that of the metal like Na+ and O2– or Ba2+ and C4–: Brown and red or blue and black j) Metals react with nonmetals to form ionic compounds. For a compound with a formula of MX 2, the ionic charge of the metal must be twice as large as that of the nonmetal like Ba2+ and Cl–: Blue and green k) Most Group 18 elements are unreactive: Purple l) Different compounds often exist between the same two nonmetal elements. Since oxygen exists as O 2– or O22–, metals can sometimes form more than one compound with oxygen: Black and red or red and green or black and green or brown and red or blue and red

2.136

Plan: To find the formula mass of potassium fluoride, add the atomic masses of potassium and fluorine. Fluorine has only one naturally occurring isotope, so the mass of this isotope equals the atomic mass of fluorine. The atomic mass of potassium is the weighted average of the two isotopic masses: (isotopic mass of isotope 1 x fractional abundance) + (isotopic mass of isotope 2 x fractional abundance). Solution: Average atomic mass of K = (isotopic mass of 39K x fractional abundance) + (isotopic mass of 41K x fractional abundance)

 93.258%   6.730%    (40.9618 u)   = 39.093 u  100%   100% 

Average atomic mass of K = (38.9637 u) 

The formula for potassium fluoride is KF, so its molecular mass is (39.093 + 18.9984)u = 58.091 u 2.137

Plan: List all possible combinations of the isotopes. BF3 contains either 10B or 11B. Determine the masses of each isotopic composition and also the masses of each molecule missing one, two, or all three F atoms. Solution: 10 19 B F3 = 10 u B + 3(19 u F) = 67 u 10 19 B F2 = 10 u B + 2(19 u F) = 48 u

B19F B 11 19 B F3 11 19 B F2 11 19 B F 11 B 10

= 10 u B + 19 u F = 29 u = 10 u B = 10. u = 11 u B + 3(19 u F) = 68 u = 11 u B + 2(19 u F) = 49 u = 11 u B + 19 u F = 30 u = 11 u B = 11 u

2.138

Plan: One molecule of NO is released per atom of N in the medicine. Divide the total mass of NO released by the molecular mass of the medicine and multiply by 100 for mass percent. Solution: NO = (14.01 + 16.00) u = 30.01 u Nitroglycerin: C3H5N3O9 = 3(12.01 u C) + 5(1.008 u H) + 3(14.01 u N) + 9(16.00 u O) = 227.10 u In C3H5N3O9 (molecular mass = 227.10 u), there are 3 atoms of N; since 1 molecule of NO is released per atom of N, this medicine would release 3 molecules of NO. The molecular mass of NO = 30.01 u. total mass of NO 3(30.01 u) Mass percent of NO = 100%   100%  = 39.6433% = 39.64% mass of compound 227.10 u Isoamyl nitrate: C5H11NO3 = 5(12.01 u C) + 11(1.008 u H) + 1(14.01 u N) + 3(16.00 u O) = 133.15 u In (CH3)2CHCH2CH2ONO2 (molecular mass = 133.15 u), there is one atom of N; since 1 molecule of NO is released per atom of N, this medicine would release 1 molecule of NO. total mass of NO 1(30.01 u) Mass percent of NO = 100%   100%  = 22.5385 %= 22.54% mass of compound 133.15 u

2.139

Plan: First, count each type of atom present to produce a molecular formula. Determine the mass fraction of each total mass of the element . The mass of TNT multiplied by the mass fraction of each element. Mass fraction = molecular mass of TNT element gives the mass of that element. Solution: The molecular formula for TNT is C7H5O6N3. The molecular mass of TNT is: C = 7(12.01 u) = 84.07 u H = 5(1.008 u) = 5.040 u O = 6(16.00 u) = 96.00 u N = 3(14.01 u) = 42.03 u 227.14 u The mass fraction of each element is: 84.07 u 5.040 u C= = 0.3701 C H= = 0.02219 H 227.14 u 227.14 u

96.00 u 42.03 u = 0.4226 O N= = 0.1850 N 227.14 u 227.14 u Masses of each element in 1.00 kg of TNT = mass fraction of element x 1.00kg. Mass (kg) C = 0.3701 x 1.00 kg = 0.370 kg C Mass (kg) H = 0.02219 x 1.00 kg = 0.0222 kg H Mass (kg) O = 0.4226 x 1.00 kg = 0.423 kg O Mass (kg) N = 0.1850 x 1.00 kg = 0.185 kg N O=

b) 238 92 U

neutrons 238 – 92 = 146

protons 92

electrons 92

234 92 U

234 – 92 = 142

214 82 Pb

214 – 82 = 132

2.140

210 82 Pb

210 – 82 = 128

206 82 Pb

206 – 82 = 124

Plan: Determine the mass percent of platinum by dividing the mass of Pt in the compound by the molecular mass of the compound and multiplying by 100. For part b), divide the total amount of money available by the cost of Pt per gram to find the mass of Pt that can be purchased. Use the mass percent of Pt to convert from mass of Pt to mass of compound. Solution: a) The molecular formula for platinol is Pt(NH3)2Cl2. Its molecular mass is: Pt = 1(195.1 u) = 195.1 u N = 2 (14.01 u) = 28.02 u H = 6(1.008 u) = 6.048 u Cl = 2(35.45 u) = 70.90 u 300.1 u mass of Pt 195.1 u Mass % Pt = 100%  = 100%  = 65.012 %= 65.01% Pt molecular mass of compound 300.1 u





 1 g Pt  b) Mass (g) of Pt = $1.00 x 106   = 31,250 g Pt  $32 

 100 g platinol  4 4 Mass (g) of platinol =  31, 250 g Pt    = 4.8070x10 g= 4.8x10 g platinol  65.01 g Pt  2.141

Plan: Obtain the information from the periodic table. The period number of an element is its row number while the group number is its column number. Solution: a) Building-block elements: Name Symbol Atomic number Atomic mass Period number Group number Hydrogen H 1 1.008 u 1 1 Carbon C 6 12.01 u 2 14 Nitrogen N 7 14.01 u 2 15 Oxygen O 8 16.00 u 2 16 b) Macronutrients: Sodium Na 11 22.99 u 3 1 Magnesium Mg 12 24.31 u 3 2 Potassium K 19 39.10 u 4 1 Calcium Ca 20 40.08 u 4 2 Phosphorus P 15 30.97 u 3 15 Sulfur S 16 32.07 u 3 16 Chlorine Cl 17 35.45 u 3 17

2.142

Plan: Review the definitions of pure substance, element, compound, homogeneous mixture, and heterogeneous mixture. Solution: Matter is divided into two categories: pure substances and mixtures. Pure substances are divided into elements and compounds. Mixtures are divided into solutions (homogeneous mixtures) and heterogeneous mixtures.

2.143

Plan: A change is physical when there has been a change in physical form but not a change in composition. In a chemical change, a substance is converted into a different substance. Solution: 1) Initially, all the molecules are present in blue-blue or red-red pairs. After the change, there are no red-red pairs, and there are now red-blue pairs. Changing some of the pairs means there has been a chemical change. 2) There are two blue-blue pairs and four red-blue pairs both before and after the change, thus no chemical change occurred. The different types of molecules are separated into different boxes. This is a physical change. 3) The identity of the box contents has changed from pairs to individuals. This requires a chemical change. 4) The contents have changed from all pairs to all triplets. This is a change in the identity of the particles, thus, this is a chemical change. 5) There are four red-blue pairs both before and after, thus there has been no change in the identity of the individual units. There has been a physical change.

CHAPTER 3 STOICHIOMETRY OF FORMULAE

AND EQUATIONS END–OF–CHAPTER PROBLEMS 3.1 Plan: The atomic mass of an element expressed in u is numerically the same as the mass of 1 mole of the element expressed in grams. We know the amount (mol) of each element and have to find the mass (in g). To convert amount (mol) of element to mass of element, multiply the amount by the molar mass of the element. Solution: Al 26.98 u  26.98 g/mol Al  26.98 g Al  Mass Al (g) = 3 mol Al   = 80.94 g Al  1 mol Al  Cl 35.45 u  35.45 g/mol Cl  35.45 g Cl  Mass Cl (g) = 2 mol Cl   = 70.90 g Cl  1 mol Cl  3.2

Plan: The molecular formula of sucrose tells us that 1 mole of sucrose contains 12 moles of carbon atoms. Multiply the amount (mol) of sucrose by 12 to obtain amount (mol) of carbon atoms; multiply the amount (mol) of carbon atoms by Avogadro‘s number to convert from amount (mol) to atoms. Solution:   12 mol C a) Amount (mol) of C atoms = 1 mol C12 H 22 O11   = 12 mol C  1 mol C12 H 22 O11     6.022 x1023 C atoms  12 mol C 25 b) C atoms =  2 mol C12 H 22O11    = 1.445x10 C atoms   1 mol C H O 1 mol C 12 22 11    

3.3

Plan: Review the list of elements that exist as diatomic or polyatomic molecules. Solution: ―1 mol of chlorine‖ could be interpreted as a mole of chlorine atoms or a mole of chlorine molecules, Cl 2. Specify which to avoid confusion. The same problem is possible with other diatomic or polyatomic molecules, e.g., F2, Br2, I2, H2, O2, N2, S8, and P4. For these elements, as for chlorine, it is not clear if atoms or molecules are being discussed.

3.4

The molecular mass is the sum of the atomic masses of the atoms or ions in a molecule. The molar mass is the mass of 1 mole of a chemical entity. Both will have the same numeric value for a given chemical substance but molecular mass will have the units of u and molar mass will have the units of g/mol.

3.5

A mole of a particular substance represents a fixed number of chemical entities and has a fixed mass. Therefore the mole gives us an easy way to determine the number of particles (atoms, molecules, etc) in a sample by taking its mass. The mole maintains the same mass relationship between macroscopic samples as exist between individual chemical entities. It relates the number of chemical entities (atoms, molecules, ions, electrons) to the mass.

3.6

Plan: The mass of the compound is given. Divide the given mass by the molar mass of the compound to convert from mass of compound to amount (mol) of compound. The molecular formula of the compound tells us that 1 mole of compound contains 2 moles of phosphorus atoms. Use the ratio between P atoms and P 4 molecules (4:1) to convert amount (mol) of phosphorus atoms to amount (mol) of phosphorus molecules. Finally, multiply amount (mol) of P4 molecules by Avogadro‘s number to find the number of molecules.

Solution: Roadmap Mass (g) of Ca3(PO4)2 Divide by M (g/mol) Amount (mol) of Ca3(PO4)2 Molar ratio between Ca3(PO4)2 and P atoms Amount (moles) of P atoms Molar ratio between P atoms and P4 molecules Amount (moles) of P4 molecules Multiply by 6.022x1023 formula units/mol Number of P4 molecules

3.7

Plan: The relative atomic masses of each element can be found by counting the number of atoms of each element and comparing the overall masses of the two samples. Solution: a) The element on the left (green) has the higher molar mass because only 5 green atoms are necessary to counterbalance the mass of 6 yellow atoms. Since the yellow atoms are lighter, their atomic mass is lower, and therefore there will be more atoms per gram on the right and fewer atoms per gram on the left. Since one mole of any compound contains the same number of particles (6.022x10 23) neither side has more atoms per mole. b) This figure requires more thought because the number of red and blue atoms is unequal and their masses are unequal. If each pan only contained 3 atoms, then the red atoms would be still be lighter. The presence of 6 red atoms means that they are much lighter. Because the red atoms are lighter, more red atoms are required to make 1 g. Therefore the higher molar mass compound is on the right (blue), the left has more atoms per gram and the right has fewer atoms per gram. Since one mole of any compound contains the same number of particles (6.022x1023) neither side has more atoms per mole. c) The element on the left (orange) has a higher molar mass since the 5 atoms weigh more than the 5 purple atoms. The purples atoms (right) are lighter so there are more atoms per gram and the orange atoms (left) would have fewer atoms per gram. Since one mole of any compound contains the same number of particles (6.022x10 23) neither side has more atoms per mole. d) We can see that it takes more red atoms to exactly counter the weight of the black atoms, therefore the black atoms (left) are heavier and have a higher molar mass. The red atoms (right) are lighter and there will be more atoms per gram versus the heavier black atoms (left) which will have fewer atoms per gram. Since one mole of any compound contains the same number of particles (6.022x10 23) neither side has more atoms per mole.

3.8

Plan: Locate each of the elements on the periodic table and record its atomic mass. The atomic mass of the element multiplied by the number of atoms present in the formula gives the mass of that element in one mole of the substance. The molar mass is the sum of the masses of the elements in the substance expressed in g/mol. Solution: a) M = (1 •M of Sr) + (2 •M of O) + (2 • M of H) = (1 • 87.62 g/mol Sr) + (2 • 16.00 g/mol O) + (2 • 1.008 g/mol H) = 121.64 g/mol of Sr(OH)2 b) M = (2 •M of N) + (3 • M of O) = (2 •14.01 g/mol N) + (3 • 16.00 g/mol O) = 76.02 g/mol of N2O3 c) M = (1 • M of Na) + (1 •M of Cl) + (3 • M of O) = (1 •22.99 g/mol Na) + (1 •35.45 g/mol Cl) + (3 • 16.00 g/mol O) = 106.44 g/mol of NaClO3 d) M = (2 •M of Cr) + (3 • M of O) = (2 • 52.00 g/mol Cr) + (3 •16.00 g/mol O) = 152.00 g/mol of Cr2O3

3.9

Plan: Locate each of the elements on the periodic table and record its atomic mass. The atomic mass of the element multiplied by the number of atoms present in the formula gives the mass of that element in one mole of the substance. The molar mass is the sum of the masses of the elements in the substance expressed in g/mol. Solution: a) M = (3 • M of N) + (12 •M of H) + (1 •M of P) + (4 •M of O) = (3 •14.01 g/mol N) + (12 •1.008 g/mol H) + (1 •30.97 g/mol P) + (4 •16.00 g/mol O) = 149.10 g/mol of (NH4)3PO4 b) M = (1 •M of C) + (2 •M of H) + (2 •M of Cl) = (1 •12.01 g/mol C) + (2 •1.008 g/mol H) + (2 •35.45 g/mol Cl) = 84.93 g/mol of CH2Cl2 c) M = (1 •M of Cu) + (1 •M of S) + (9 •M of O) + (10 •M of H) = (1 •63.55 g/mol Cu) + (1 •32.07 g/mol S) + (9 •16.00 g/mol O) + (10 •1.008 g/mol H) = 249.70 g/mol of CuSO4•5H2O d) M = (1 •M of Br) + (3 •M of F) = (1 •79.90 g/mol Br) + (3 •19.00 g/mol F) = 136.90 g/mol of BrF3

3.10

Plan: Locate each of the elements on the periodic table and record its atomic mass. The atomic mass of the element multiplied by the number of atoms present in the formula gives the mass of that element in one mole of the substance. The molar mass is the sum of the masses of the elements in the substance expressed in g/mol. Solution: a) M = (1 •M of Sn) + (1 •M of O) = (1 •118.7 g/mol Sn) + (1 •16.00 g/mol O) = 134.7 g/mol of SnO b) M = (1 •M of Ba) + (2 •M of F) = (1 •137.3 g/mol Ba) + (2 •19.00 g/mol F) = 175.3 g/mol of BaF2 c) M = (2 •M of Al) + (3 •M of S) + (12 •M of O) = (2 •26.98 g/mol Al) + (3 •32.07 g/mol S) + (12 •16.00 g/mol O) = 342.17 g/mol of Al2(SO4)3 d) M = (1 •M of Mn) + (2 •M of Cl) = (1 •54.94 g/mol Mn) + (2 • 35.45 g/mol Cl) = 125.84 g/mol of MnCl2

3.11

a) M = (2 •M of N) + (4 •M of O) = (2 •14.01 g/mol N) + (4 •16.00 g/mol O) = 92.02 g/mol of N2O4 b) M = (4 •M of C) + (10 •M of H) + (1 •M of O) = (4 •12.01 g/mol C) + (10 •1.008 g/mol H) + (1 •16.00 g/mol O) = 74.12 g/mol of C4H9OH c) M = (1 •M of Mg) + (1 •M of S) + (11 x M of O) + (14 •M of H) = (1 •24.31 g/mol Mg) + (1 •32.07 g/mol S) + (11 •16.00 g/mol O) + (14 •1.008 g/mol H) = 246.49 g/mol of MgSO4•7H2O d) M = (1 •M of Ca) + (4 •M of C) + (6 •M of H) + (4 •M of O) = (1 •40.08 g/mol Ca) + (4 •12.01 g/mol C) + (6 •1.008 g/mol H) + (4 •16.00 g/mol O) = 158.17 g/mol of Ca(C2H3O2)2 3.12

Plan: Determine the molar mass of each substance, then perform the appropriate molar conversions. To find the mass in part a), multiply the amount (mol) by the molar mass of the substance. In part b), first convert mass of compound to amount (mol) of compound by dividing by the molar mass of the compound. The molecular formula of the compound tells us that 1 mole of compound contains 6 moles of oxygen atoms; use the 1:6 ratio to convert amount (mol) of compound to amount (mol) of oxygen atoms. In part c), convert mass of compound to amount (mol) of compound by dividing by the molar mass of the compound. Since 1 mole of compound contains 6 moles of oxygen atoms, multiply the amount (mol) of compound by 6 to obtain amount (mol) of oxygen atoms; then multiply by Avogadro‘s number to obtain the number of oxygen atoms. Solution: a) M of KMnO4 = (1 •M of K) + (1 •M of Mn) + (4 •M of O) = (1 •39.10 g/mol K) + (1 •54.94 g/mol Mn) + (4 •16.00 g/mol O) = 158.04 g/mol of KMnO4  158.04 g KMnO4  2 Mass of KMnO4 = 0.68 mol KMnO 4   = 107.467 g= 1.1x10 g KMnO4  1 mol KMnO 4  b) M of Ba(NO3)2 = (1 •M of Ba) + (2 •M of N) + (6 •M of O) = (1 •137.3 g/mol Ba) + (2 •14.01 g/mol N) + (6 •16.00 g/mol O) = 261.3 g/mol Ba(NO3)2  1 mol Ba(NO3 ) 2  Amount (mol) of Ba(NO3)2 = 8.18 g Ba(NO3 ) 2   = 0.031305 mol Ba(NO3)2  261.3 g Ba(NO3 ) 2   6 mol O atoms  Amount (mol) of O atoms = 0.031305 mol Ba(NO3 ) 2    1 mol Ba(NO3 ) 2  = 0.18783 mol= 0.188 mol O atoms c) M of CaSO4•2H2O = (1 •of Ca) + (1 •M of S) + (6 •M of O) + (4 •M of H) = (1 •40.08 g/mol Ca) + (1 •32.07 g/mol S) + (6 •16.00 g/mol O) + (4 •1.008 g/mol H) = 172.18 g/mol (Note that the waters of hydration are included in the molar mass.)  1 mol CaSO4 2H 2O  Amount (mol) of CaSO4•2H2O = 7.3x103 g CaSO4 2H 2O    172.18 g CaSO4 2H 2O 





= 4.239749x10–5 mol

 6 mol O atoms  Amount (mol) of O atoms = 4.239749 x105 mol CaSO 4 2H 2O    1 mol CaSO4 2H 2O  = 2.54385x10–4 mol O atoms  6.022 x1023 O atoms  Number of O atoms = 2.54385x104 mol O atoms   1 mol O atoms    = 1.5319x1020 atoms= 1.5x1020 O atoms



3.13



Plan: Determine the molar mass of each substance, then perform the appropriate molar conversions. To find the mass in part a), divide the number of molecules by Avogadro‘s number to find amount (mol) of compound and then multiply the mole amount by the molar mass in grams; convert from mass in g to mass in kg.

In part b), first convert mass of compound to amount (mol) of compound by dividing by the molar mass of the compound. The molecular formula of the compound tells us that 1 mole of compound contains 2 moles of chlorine atoms; use the 1:2 ratio to convert amount (mol) of compound to amount (mol) of chlorine atoms. In part c), convert mass of compound to amount (mol) of compound by dividing by the molar mass of the compound. Since 1 mole of compound contains 2 moles of H– ions, multiply the amount (mol) of compound by 2 to obtain amount (mol) of H– ions; then multiply by Avogadro‘s number to obtain the number of H – ions. Solution: a) M of NO2 = (1 x M of N) + (2 x M of O) = (1 x 14.01 g/mol N) + (2 x 16.00 g/mol O) = 46.01g/mol of NO 2   1 mol NO2 Amount (mol) of NO2 = 4.6x1021 molecules NO2  = 7.63866x10–3 mol NO2 23  6.022 x10 molecules NO  2  





 46.01 g NO2   1 kg  –4 –4 Mass (kg) of NO2 = 7.63866x10 3 mol NO2    3  = 3.51455x10 kg= 3.5x10 kg NO2 1 mol NO 10 g 2    b) M of C2H4Cl2 = (2 •M of C) + (4 •M of H) + (2 x M of Cl) = (2 •12.01g/mol C) + (4 •1.008 g/mol H) + (2 •35.45 g/mol Cl) = 98.95 g/mol of C2H4Cl2  1 mol C2 H 4 Cl2  –4 Amount (mol) of C2H4Cl2 = 0.0615 g C2 H 4 Cl2   = 6.21526x10 mol C2H4Cl2 98.95 g C H Cl 2 4 2  





 2 mol Cl atoms  –3 Amount (mol) of Cl atoms = 6.21526x10 4 mol C2 H 4Cl 2   = 1.2431x10 1 mol C H Cl 2 4 2   = 1.24x10–3 mol Cl atoms c) M of SrH2 = (1 •M of Sr) + (2 •M of H) = (1 •87.62 g/mol Sr) + (2 •1.008 g/mol H) = 89.64 g/mol of SrH2  1 mol SrH 2  Amount (mol) of SrH2 = 5.82 g SrH 2   = 0.0649264 mol SrH2  89.64 g SrH 2 





 2 mol H   Amount (mol) of H– ions = 0.0649264 mol SrH 2  = 0.1298528 mol H– ions  1 mol SrH  2  

 6.022x1023 H  ions  22 22 – Number of H– ions = 0.1298528 mol H  ions   = 7.81974x10 = 7.82x10 H ions   1 mol H  



3.14







b) M of Fe(ClO4)3 = (1 •M of Fe) + (3 •M of Cl) + (12 •M of O) = (1 •55.85 g/mol Fe) + (3 •35.45 g/mol S) + (12 •16.00 g/mol O) = 354.20 g/mol of Fe(ClO4)3  103 g  Mass (g) of Fe(ClO4)3 = 15.8 kg Fe(ClO4 )3  = 1.58 x 104 kg Fe(ClO4)3  1 kg   

 1 mol Fe(ClO 4 )3  Amount (mol) of Fe(ClO4)3 = 1.58x104 g Fe(ClO4 )3    354.20 g Fe(ClO4 )3  = 44.6076 mol= 44.6 mol Fe(ClO4)3 c) M of NH4NO2 = (2 •M of N) + (4 •M of H) + (2 •M of O) = (2 •14.01 g/mol N) + (4 •1.008 g/mol H) + (2 •16.00 g/mol O) = 64.05 g/mol NH4NO2  103 g  Mass (g) of NH4NO2 =  92.6 mg NH 4 NO2   = 0.0926 g NH4NO2  1 mg   





 1 mol NH 4 NO 2  –3 Amount (mol) of NH4NO2 =  0.0926 g NH 4 NO2    = 1.44575x10 mol NH4NO2 64.05 g NH NO 4 2    2 mol N atoms  –3 Amount (mol) of N atoms = 1.44575x103 mol NH 4 NO2   = 2.8915x10 mol N atoms  1 mol NH 4 NO2 





 6.022 x1023 N atoms  Number of N atoms = 2.8915x103 mol N atoms   1 mol N atoms    = 1.74126 x 1021 atoms= 1.74 x 1021 N atoms



3.15



Plan: Determine the molar mass of each substance, then perform the appropriate molar conversions. In part a), divide the mass by the molar mass of the compound to find amount (mol) of compound. Since 1 mole of compound contains 3 moles of ions (1 mole of Sr 2+ and 2 moles of F–), multiply the amount (mol) of compound by 3 to obtain amount (mol) of ions and then multiply by Avogadro‘s number to obtain the number of ions. In part b), multiply the amount (mol) by the molar mass of the substance to find the mass in g and then convert to kg. In part c), divide the number of formula units by Avogadro‘s number to find amount (mol); multiply the amount (mol) by the molar mass to obtain the mass in g and then convert to mg. Solution: a) M of SrF2 = (1 •M of Sr) + (2 •M of F) = (1 •87.62 g/mol Sr) + (2 •19.00 g/mol F) = 125.62 g/mol of SrF 2  1 mol SrF2  Amount (mol) of SrF2 = 38.1 g SrF2   = 0.303296 mol SrF2  125.62 g SrF2   3 mol ions  Amount (mol) of ions = 0.303296 mol SrF2   = 0.909888 mol ions  1 mol SrF2 

 6.022 x1023 ions  Number of ions =  0.909888 mol ions   = 5.47935x1023 = 5.48x1023 ions  1 mol ions    b) M of CuCl2•2H2O = (1 •M of Cu) + (2 •M of Cl) + (4 •M of H) + (2 •M of O) = (1 •63.55 g/mol Cu) + (2 •35.45 g/mol Cl) + (4 •1.008 g/mol H) + (2 •16.00 g/mol O) = 170.48 g/mol of CuCl2•2H2O (Note that the waters of hydration are included in the molar mass.)  170.48 g CuCl 2 •2H 2O  Mass (g) of CuCl2•2H2O =  3.58 mol CuCl 2 •2H 2O    = 610.32 g CuCl2•2H2O  1 mol CuCl 2 •2H 2O   1 kg  Mass (kg) of CuCl2•2H2O = 610.32 g CuCl2 2H 2 O  3  = 0.61032 = 0.610 kg CuCl2•2H2O  10 g    c) M of Bi(NO3)3•5H2O = (1 •M of Bi) + (3 •M of N) + (10 •M of H) + (14 •M of O) = (1 •209.0 g/mol Bi) + (3 •14.01 g/mol N) + (10 •1.008 g/mol H) + (14 •16.00 g/mol H) = 485.11 g/mol of Bi(NO 3)3•5H2O (Note that the waters of hydration are included in the molar mass.)   1 mol Amount (mol) of Bi(NO3)3•5H2O = 2.88 x1022 FU   = 0.047825 mol Bi(NO3)3•5H2O 23  6.022 x10 FU 





 485.1 g Bi(NO3 )3 5H 2 O  Mass (g) of Bi(NO3)3•5H2O = 0.047825 mol Bi(NO3 )3 5H 2 O   = 23.1999 g  1 mol Bi(NO3 )3 5H 2 O 

 1 mg  Mass (mg) of Bi(NO3)3•5H2O = 23.1999 g Bi(NO3 )3 5H 2 O  3   10 g    4 = 23199.9 mg= 2.32x10 mg Bi(NO3)3•5H2O

3.16

Plan: The formula of each compound must be determined from its name. The molar mass for each formula comes from the formula and atomic masses from the periodic table. Determine the molar mass of each substance, then perform the appropriate molar conversions. In part a), multiply the amount (mol) by the molar mass of the compound to find the mass of the sample. In part b), divide the number of molecules by Avogadro‘s number to find amount (mol); multiply the amount (mol) by the molar mass to obtain the mass. In part c), divide the mass by the molar mass to find amount (mol) of compound and multiply amount (mol) by Avogadro‘s number to find the number of formula units. In part d), use the fact that each formula unit contains 1 Na ion, 1 perchlorate ion, and that each perchlorate ion contains 1 Cl atom, and 4 O atoms. Solution: a) Carbonate is a polyatomic anion with the formula, CO32–. Copper(I) indicates Cu+. The correct formula for this ionic compound is Cu2CO3. M of Cu2CO3 = (2 •M of Cu) + (1 •M of C) + (3 •M of O) = (2 •63.55 g/mol Cu) + (1 •12.01 g/mol C) + (3 •16.00 g/mol O) = 187.11 g/mol of Cu2CO3  187.11 g Cu 2 CO3  3 Mass (g) of Cu2CO3 = 8.35 mol Cu 2 CO3   = 1562.4 = 1.56x10 g Cu2CO3 1 mol Cu CO 2 3   b) Dinitrogen pentaoxide has the formula N2O5. Di- indicates 2 N atoms and penta- indicates 5 O atoms. M of N2O5 = (2 •M of N) + (5 •M of O) = (2 •14.01 g/mol N) + (5 •16.00 g/mol O) = 108.02 g/mol of N2O5   1 mol N 2O5 Amount (mol) of N2O5 = 4.04 x1020 N 2O5 molecules  = 6.7087x10–4 mol N2O5  6.022x1023 N O molecules  2 5  





 108.02 g N 2O5  Mass (g) of N2O5 = 6.7087x104 mol N 2O5   = 0.072467 g= 0.0725 g N2O5  1 mol N 2O5  c) The correct formula for this ionic compound is NaClO 4; Na has a charge of +1 (Group 1 ion) and the perchlorate ion is ClO4– . M of NaClO4 = (1• M of Na) + (1 •M of Cl) + (4 •M of O) = (1 •22.99 g/mol Na) + (1 •35.45 g/mol Cl) + (4 •16.00 g/mol O) = 122.44 g/mol of NaClO4  1 mol NaClO 4  Amount (mol) of NaClO4 = 78.9 g NaClO 4   = 0.644397 mol= 0.644 mol NaClO4  122.44 g NaClO 4 





 6.022 x1023 formula units NaClO 4  Formula units of NaClO4 =  0.644397 mol NaClO 4     1 mol NaClO 4   = 3.88056x1023 formula units= 3.88x1023 formula unit NaClO4   1 Na  ion d) Number of Na+ ions = 3.88056x1023 formula units NaClO4   1 formula unit NaClO  4   = 3.88x1023 Na+ ions   1 ClO4 ion Number of ClO4– ions = 3.88056x1023 formula units NaClO4   1 formula unit NaClO  4   = 3.88x1023 ClO4– ions   1 Cl atom Number of Cl atoms = 3.88056x1023 formula units NaClO4    1 formula unit NaClO4 













= 3.88x1023 Cl atoms Silberberg, Amateis, Venkateswaran, Chen, Chemistry: The Molecular Nature of Matter and Change, 3rd Canadian Edition Page 3-61 Instructor‘s Solution Manual © Copyright 2021 McGraw-Hill Ryerson Ltd.

  4 O atoms Number of O atoms = 3.88056x1023 formula units NaClO 4    1 formula unit NaClO 4  = 1.55x1024 O atoms



3.17



Plan: The formula of each compound must be determined from its name. The molar mass for each formula comes from the formula and atomic masses from the periodic table. Determine the molar mass of each substance, then perform the appropriate molar conversions. In part a), multiply the amount (mol) by the molar mass of the compound to find the mass of the sample. In part b), divide the number of molecules by Avogadro‘s number to find amount (mol); multiply the amount (mol) by the molar mass to obtain the mass. In part c), divide the mass by the molar mass to find amount (mol) of compound and multiply amount (mol) by Avogadro‘s number to find the number of formula units. In part d), use the fact that each formula unit contains 2 Li ions, 1 sulfate ion, 1 S atom, and 4 O atoms. Solution: a) Sulfate is a polyatomic anion with the formula, SO42–. Chromium(III) indicates Cr3+. Decahydrate indicates 10 water molecules (―waters of hydration‖). The correct formula for this ionic compound is Cr 2(SO4)3•10H2O. M of Cr2(SO4)3•10H2O = (2 •M of Cr) + (3 •M of S) + (22 •M of O) + (20 •M of H) = (2 •52.00 g/mol Cr) + (3 •32.07 g/mol S) + (22 •16.00 g/mol O) + (20 •1.008 g/mol H) = 572.4 g/mol of Cr2(SO4)3•10H2O  572.4 g  Mass (g) of Cr2(SO4)3•10H2O = 8.42 mol Cr2 (SO4 )3 10H 2O     mol  = 4819.608 g= 4.82x103 g Cr2(SO4)3•10H2O b) Dichlorine heptoxide has the formula Cl2O7. Di- indicates 2 Cl atoms and hepta- indicates 7 O atoms. M of Cl2O7 = (2 •M of Cl) + (7 •M of O) = (2 •35.45 g/mol Cl) + (7 •16.00 g/mol O) = 182.9 g/mol of Cl2O7   1 mol Amount (mol) of Cl2O7 = 1.83x1024 molecules Cl 2O7   = 3.038858 mol Cl2O7 23  6.022 x10 molecules 

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

 182.9 g Cl2 O7  2 Mass (g) of Cl2O7 = 3.038858 mol Cl2 O7   = 555.807 g= 5.56x10 g Cl2O7 1 mol   c) The correct formula for this ionic compound is Li2SO4; Li has a charge of +1 (Group 1 ion) and the sulfate ion is SO42– . M of Li2SO4 = (2 •M of Li) + (1 •M of S) + (4 •M of O) = (2 •6.941 g/mol Li) + (1 •32.07 g/mol S) + (4 •16.00 g/mol O) = 109.95 g/mol of Li2SO4  1 mol Li 2SO 4  Amount (mol) of Li2SO4 = 6.2 g Li 2SO 4   = 0.056389mol = 0.056 mol Li2SO4  109.95 g Li 2SO 4 

 6.022 x1023 FU  formula unit of Li2SO4 =  0.056389 mol Li 2SO4    1 mol Li SO  2 4   22 22 = 3.3957x10 formula unit = 3.4x10 formula unit Li2SO4   2 Li  ions d) Number of Li+ ions = 3.3957x1022 formula units Li 2SO4   1 formula unit Li SO  2 4   = 6.7914x1022 ions= 6.8x1022 Li+ ions   1 SO42  ion Number of SO42– ions = 3.3957x1022 formula units Li 2SO4   1 formula unit Li SO  2 4   22 22 2– = 3.3957x10 ions= 3.4x10 SO4 ions   1 S atom Number of S atoms = 3.3957x1022 formula units Li 2SO 4    1 formula unit Li 2SO 4 









= 3.3957x1022 atoms= 3.4x1022 S atoms

  4 O atoms Number of O atoms = 3.3957x1022 formula units Li 2SO 4    1 formula unit Li 2SO 4  = 1.3583x1023 atoms= 1.4x1023 O atoms

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3.18



Plan: Determine the formula and the molar mass of each compound. The formula gives the relative number of amount (mol) of each element present. Multiply the amount (mol) of each element by its molar mass to find the total mass of element total mass of element in 1 mole of compound. Mass percent = 100 . molar mass of compound Solution: a) Ammonium bicarbonate is an ionic compound consisting of ammonium ions, NH 4+ and bicarbonate ions, HCO3–. The formula of the compound is NH4HCO3. M of NH4HCO3 = (1 •M of N) + (5 •M of H) + (1 •M of C) + (3 •M of O) = (1 •14.01 g/mol N) + (5 •1.008 g/mol H) + (1 •12.01 g/mol C) + (3 •16.00 g/mol O) = 79.06 g/mol of NH4HCO3 There are 5 moles of H in 1 mole of NH4HCO3.  1.008 g H  Mass (g) of H = 5 mol H   = 5.040 g H  1 mol H  total mass H 5.040 g H 100  = 100  = 6.374905 %= 6.375% H molar mass of compound 79.06 g NH 4 HCO3 b) Sodium dihydrogen phosphate heptahydrate is a salt that consists of sodium ions, Na +, dihydrogen phosphate ions, H2PO4–, and seven waters of hydration. The formula is NaH2PO4•7H2O. Note that the waters of hydration are included in the molar mass. M of NaH2PO4•7H2O = (1 •M of Na) + (16 •M of H) + (1 •M of P) + (11 •M of O) = (1 •22.99 g/mol Na) + (16 •1.008 g/mol H) + (1 •30.97 g/mol P) + (11 •16.00 g/mol O) = 246.09 g/mol NaH2PO4•7H2O There are 11 moles of O in 1 mole of NaH2PO4•7H2O.  16.00 g O  Mass (g) of O = 11 mol O   = 176.00 g O  1 mol O 

Mass percent =

3.19

total mass O 176.00 g O 100%  = 100%  molar mass of compound 246.09 g NaH 2 PO 4 7H 2O = 71.51855 %= 71.52% O

Plan: Determine the formula and the molar mass of each compound. The formula gives the relative amount (mol) of each element present. Multiply the amount (mol) of each element by its molar mass to find the total mass of total mass of element element in 1 mole of compound. Mass percent = 100 . molar mass of compound Solution: a) Strontium periodate is an ionic compound consisting of strontium ions, Sr 2+ and periodate ions, IO4–. The formula of the compound is Sr(IO4)2. M of Sr(IO4)2 = (1 •M of Sr) + (2 •Mof I) + (8 •M of O) = (1 •87.62 g/mol Sr) + (2 •126.9 g/mol I) + (8 •16.00 g/mol O) = 469.4 g/mol of Sr(IO4)2 There are 2 moles of I in 1 mole of Sr(IO4)2.  126.9 g I  Mass (g) of I = 2 mol I   = 253.8 g I  1 mol I  total mass I 253.8 g I 100%  = 100%  = 54.0690% = 54.07% I molar mass of compound 469.4 g Sr(IO 4 ) 2 b) Potassium permanganate is an ionic compound consisting of potassium ions, K + and permanganate ions, MnO4–. The formula of the compound is KMnO4. M of KMnO4 = (1 •M of K) + (1 •M of Mn) + (4 •M of O)

Mass percent =

= (1 •39.10 g/mol K) + (1 •54.94 g/mol Mn) + (4 •16.00 g/mol O) = 158.04 g/mol of KMnO4 There is 1 mole of Mn in 1 mole of KMnO4.  54.94 g Mn  Mass (g) of Mn = 1 mol Mn   = 54.94 g Mn  1 mol Mn  Mass percent =

3.20

total mass Mn 54.94 g Mn 100%  = 100%  molar mass of compound 158.04 g KMnO 4 = 34.76335% = 34.76% Mn

Plan: Determine the formula and the molar mass of each compound. The formula gives the relative amount (mol) of each element present. Multiply the amount (mol) of each element by its molar mass to find the total mass of total mass of element element in 1 mole of compound. Mass fraction = . molar mass of compound Solution: a) Cesium acetate is an ionic compound consisting of Cs+ cations and C2H3O2– anions. (Note that the formula for acetate ions can be written as either C2H3O2– or CH3COO–.) The formula of the compound is CsC2H3O2. M of CsC2H3O2 = (1 •M of Cs) + (2 •M of C) + (3 •M of H) + (2 •M of O) = (1 •132.9 g/mol Cs) + (2 •12.01 g/mol C) + (3 •1.008 g/mol H) + (2 •16.00 g/mol O) = 191.9 g/mol of CsC2H3O2 There are 2 moles of C in 1 mole of CsC2H3O2.  12.01 g C  Mass (g) of C = 2 mol C   = 24.02 g C  1 mol C  total mass C 24.02 g C = = 0.125169 = 0.1252 mass fraction C molar mass of compound 191.9 g CsC2 H3O 2 b) Uranyl sulfate trihydrate is is a salt that consists of uranyl ions, UO 22+, sulfate ions, SO42–, and three waters of hydration. The formula is UO2SO4•3H2O. Note that the waters of hydration are included in the molar mass. M of UO2SO4•3H2O = (1 •M of U) + (9 •M of O) + (1 •M of S) + (6 •M of H) = (1 •238.0 g/mol U) + (9 •16.00 g/mol O) + (1 •32.07 g/mol S) + (6 •1.008 g/mol H) = 420.1 g/mol of UO2SO4•3H2O There are 9 moles of O in 1 mole of UO2SO4•3H2O.  16.00 g O  Mass (g) of O = 9 mol O   = 144.0 g O  1 mol O 

Mass fraction =

Mass fraction = 3.21

total mass O 144.0 g O = = 0.3427755 = 0.3428 mass fraction O molar mass of compound 420.1 g UO 2SO 4 3H 2 O

total mass Cl 70.90 g Cl = = 0.342545 = 0.3425 mass fraction Cl molar mass of compound 206.98 g Ca(ClO3 ) 2 b) Dinitrogen trioxide has the formula N2O3. Di- indicates 2 N atoms and triindicates 3 O atoms. M of N2O3 = (2 •M of N) + (3 •M of O) = (2 •14.01 g/mol N) + (3 •16.00 g/mol O) = 76.02 g/mol of N2O3 There are 2 moles of N in 1 mole of N2O3.  14.01 g N  Mass (g) of N = 2 mol N   = 28.02 g N  1 mol N 

Mass fraction =

Mass fraction = 3.22

total mass N 28.02 g N = = 0.368587 = 0.3686 mass fraction N molar mass of compound 76.02 g N 2 O3

Plan: Divide the mass given by the molar mass of O2 to find amount (mol). Since 1 mole of oxygen molecules contains 2 moles of oxygen atoms, multiply the amount (mol) by 2 to obtain amount (mol) of atoms and then multiply by Avogadro‘s number to obtain the number of atoms. Solution:  1 mol O 2  Amount (mol) of O2 = 38.0 g O 2   = 1.1875 mol O2  32.00 g O 2   2 mol O atoms  Amount (mol) of O atoms = 1.1875 mol O 2   = 2.375 mol O atoms  1 mol O 2 

 6.022x1023 O atoms  Number of O atoms =  2.375 mol O atoms   = 1.430225x1024 = 1.43x1024 O atoms  1 mol O atoms    3.23

Plan: Determine the formula of cisplatin from the figure, and then calculate the molar mass from the formula. Divide the mass given by the molar mass to find amount (mol) of cisplatin. Since 1 mole of cisplatin contains 6 moles of hydrogen atoms, multiply the amount (mol) given by 6 to obtain amount (mol) of hydrogen and then multiply by Avogadro‘s number to obtain the number of atoms. Solution: The formula for cisplatin is Pt(Cl)2(NH3) 2. M of Pt(Cl)2(NH3) 2 = (1 •M of Pt) + (2 •M of Cl) + (2 •M of N) + (6 •M of H) = (1 •195.1 g/mol Pt) + (2 •35.45 g/mol Cl) + (2 •14.01 g/mol N) + (6 •1.008 g/mol H) = 300.1 g/mol of Pt(Cl)2(NH3) 2  1 mol cisplatin  a) Amount (mol) of cisplatin = 285.3 g cisplatin   = 0.9506831 mol= 0.9507 mol cisplatin  300.1 g cisplatin   6 mol H  b) Amount (mol) of H atoms = 0.98 mol cisplatin   = 5.88 mol H atoms 1 mol cisplatin  

 6.022 x1023 H atoms  Number of H atoms =  5.88 mol H atoms   = 3.540936x1024 atoms= 3.5x1024 H atoms  1 mol H atoms   

3.24

Plan: Determine the formula of allyl sulfide from the figure, and then calculate the molar mass from the formula. In part a), multiply the given amount in moles by the molar mass to find the mass of the sample. In part b), divide the given mass by the molar mass to find amount (mol) of compound. Since 1 mole of compound contains 6 moles of carbon atoms, multiply the amount (mol) of compound by 6 to obtain amount (mol) of carbon and then multiply by Avogadro‘s number to obtain the number of atoms. Solution: The formula, from the figure, is (C3H5)2S. M of (C3H5)2S = (6 •M of C) + (10 •M of H) + (1 •M of S) = (6 •12.01 g/mol C) + (10 •1.008 g/mol H) + (1 •32.07 g/mol N) = 114.21 g/mol of (C3H5)2S

 114.21 g allyl sulfide  a) Mass (g) of allyl sulfide =  2.63 mol allyl sulfide    = 300.3723 g= 300. g allyl sulfide  1 mol allyl sulfide   1 mol (C3 H5 ) 2 S  b) Amount (mol) of allyl sulfide =  35.7 g (C3 H 5 ) 2 S    = 0.312582 mol allyl sulfide  114.21 g (C3 H 5 ) 2 S    6 mol C Amount (mol) of C atoms =  0.312582 mol (C3H 5 ) 2 S    = 1.8755 mol C atoms  1 mol (C3 H 5 ) 2 S 

 6.022 x1023 C atoms  Number of C atoms = 1.8755 mol C atoms   = 1.129426x1024 atoms= 1.13x1024 C atoms  1 mol C atoms   

3.25

Plan: Determine the molar mass of rust. Convert mass in kg to mass in g and divide by the molar mass to find the amount (mol) of rust. Since each mole of rust contains 1 mole of Fe2O3, multiply the amount (mol) of rust by 1 to obtain amount (mol) of Fe2O3. Multiply the amount (mol) of Fe2O3 by 2 to obtain amount (mol) of Fe (1:2 Fe2O3:Fe mole ratio) and multiply by the molar mass of Fe to convert to mass. Solution: a) M of Fe2O3•4H2O = (2 •M of Fe) + (7 •M of O) + (8 •M of H) = (2 •55.85 g/mol Fe) + (7 •16.00 g/mol O) + (8 •1.008 g/mol H) = 231.76 g/mol  103 g  Mass (g) of rust =  45.2 kg rust   = 4.52x104 g  1 kg     1 mol rust  Amount (mol) of rust = 4.52x104 g rust   = 195.029 mol= 195 mol rust  231.76 g rust  b) The formula shows that there is 1 mole of Fe2O3 for every mole of rust, so there are also 195 mol of Fe2O3.  2 mol Fe  c) Amount (mol) of iron = 195.029 mol Fe 2 O3    = 390.058 mol Fe  1 mol Fe 2 O3 





 55.85 g Fe  4 Mass (g) of iron =  390.058 mol Fe    = 21784.74 g= 2.18x10 g Fe  1 mol Fe 

3.26

Plan: Determine the molar mass of propane. Divide the given mass by the molar mass to find the amount (mol). Since each mole of propane contains 3 moles of carbon, multiply the amount (mol) of propane by 3 to obtain amount (mol) of C atoms. Multiply the amount (mol) of C by its molar mass to obtain mass of carbon. Solution: a) The formula of propane is C3H8. M of C3H8 = (3 •M of C) + (8 •M of H) = (3 •12.01 g/mol C) + (8•1.008 g/mol H) = 44.09 g/mol  1 mol C3 H8  Amount (mol) of C3H8 =  85.5 g C3 H8    = 1.939215 mol= 1.94 mol C3H8  44.09 g C3 H8   3 mol C  b) Amount (mol) of C = 1.939215 mol C3H8    = 5.817645 mol C  1 mol C3 H8   12.01 g C  Mass (g) of C =  5.817645 mol C    = 69.86992 g= 69.9 g C  1 mol C 

3.27

Plan: Determine the formula and the molar mass of each compound. The formula gives the relative amount (mol) of nitrogen present. Multiply the amount (mol) of nitrogen by its molar mass to find the total mass of nitrogen in 1 mole of compound. Divide the total mass of nitrogen by the molar mass of compound and multiply by 100 to  mol N  molar mass N  determine mass percent. Mass percent = 100%  . Then rank the values in order of molar mass of compound decreasing mass percent N. Solution:

Name Potassium nitrate Ammonium nitrate Ammonium sulfate Urea

Formula Molar Mass (g/mol) KNO3 101.11 NH4NO3 80.05 (NH4)2SO4 132.15 CO(NH2)2 60.06 1 mol N  14.01 g/mol N  x 100% = 13.856196 %= 13.86% N Mass % N in potassium nitrate = 101.11 g/mol Mass % N in ammonium nitrate = Mass % N in ammonium sulfate =

 2 mol N 14.01 g/mol N  80.05 g/mol

 2 mol N  14.01 g/mol N  132.15 g/mol

 2 mol N 14.01 g/mol N 

Mass % N in urea =

x 100% = 21.20318 %= 21.20% N

x 100% = 46.6533 %= 46.65% N

60.06 g/mol Rank is CO(NH2)2 > NH4NO3 > (NH4)2SO4 > KNO3 3.28

x 100% = 35.003123% = 35.00% N

Plan: The volume must be converted from cubic metres to cubic centimetres. The volume and the density will give the mass of galena which is then divided by molar mass to obtain amount (mol). Part b) requires a conversion from cubic decimetres to cubic centimetres. The density allows a change from volume in cubic centimetres to mass which is then divided by the molar mass to obtain amount (mol); the amount in moles is multiplied by Avogadro‘s number to obtain formula units of PbS which is also the number of Pb atoms due to the 1:1 PbS:Pb mole ratio. Solution: Lead(II) sulfide is composed of Pb2+ and S2– ions and has a formula of PbS. M of PbS = (1 •M of Pb) + (1 •M of S) = (1 •207.2 g/mol Pb) + (1 •32.07 g/mol S) = 239.3 g/mol 3

 100 cm  3 a) Volume (cm3) = 1.00 m3 PbS   = 1,000,000 cm  1m 









 7.46 g PbS  6 Mass (g) of PbS = 1x106 cm3 PbS   = 7.46x10 g PbS  1 cm3   1 mol PbS  4 Amount (mol) of PbS = 7.46x106 g PbS   = 31,174.26 mol = 3.12x10 mol PbS  239.3 g PbS 





  0.1 m 3   1 cm 3   b) Volume (cm ) = 1.00 dm PbS  = 1.00x103 cm3  1 dm 3   102 m 3     7.46 g PbS   Mass (g) of PbS = 1.00x103 cm3 PbS   = 7460 g PbS 3  1 cm   1 mol PbS  Amount (mol) of PbS =  7460 g PbS   = 31.17426 mol PbS  239.3 g PbS  3









 1 mol Pb  Amount (mol) of Pb =  31.17426 mol PbS   = 31.17426 mol Pb  1 mol PbS  Number of lead atoms =  6.022x1023 Pb atoms  25 25  31.17426 mol Pb    = 1.87731x10 atoms= 1.88x10 Pb atoms 1 mol Pb   3.29

Plan: If the molecular formula for hemoglobin (Hb) were known, the number of Fe 2+ ions in a molecule of hemoglobin could be calculated. It is possible to calculate the mass of iron from the percentage of iron and the molar mass of the compound. Assuming you have 1 mole of hemoglobin, take 0.33% of its molar mass as the

mass of Fe in that 1 mole. Divide the mass of Fe by its molar mass to find amount (mol) of Fe in 1 mole of hemoglobin which is also the number of ions in 1 molecule. Solution:  0.33% Fe   6.8 x104 g  Mass of Fe =   = 224.4 g Fe    100% Hb   mol   1 mol Fe  2+ Amount (mol) of Fe =  224.4 g Fe    = 4.0179 mol= 4.0 mol Fe /mol Hb 55.85 g Fe   Thus, there are 4 Fe2+/molecule Hb.

3.30

Plan: Review the definitions of empirical and molecular formulas. Solution: An empirical formula describes the type and simplest ratio of the atoms of each element present in a compound, whereas a molecular formula describes the type and actual number of atoms of each element in a molecule of the compound. The empirical formula and the molecular formula can be the same. For example, the compound formaldehyde has the molecular formula, CH2O. The carbon, hydrogen, and oxygen atoms are present in the ratio of 1:2:1. The ratio of elements cannot be further reduced, so formaldehyde‘s empirical formula and molecular formula are the same. Acetic acid has the molecular formula, C2H4O2. The carbon, hydrogen, and oxygen atoms are present in the ratio of 2:4:2, which can be reduced to 1:2:1. Therefore, acetic acid‘s empirical formula is CH2O, which is different from its molecular formula. Note that the empirical formula does not uniquely identify a compound, because acetic acid and formaldehyde share the same empirical formula but are different compounds.

3.31

1. Compositional data may be given as the mass of each element present in a sample of compound. 2 Compositional data may be provided as mass percents of each element in the compound. 3. Compositional data obtained through combustion analysis provides the mass of C and H in a compound.

3.32

Plan: Remember that the molecular formula tells the actual amount (mol) of each element in one mole of compound. Solution: a) No, this information does not allow you to obtain the molecular formula. You can obtain the empirical formula from the f amount (mol) of each type of atom in a compound, but not the molecular formula. b) Yes, you can obtain the molecular formula from the mass percentages and the total number of atoms. Plan: 1) Assume a 100.0 g sample and convert masses (from the mass % of each element) to amount (mol) using molar mass. 2) Identify the element with the lowest f amount (mol) and use this number to divide into the number of amount (mol) for each element. You now have at least one elemental mole ratio (the one with the smallest number of moles) equal to 1.00 and the remaining mole ratios that are larger than one. 3) Examine the numbers to determine if they are whole numbers. If not, multiply each number by a whole-number factor to get whole numbers for each element. You will have to use some judgment to decide when to round. Write the empirical formula using these whole numbers. 4) Check the total number of atoms in the empirical formula. If it equals the total number of atoms given then the empirical formula is also the molecular formula. If not, then divide the total number of atoms given by the total number of atoms in the empirical formula. This should give a whole number. Multiply the number of atoms of each element in the empirical formula by this whole number to get the molecular formula. If you do not get a whole number when you divide, return to step 3 and revise how you multiplied and rounded to get whole numbers for each element.

Roadmap: Mass (g) of each element (express mass percent

directly as grams)

Divide by M (g/mol) Amount (mol) of each element

Use amount of moles as subscripts Preliminary empirical formula

Change to integer subscripts Empirical formula

Divide total number of atoms in molecule by the number of atoms in the empirical formula and multiply the empirical formula by that factor Molecular formula c) Yes, you can determine the molecular formula from the mass percent and the number of atoms of one element in a compound. Plan: 1) Follow steps 1–3 in part b). 2) Compare the number of atoms given for the one element to the number in the empirical formula. Determine the factor the number in the empirical formula must be multiplied by to obtain the given number of atoms for that element. Multiply the empirical formula by this number to get the molecular formula. Roadmap: (Same first three steps as in b). Empirical formula

Divide the number of atoms of the one element in the molecule by the number of atoms of that element in the empirical formula and multiply the empirical formula by that factor Molecular formula

d) No, the mass % will only lead to the empirical formula. e) Yes, a structural formula shows all the atoms in the compound. Plan: Count the number of atoms of each type of element and record as the number for the molecular formula. Roadmap: Structural formula

Count the number of atoms of each element and use these numbers as subscripts Molecular formula 3.33

MgCl2 is an empirical formula, since ionic compounds such as MgCl2 do not contain molecules.

3.34

Plan: Examine the number of atoms of each type in the compound. Divide all atom numbers by the common factor that results in the lowest whole-number values. Add the molar masses of the atoms to obtain the empirical formula mass. Solution: a) C2H4 has a ratio of 2 carbon atoms to 4 hydrogen atoms, or 2:4. This ratio can be reduced to 1:2, so that the empirical formula is CH2. The empirical formula mass is 12.01 g/mol C + 2(1.008 g/mol H) = 14.03 g/mol. b) The ratio of atoms is 2:6:2, or 1:3:1. The empirical formula is CH3O and its empirical formula mass is 12.01 g/mol C + 3(1.008 g/mol H) + 16.00 g/mol O = 31.03 g/mol. c) Since, the ratio of elements cannot be further reduced, the molecular formula and empirical formula are the same, N2O5. The formula mass is 2(14.01 g/mol N) + 5(16.00 g/mol O) = 108.02 g/mol. d) The ratio of elements is 3 atoms of barium to 2 atoms of phosphorus to 8 atoms of oxygen, or 3:2:8. This ratio cannot be further reduced, so the empirical formula is also Ba3(PO4)2, with a formula mass of 3(137.3 g/mol Ba) + 2(30.97 g/mol P) + 8(16.00 g/mol O) = 601.8 g/mol. e) The ratio of atoms is 4:16, or 1:4. The empirical formula is TeI4, and the formula mass is 127.6 g/mol Te + 4(126.9 g/mol I) = 635.2 g/mol.

3.35

Plan: Examine the number of atoms of each type in the compound. Divide all atom numbers by the common factor that results in the lowest whole-number values. Add the molar masses of the atoms to obtain the empirical formula mass. Solution: a) C4H8 has a ratio of 4 carbon atoms to 8 hydrogen atoms, or 4:8. This ratio can be reduced to 1:2, so that the empirical formula is CH2. The empirical formula mass is 12.01 g/mol C + 2(1.008 g/mol H) = 14.03 g/mol. b) C3H6O3 has a ratio of atoms of 3:6:3, or 1:2:1. The empirical formula is CH2O and its empirical formula mass is 12.01 g/mol C + 2(1.008 g/mol H) + 16.00 g/mol O = 30.03 g/mol. c) P4O10 has a ratio of 4 P atoms to 10 O atoms, or 4:10. This ratio can be reduced to 2:5, so that the empirical formula is P2O5. The empirical formula mass is 2(30.97 g/mol P) + 5(16.00 g/mol O) = 141.94 g/mol. d) Ga2(SO4)3 has a ratio of 2 atoms of gallium to 3 atoms of sulfur to 12 atoms of oxygen, or 2:3:12. This ratio cannot be further reduced, so the empirical formula is also Ga2(SO4)3, with a formula mass of 2(69.72 g/mol Ga) + 3(32.07 g/mol S) + 12(16.00 g/mol O) = 427.6 g/mol. e) Al2Br6 has a ratio of atoms of 2:6, or 1:3. The empirical formula is AlBr3, and the formula mass is 26.98 g/mol Al + 3(79.90 g/mol Br) = 266.7 g/mol.

3.36

The compound has 2 sulfur atoms and 2 chlorine atoms and a molecular formula of S2Cl2. The compound‘s name is disulfur dichloride. Sulfur is named first since it has the lower group number. The prefix di- is used for both elements since there are 2 atoms of each element. The empirical formula is S 2 Cl 2 or SCl. 2

M of S2Cl2 = (2 •M of S) + (2 •M of Cl) = (2 •32.07 g/mol S) + (2 •35.45 g/mol Cl) = 135.04 g/mol 3.37

Plan: Use the chemical symbols and count the atoms of each type to obtain the molecular formula. Divide the molecular formula by the largest common factor to give the empirical formula. Use nomenclature rules to derive the name. This compound is composed of two nonmetals. The naming rules for binary covalent compounds indicate that the element with the lower group number is named first. Greek numerical prefixes are used to indicate the number of atoms of each element in the compound. The molecular (formula) mass is the sum of the atomic masses of all of the atoms. Solution: The compound has 4 phosphorus atoms and 6 oxygen atoms and a molecular formula of P 4O6. The compound‘s name is tetraphosphorus hexoxide. Phosphorus is named first since it has the lower group number. The prefix tetra- is for phosphorus since there are 4 Patoms and hexa- is used for oxygen since there are 6 O atoms. The empirical formula is P4 O 6 or P2O3. 2

M of P4O6 = (4 •M of P) + (6 •M of O) = (4 •30.97 g/mol P) + (6 •16.00 g/mol O) = 219.88 g/mol 3.38

Plan: Determine the molar mass of each empirical formula. The subscripts in the molecular formula are wholenumber multiples of the subscripts in the empirical formula. To find this whole number, divide the molar mass of the compound by its empirical formula mass. Multiply each subscript in the empirical formula by the whole number. Solution: Only approximate whole-number values are needed. a) CH2 has empirical mass equal to 12.01 g/mol C + 2(1.008 g/mol C) = 14.03 g/mol  42.08 g/mol  molar mass of compound Whole-number multiple = =   =3 empirical formula mass  14.03 g/mol  Multiplying the subscripts in CH2 by 3 gives C3H6. b) NH2 has empirical mass equal to 14.01 g/mol N + 2(1.008 g/mol H) = 16.03 g/mol  32.05 g/mol  molar mass of compound Whole-number multiple = =  = 2 empirical formula mass  16.03 g/mol  Multiplying the subscripts in NH2 by 2 gives N2H4. c) NO2 has empirical mass equal to 14.01 g/mol N + 2(16.00 g/mol O) = 46.01 g/mol  92.02 g/mol  molar mass of compound Whole-number multiple = =  =2 empirical formula mass  46.01 g/mol  Multiplying the subscripts in NO2 by 2 gives N2O4. d) CHN has empirical mass equal to 12.01 g/mol C + 1.008 g/mol H + 14.01 g/mol N = 27.03 g/mol  135.14 g/mol  molar mass of compound Whole-number multiple = =  =5 empirical formula mass  27.03 g/mol  Multiplying the subscripts in CHN by 5 gives C5H5N5.

3.39

Whole-number multiple =

 78.11 g/mol  molar mass of compound =  =6 empirical formula mass  13.02 g/mol 

Multiplying the subscripts in CH by 6 gives C6H6. b) C3H6O2 has empirical mass equal to 3(12.01 g/mol C) + 6(1.008 g/mol H) + 2(16.00 g/mol O) = 74.08 g/mol  74.08 g/mol  molar mass of compound Whole-number multiple = =  =1 empirical formula mass  74.08 g/mol  Multiplying the subscripts in C3H6O2 by 1 gives C3H6O2. c) HgCl has empirical mass equal to 200.6 g/mol Hg + 35.45 g/mol Cl = 236.0 g/mol  472.1 g/mol  molar mass of compound Whole-number multiple = =  =2 empirical formula mass  236.0 g/mol  Multiplying the subscripts in HgCl by 2 gives Hg2Cl2. d) C7H4O2 has empirical mass equal to 7(12.01 g/mol C) + 4(1.008 g/mol H) + 2(16.00 g/mol O) = 120.10 g/mol  240.20 g/mol  molar mass of compound Whole-number multiple = =  =2 empirical formula mass  120.10 g/mol  Multiplying the subscripts in C7H4O2 by 2 gives C14H8O4. 3.40

Plan: The empirical formula is the smallest whole-number ratio of the atoms or moles in a formula. All data must be converted to amount (mol) of an element by dividing mass by the molar mass. Divide each mole number by the smallest mole number to convert the mole ratios to whole numbers. Solution: a) 0.063 mol Cl and 0.22 mol O: preliminary formula is Cl 0.063O0.22 Converting to integer subscripts (dividing all by the smallest subscript): Cl 0.063 O 0.22 → Cl1O3.5 0.063

0.063

The formula is Cl1O3.5, which in whole numbers (x 2) is Cl2O7. b) Find amount (mol) of elements by dividing by molar mass:  1 mol Si  Amount (mol) of Si =  2.45 g Si    = 0.08722 mol Si  28.09 g Si   1 mol Cl  Amount (mol) of Cl = 12.4 g Cl    = 0.349788 mol Cl  35.45 g Cl  Preliminary formula is Si0.08722Cl0.349788 Converting to integer subscripts (dividing all by the smallest subscript): Si 0.08722 Cl 0.349788 → Si1Cl4 0.08722

0.349788

The empirical formula is SiCl4. c) Assume a 100 g sample and convert the masses to amount (mol) by dividing by the molar mass:  27.3 parts C by mass   1 mol C  Amount (mol) of C = 100 g    = 2.2731 mol C   100 parts by mass   12.01 g C   72.7 parts O by mass   1 mol O  Amount (mol) of O = 100 g    = 4.5438 mol O   100 parts by mass   16.00 g O  Preliminary formula is C2.2731O4.5438 Converting to integer subscripts (dividing all by the smallest subscript): C 2.2731 O 4.5438 → C1O2 2.2731

2.2731

The empirical formula is CO2. 3.41

Plan: The empirical formula is the smallest whole-number ratio of the atoms or moles in a formula. All data must be converted to moles of an element by dividing mass by the molar mass. Divide each mole number by the smallest mole number to convert the mole ratios to whole numbers.

Solution: a) 0.039 mol Fe and 0.052 mol O: preliminary formula is Fe 0.039O0.052 Converting to integer subscripts (dividing all by the smallest subscript): Fe 0.039 O 0.052 → Fe1O1.33 0.039

0.039

The formula is Fe1O1.33, which in whole numbers (x 3) is Fe3O4. b) Find amount (mol) of elements by dividing by molar mass:  1 mol P  Amount (mol) of P =  0.903 g P    = 0.029157 mol P  30.97 g P   1 mol Br  Amount (mol) of Br =  6.99 g Br    = 0.087484 mol Br  79.90 g Br  Preliminary formula is P0.029157Br0.087484 Converting to integer subscripts (dividing all by the smallest subscript): P0.029157 Br0.087484 → P1Br3 0.029157

0.029157

The empirical formula is PBr3. c) Assume a 100 g sample and convert the masses to moles by dividing by the molar mass: 79.9% C and 100 – 79.9 = 20.1% H  79.9 parts C by mass   1 mol C  Amount (mol) of C = 100 g    = 6.6528 mol C   100 parts by mass   12.01 g C   20.1 parts H by mass   1 mol H  Amount (mol) of H = 100 g    = 19.940 mol H   100 parts by mass   1.008 g H  Preliminary formula is C6.6528H19.940 Converting to integer subscripts (dividing all by the smallest subscript): C 6.6528 H 19.940 → C1H3 6.6528

6.6528

The empirical formula is CH3. 3.42

Plan: The percent oxygen is 100% minus the percent nitrogen. Assume 100 grams of sample, and then the amount (mol) of each element may be found by dividing the mass of each element by its molar mass. Divide each of the moles by the smaller value, and convert to whole numbers to get the empirical formula. The subscripts in the molecular formula are whole-number multiples of the subscripts in the empirical formula. To find this whole number, divide the molar mass of the compound by its empirical formula mass. Multiply each subscript in the empirical formula by the whole number. Solution: a) % O = 100% − % N = 100% − 30.45% N = 69.55% O Assume a 100 g sample and convert the masses to moles by dividing by the molar mass:  30.45 parts N by mass   1 mol N  Amount (mol) of N = 100 g    = 2.1734 mol N   100 parts by mass   14.01 g N   69.55 parts O by mass   1 mol O  Amount (mol) of O = 100 g    = 4.3469 mol O   100 parts by mass   16.00 g O  Preliminary formula is N2.1734O4.3469 Converting to integer subscripts (dividing all by the smallest subscript): N 2.1734 O 4.3469 → N1O2 2.1734

2.1734

The empirical formula is NO2. b) Formula mass of empirical formula = 14.01 g/mol N + 2(16.00 g/mol O) = 46.01 g/mol  90 g/mol  molar mass of compound Whole-number multiple = =   =2 empirical formula mass  46.01 g/mol  Silberberg, Amateis, Venkateswaran, Chen, Chemistry: The Molecular Nature of Matter and Change, 3rd Canadian Edition Page 3-73 Instructor‘s Solution Manual © Copyright 2021 McGraw-Hill Ryerson Ltd.

Multiplying the subscripts in NO2 by 2 gives N2O4 as the molecular formula. Note: Only an approximate value of the molar mass is needed. 3.43

Plan: The percent silicon is 100% minus the percent chorine. Assume 100 grams of sample, and then the amount (mol) of each element may be found by dividing the mass of each element by its molar mass. Divide each of the amount (mol) by the smaller value, and convert to whole numbers to get the empirical formula. The subscripts in the molecular formula are whole-number multiples of the subscripts in the empirical formula. To find this whole number, divide the molar mass of the compound by its empirical formula mass. Multiply each subscript in the empirical formula by the whole number. Solution: a) % Si = 100% − % Cl = 100% − 79.1% Cl = 20.9% Si Assume a 100 g sample and convert the masses to moles by dividing by the molar mass:  20.9 parts Si by mass   1 mol Si  Amount (mol) of Si = 100 g    = 0.7440 mol Si   100 parts by mass   28.09 g Si   79.1 parts Cl by mass   1 mol Cl  Amount (mol) of Cl = 100 g    = 2.2313 mol Cl   100 parts by mass   35.45 g Cl  Preliminary formula is Si0.7440Cl2.2313 Converting to integer subscripts (dividing all by the smallest subscript): Si 0.7440 Cl 2.2313 → Si1Cl3 0.7440

0.7440

The empirical formula is SiCl3. b) Formula mass of empirical formula = 28.09 g/mol Si + 3(35.45 g/mol Cl) = 134.44 g/mol  269 g/mol  molar mass of compound Whole-number multiple = =   =2 empirical formula mass  134.44 g/mol  Multiplying the subscripts in SiCl3 by 2 gives Si2Cl6 as the molecular formula. 3.44

Plan: The amount (mol) of the metal is known, and the amount (mol) of fluorine atoms may be found in part a) from the M:F mole ratio in the compound formula. In part b), convert amount (mol) of F atoms to mass and subtract the mass of F from the mass of MF2 to find the mass of M. In part c), divide the mass of M by amount (mol) of M to determine the molar mass of M which can be used to identify the element. Solution: a) Determine the amount (mol) of fluorine.  2 mol F  Amount (mol) of F = 0.600 mol M   = 1.20 mol F  1 mol M  b) Determine the mass of M.  19.00 g F  Mass of F = 1.20 mol F   = 22.8 g F  1 mol F  Mass (g) of M = MF2(g) – F(g) = 46.8 g – 22.8 g = 24.0 g M c) The molar mass is needed to identify the element. 24.0 g M Molar mass of M = = 40.0 g/mol 0.600 mol M The metal with the closest molar mass to 40.0 g/mol is calcium.

3.45

Plan: The amount (mol) of the metal oxide is known, and the amount (mol) of oxygen atoms may be found in part a) from the compound:oxygen mole ratio in the compound formula. In part b), convert amount (mol) of O atoms to mass and subtract the mass of O from the mass of M2O3 to find the mass of M. In part c), find amount (mol) of M from the compound:M mole ratio and divide the mass of M by amount (mol) of M to determine the molar mass of M which can be used to identify the element. Solution: a) Determine the amount (mol) of oxygen.

 3 mol O  Amount (mol) of O = 0.370 mol M 2 O3   = 1.11 mol O  1 mol M 2 O3  b) Determine the mass of M.  16.00 g O  Mass of O = 1.11 mol O   = 17.76 g O  1 mol O 

Mass(g) of M = M2O3(g) – O(g) = 55.4 g (M + O) – 17.76 = 37.64 = 37.6 g M c) First, the number of moles of M must be calculated.  2 mol M  Amount (mol) M = 0.370 mol M 2 O3   = 0.740 mol M  1 mol M 2 O3  The molar mass is needed to identify the element. 37.6 g M Molar mass of M = = 50.86 g/mol 0.740 mol M The metal with the closest molar mass to 50.9 g/mol is vanadium. 3.46

Plan: The empirical formula is the smallest whole-number ratio of the atoms or moles in a formula. Divide each mmole number by the smallest mmole value to convert the mmole ratios to whole numbers. Since all the values are given in millimoles, there is no need to convert to moles. Solution: Preliminary formula is C6.16H8.56N1.23 Converting to integer subscripts (dividing all by the smallest subscript): C 6.16 H 8.56 N1.23 → C5H7N1 1.23

1.23

The empirical formula is C5H7N. 3.47

Plan: The empirical formula is the smallest whole-number ratio of the atoms or moles in a formula. Assume 100 grams of cortisol so the percentages are numerically equivalent to the masses of each element. Convert each of the masses to moles by dividing by the molar mass of each element involved. Divide each mole number by the smallest mole number to convert the mole ratios to whole numbers. The subscripts in the molecular formula are whole-number multiples of the subscripts in the empirical formula. To find this whole number, divide the molar mass of the compound by its empirical formula mass. Multiply each subscript in the empirical formula by the whole number. Solution:  1 mol C  Amount (mol) of C =  69.6 g C    = 5.7952 mol C  12.01 g C   1 mol H  Amount (mol) of H =  8.34 g H    = 8.2738 mol H  1.008 g H   1 mol O  Amount (mol) of O =  22.1 g O    = 1.38125 mol O  16.00 g O  Preliminary formula is C5.7952H8.2738O1.38125 Converting to integer subscripts (dividing all by the smallest subscript): C 5.7952 H 8.2738 O1.38125 → C4.2H6O1 1.38125

1.38125

The carbon value is not close enough to a whole number to round the value. The smallest number that 4.20 may be multiplied by to get close to a whole number is 5. (You may wish to prove this to yourself.) All three ratios need to be multiplied by five: 5(C4.2H6O1) = C21H30O5. The empirical formula mass is = 21(12.01 g/mol C) + 30(1.008 g/mol H) + 5(16.00 g/mol O) = 362.45 g/mol  362.47 g/mol  molar mass of compound Whole-number multiple = =   =1 empirical formula mass  362.45 g/mol  The empirical formula mass and the molar mass given are the same, so the empirical and the molecular formulas are the same. The molecular formula is C21H30O5. Silberberg, Amateis, Venkateswaran, Chen, Chemistry: The Molecular Nature of Matter and Change, 3rd Canadian Edition Page 3-75 Instructor‘s Solution Manual © Copyright 2021 McGraw-Hill Ryerson Ltd.

3.48

Plan: Determine the molecular formula from the figure, and the molar mass from the molecular formula. The formula gives the relative amount (mol) of each element present. Multiply the amount (mol) of each element by its molar mass to find the total mass of element in 1 mole of compound. total mass of element Mass percent = 100 . molar mass of compound Solution: Molecular formula = C8H9NO2 Molar mass = 8(12.01 g/mol C) + 9(1.008 g/mol H) + 1(14.01 g/mol N) + 2(16.00 g/mol O) = 151.16 g/mol There are 8 moles of C in 1 mole of C8H9NO2.  12.01 g C  Mass (g) of C = 8 mol C    = 96.08 g C  1 mol C  Mass percent =

total mass C 96.08 g C 100%  = 100%  molar mass of compound 151.16 g C8 H 9 NO 2

= 63.5618% = 63.56% C There are 9 moles of H in 1 mole of C8H9NO2.  1.008 g H  Mass (g) of H =  9 mol H    = 9.072 g H  1 mol H  total mass H 9.072 g H 100%  = 100% molar mass of compound 151.16 g C8 H9 NO2 = 6.00159% = 6.002% H There is 1 mole of N in 1 mole of C8H9NO2.  14.01 g N  Mass (g) of N = 1 mol N    = 14.01 g N  1 mol N 

Mass percent =

total mass N 14.01 g N 100%  = 100%  molar mass of compound 151.16 g C8 H 9 NO 2 = 9.2683% = 9.268% N There are 2 moles of O in 1 mole of C8H9NO2.  16.00 g O  Mass (g) of O =  2 mol H    = 32.00 g O  1 mol O 

Mass percent =

total mass O 32.00 g O 100%  = 100%  molar mass of compound 151.16 g C8 H 9 NO 2 = 21.1696% = 21.17% O

Mass percent =

3.49

Plan: In combustion analysis, finding the amount (mol) of carbon and hydrogen is relatively simple because all of the carbon present in the sample is found in the carbon of CO 2, and all of the hydrogen present in the sample is found in the hydrogen of H2O. Convert the mass of CO2 to moles and use the ratio between CO2 and C to find the amount (mol) and mass of C present. Do the same to find the amount (mol) and mass of H from H 2O. The amount (mol) of oxygen are more difficult to find, because additional O 2 was added to cause the combustion reaction. Subtracting the masses of C and H from the mass of the sample gives the mass of O. Convert the mass of O to moles of O. Take the moles of C, H, and O and divide by the smallest value to convert to whole numbers to get the empirical formula. Determine the empirical formula mass and compare it to the molar mass given in the problem to see how the empirical and molecular formulas are related. Finally, determine the molecular formula. Solution:  1 mol CO 2   1 mol C  Amount (mol) of C =  0.449 g CO 2     = 0.010202 mol C  44.01 g CO 2   1 mol CO 2 

 12.01 g C  Mass (g) of C =  0.010202 mol C    = 0.122526 g C  1 mol C   1 mol H 2 O  2 mol H  Amount (mol) of H =  0.184 g H 2 O     = 0.020422 mol H  18.02 g H 2 O  1 mol H 2 O   1.008 g H  Mass (g) of H =  0.020422 mol H    = 0.020585 g H  1 mol H  Mass (g) of O = Sample mass – (mass of C + mass of H) = 0.1595 g – (0.122526 g C + 0.020585 g H) = 0.016389 g O  1 mol O  Amount (mol) of O =  0.016389 g O    = 0.0010243 mol O  16.00 g O 

Preliminary formula = C0.010202H0.020422O0.0010243 Converting to integer subscripts (dividing all by the smallest subscript): C 0.010202 H 0.020422 O 0.0010243 → C10H20O1 0.0010243

0.0010243

Empirical formula = C10H20O Empirical formula mass = 10(12.01 g/mol C) + 20(1.008 g/mol H) + 1(16.00 g/mol O) = 156.26 g/mol The empirical formula mass is the same as the given molar mass so the empirical and molecular formulas are the same. The molecular formula is C10H20O. 3.50

A balanced chemical equation describes: 1) The identities of the reactants and products. 2) The molar (and molecular) ratios by which reactants form products. 3) The physical states of all substances in the reaction.

3.51

In a balanced equation, the total mass of the reactants is equal to the total mass of the products formed in the reaction. Thus, the law of mass conversation is obeyed.

3.52

Students I and II are incorrect. Both students changed a given formula. Only coefficients should be changed when balancing; subscripts cannot be changed. Student I failed to identify the product correctly, writing AlCl 2 instead of AlCl3. Student II used atomic chlorine instead of molecular chlorine as a reactant. Student III followed the correct process, changing only coefficients.

3.53

Plan: Examine the diagram and label each formula. We will use A for red atoms and B for green atoms. Solution: The reaction shows A2 and B2 diatomic molecules forming AB molecules. Equal numbers of A2 and B2 combine to give twice as many molecules of AB. Thus, the reaction is A2 + B2  2 AB. This is the balanced equation in b.

3.54

Balance the H next, because H is present in only one reactant and only one product. The 12 H atoms in 4H 3PO4 on the right require a coefficient of 6 in front of H2O: ___ P4O10(s) + 6H2O(l)  4H3PO4(l) Balance the O last, because it appears in both reactants and is harder to balance. There are 16 O atoms on each side: P4O10(s) + 6H2O(l)  4H3PO4(l) c) __B2O3(s) + __ NaOH(aq)  __Na3BO3(aq) + __H2O(l) Balance oxygen last because it is present in more than one place on each side of the reaction. The 2 B atoms in B2O3 on the left require a coefficient of 2 in front of Na 3BO3 on the right: __B2O3(s) + __NaOH(aq)  2Na3BO3(aq) + __H2O(l) The 6 Na atoms in 2Na3BO3 on the right require a coefficient of 6 in front of NaOH on the left: __B2O3(s) + 6NaOH(aq)  2Na3BO3(aq) + __H2O(l) The 6 H atoms in 6NaOH on the left require a coefficent of 3 in front of H 2O on the right: __B2O3(s) + 6NaOH(aq)  2Na3BO3(aq) + 3H2O(l) The oxygen is now balanced with 9 O atoms on each side: B2O3(s) + 6NaOH(aq)  2Na3BO3(aq) + 3H2O(l) d) __CH3NH2(g) + __O2(g)  __CO2(g) + __H2O(g) + __N2(g) There are 2 N atoms on the right in N2 so a coefficient of 2 is required in front of CH3NH2 on the left: 2CH3NH2(g) + __O2(g)  __CO2(g) + __H2O(g) + __N2(g) There are now 10 H atoms in 2CH3NH2 on the left so a coefficient of 5 is required in front of H 2O on the right: 2CH3NH2(g) + __O2(g)  __CO2(g) + 5H2O(g) + __N2(g) The 2 C atoms on the left require a coefficient of 2 in front of CO2 on the right: 2CH3NH2(g) + __O2(g)  2CO2(g) + 5H2O(g) + __N2(g) The 9 O atoms on the right (4 O atoms in 2CO2 plus 5 in 5H2O) require a coefficient of 9/2 in front of O 2 on the left: 2CH3NH2(g) + 9/2O2(g)  2CO2(g) + 5H2O(g) + __N2(g) Multiply all coefficients by 2 to obtain whole numbers: 4CH3NH2(g) + 9O2(g)  4CO2(g) + 10H2O(g) + 2N2(g) 3.55

Plan: Balancing is a trial-and-error procedure. Balance one element at a time, placing coefficients where needed to have the same number of atoms of a particular element on each side of the equation. The smallest whole-number coefficients should be used. Solution: a) __Cu(NO3)2(aq) + __KOH(aq)  __Cu(OH)2(s) + __ KNO3(aq) The 2 N atoms in Cu(NO3)2 on the left require a coefficient of 2 in front of KNO3 on the right: __Cu(NO3)2(aq) + __ KOH(aq)  __Cu(OH)2(s) + 2KNO3(aq) The 2 K atoms in 2KNO3 on the right require a coefficient of 2 in front of KOH on the left: __Cu(NO3)2(aq) + 2KOH(aq)  __Cu(OH)2(s) + 2KNO3(aq) There are 8 O atoms and 2 H atoms on each side: Cu(NO3)2(aq) + 2KOH(aq)  Cu(OH)2(s) + 2KNO3(aq) b) __BCl3(g) + __H2O(l)  __H3BO3(s) + __HCl(g) The 3 Cl atoms in BCl3 on the left require a coefficient of 3 in front of HCl on the right: __BCl3(g) + __H2O(l)  __H3BO3(s) + 3HCl(g) The 6 H atoms on the right (3 in H3BO3 and 3 in HCl) require a coefficient of 3 in front of H 2O on the left: __BCl3(g) + 3H2O(l)  __H3BO3(s) + 3HCl(g) There are 3 O atoms and 1 B atom on each side: BCl3(g) + 3H2O(l)  H3BO3(s) + 3HCl(g) c) __CaSiO3(s) + __HF(g)  __SiF4(g) + __CaF2(s) + __H2O(l) The 6 F atoms on the right (4 in SiF4 and 2 in CaF2) require a coefficient of 6 in front of HF on the left: __CaSiO3(s) + 6HF(g)  __SiF4(g) + __CaF2(s) + __H2O(l) The 6 H atoms in 6HF on the left require a coefficient of 3 in front of H2O on the right: __CaSiO3(s) + 6HF(g)  __SiF4(g) + __CaF2(s) + 3H2O(l) There are 1 Ca atom, 1 Si atom, and 3 O atoms on each side: CaSiO3(s) + 6HF(g)  SiF4(g) + CaF2(s) + 3H2O(l) Silberberg, Amateis, Venkateswaran, Chen, Chemistry: The Molecular Nature of Matter and Change, 3rd Canadian Edition Page 3-78 Instructor‘s Solution Manual © Copyright 2021 McGraw-Hill Ryerson Ltd.

d) __ (CN)2(g) + __H2O(l)  __H2C2O4(aq) + __NH3(g) The 2 N atoms in (CN)2 on the left requires a coefficient of 2 in front of NH 3 on the left: __ (CN)2(g) + __H2O(l)  __H2C2O4(aq) + 2NH3(g) The 4 O atoms in H2C2O4 on the right requires a coefficient of 4 in front of H 2O on the right: __ (CN)2(g) + 4H2O(l)  __H2C2O4(aq) + 2NH3(g) There are 2 C atoms and 8 H atoms on each side: (CN)2(g) + 4H2O(l)  H2C2O4(aq) + 2NH3(g) 3.56

Plan: Balancing is a trial-and-error procedure. Balance one element at a time, placing coefficients where needed to have the same number of atoms of a particular element on each side of the equation. The smallest whole-number coefficients should be used. Solution: a) __SO2(g) + __O2(g)  __SO3(g) There are 4 O atoms on the left and 3 O atoms on the right. Since there is an odd number of O atoms on the right, place a coefficient of 2 in front of SO3 for an even number of 6 O atoms on the right: __SO2(g) + __O2(g)  2SO3(g) Since there are now 2 S atoms on the right, place a coefficient of 2 in front of SO 2 on the left. There are now 6 O atoms on each side: 2SO2(g) + O2(g)  2SO3(g) b) __Sc2O3(s) + __H2O(l) __ Sc(OH)3(s) The 2 Sc atoms on the left require a coefficient of 2 in front of Sc(OH)3 on the right: __Sc2O3(s) + __H2O(l)  2Sc(OH)3(s) The 6 H atoms in 2Sc(OH)3 on the right require a coefficient of 3 in front of H 2O on the left. There are now 6 O atoms on each side: Sc2O3(s) + 3H2O(l)  2Sc(OH)3(s) c) __H3PO4(aq) + __NaOH(aq)  __Na2HPO4(aq) + __H2O(l) The 2 Na atoms in Na2HPO4 on the right require a coefficient of 2 in front of NaOH on the left: __H3PO4(aq) + 2NaOH(aq)  __Na2HPO4(aq) + __H2O(l) There are 6 O atoms on the right (4 in H3PO4 and 2 in 2NaOH); there are 4 O atoms in Na2HPO4 on the right so a coefficient of 2 in front of H 2O will result in 6 O atoms on the right: __H3PO4(aq) + 2NaOH(aq)  __Na2HPO4(aq) + 2H2O(l) Now there are 4 H atoms on each side: H3PO4(aq) + 2NaOH(aq)  Na2HPO4(aq) + 2H2O(l) d) __C6H10O5(s) + __O2(g)  __CO2(g) + __H2O(g) The 6 C atoms in C6H10O5 on the left require a coefficient of 6 in front of CO2 on the right: __C6H10O5(s) + __O2(g)  6CO2(g) + __H2O(g) The 10 H atoms in C6H10O5 on the left require a coefficient of 5 in front of H 2O on the right: __C6H10O5(s) + __O2(g)  6CO2(g) + 5H2O(g) There are 17 O atoms on the right (12 in 6CO2 and 5 in 5H2O); there are 5 O atoms in C6H10O5 so a coefficient of 6 in front of O2 will bring the total of O atoms on the left to 17: C6H10O5(s) + 6O2(g)  6CO2(g) + 5H2O(g) 3.57

b) __Ca3(PO4)2(s) + __SiO2(s) + __C(s)  __P4(g) + __CaSiO3(l) + __CO(g) The 4 P atoms in P4 require a coefficient of 2 in front of Ca3(PO4)2 on the left: 2Ca3(PO4)2(s) + __SiO2(s) + __C(s)  __P4(g) + __CaSiO3(l) + __CO(g) The 6 Ca atoms in 2Ca3(PO4)2 on the left require a coefficient of 6 in front of CaSiO 3 on the right: 2Ca3(PO4)2(s) + __SiO2(s) + __C(s)  __P4(g) + 6CaSiO3(l) + __CO(g) The 6 Si atoms in 6CaSiO3 on the right require a coefficient of 6 in front of SiO2 on the left: 2Ca3(PO4)2(s) + 6SiO2(s) + __C(s)  __P4(g) + 6CaSiO3(l) + __CO(g) There are 28 O atoms on the left (16 in 2Ca3(PO4)2 and 12 in 6SiO2); there are 18 O atoms on the right in 6CaSiO3 so a coefficient of 10 in front of CO on the right will bring the total O atoms to 18 on the right: 2Ca3(PO4)2(s) + 6SiO2(s) + __C(s)  __P4(g) + 6CaSiO3(l) + 10CO(g) The 10 C atoms in 10CO on the right require a coefficient of 10 in front of C on the left: 2Ca3(PO4)2(s) + 6SiO2(s) + 10C(s)  P4(g) + 6CaSiO3(l) + 10CO(g) c) __Fe(s) + __H2O(g)  __Fe3O4(s) + __H2(g) The 3 Fe atoms in Fe3O4 on the right require a coefficient of 3 in front of Fe on the left: 3Fe(s) + __H2O(g)  __Fe3O4(s) + __H2(g) The 4 O atoms in Fe3O4 on the right require a coefficient of 4 in front of H 2O on the left: 3Fe(s) + 4H2O(g)  __Fe3O4(s) + __H2(g) The 8 H atoms on the left in 4H2O require a coefficient of 4 in front of H2 on the right: 3Fe(s) + 4H2O(g)  Fe3O4(s) + 4H2(g) d) __S2Cl2(l) + __NH3(g)  __S4N4(s) + __S8(s) + __NH4Cl(s) The 12 S atoms on the right (4 in S4N4 and 8 in S8) require a coefficient of 6 in front of S2Cl2 on the left: 6S2Cl2(l) + __NH3(g)  __S4N4(s) + __S8(s) + __NH4Cl(s) The 12 Cl atoms in 6S2Cl2 on the left require a coefficient of 12 in front of NH4Cl on the right: 6S2Cl2(l) + __NH3(g)  __S4N4(s) + __S8(s) + 12NH4Cl(s) The 16 N atoms on the right (4 in S4N4 and 12 in 12NH4Cl) require a coefficient of 16 in front of NH3 on the left: 6S2Cl2(l) + 16NH3(g)  S4N4(s) + S8(s) + 12NH4Cl(s) Note there are 48 H atoms on both sides, so the equation is balanced.

3.58

Plan: The names must first be converted to chemical formulas. Balancing is a trial-and-error procedure. Balance one element at a time, placing coefficients where needed to have the same number of atoms of a particular element on each side of the equation. The smallest whole-number coefficients should be used. Remember that oxygen is diatomic. Solution: a) Gallium (a solid) and oxygen (a gas) are reactants and solid gallium(III) oxide is the only product: __Ga(s) + __O2(g)  __Ga2O3(s) A coefficient of 2 in front of Ga on the left is needed to balance the 2 Ga atoms in Ga 2O3: 2Ga(s) + __O2(g)  __Ga2O3(s) The 3 O atoms in Ga2O3 on the right require a coefficient of 3/2 in front of O 2 on the left: 2Ga(s) + 3/2O2(g)  __Ga2O3(s) Multiply all coefficients by 2 to obtain whole numbers: 4Ga(s) + 3O2(g)  2Ga2O3(s) b) Liquid hexane and oxygen gas are the reactants while carbon dioxide gas and gaseous water are the products: __C6H14(l) +__O2(g)  __CO2(g) + __H2O(g) The 6 C atoms in C6H14 on the left require a coefficient of 6 in front of CO 2 on the right: __C6H14(l) +__O2(g)  6CO2(g) + __H2O(g) The 14 H atoms in C6H14 on the left require a coefficient of 7 in front of H 2O on the right: __C6H14(l) +__O2(g)  6CO2(g) + 7H2O(g) The 19 O atoms on the right (12 in 6CO2 and 7 in 7H2O) require a coefficient of 19/2 in front of O2 on the left: Multiply all coefficients by 2 to obtain whole numbers: 2C6H14(l) + 19O2(g)  12CO2(g) + 14H2O(g) c) Aqueous solutions of calcium chloride and sodium phosphate are the reactants; solid calcium phosphate and an aqueous solution of sodium chloride are the products: __CaCl2(aq) + __Na3PO4(aq)  __Ca3(PO4)2(s) + __NaCl(aq) The 3 Ca atoms in Ca3(PO4)2 on the right require a coefficient of 3 in front of CaCl 2 on the left: 3CaCl2(aq) + __Na3PO4(aq)  __Ca3(PO4)2(s) + __NaCl(aq) The 6 Cl atoms in 3CaCl2 on the left require a coefficient of 6 in front of NaCl on the right: 3CaCl2(aq) + __Na3PO4(aq)  __Ca3(PO4)2(s) + 6NaCl(aq) The 6 Na atoms in 6NaCl on the right require a coefficient of 2 in front of Na 3PO4 on the left: 3CaCl2(aq) + 2Na3PO4(aq)  __Ca3(PO4)2(s) + 6NaCl(aq) There are now 2 P atoms on each side: 3CaCl2(aq) + 2Na3PO4(aq)  Ca3(PO4)2(s) + 6NaCl(aq)

3.59

The 4 O atoms in 2SiO2 on the right require a coefficient of 4 in front of H 2O on the left. __Si2Cl6(l) + 4H2O(l)  2SiO2(s) + 6HCl(g) + __H2(g) There are 8 H atoms in 4H2O on the left; there are 8 H atoms on the right (6 in 6HCl and 2 in H 2): Si2Cl6(l) + 4H2O(l)  2SiO2(s) + 6HCl(g) + H2(g) c) Nitrogen dioxide and water are the reactants and an aqueous solution of nitric acid and nitrogen monoxide gas are the products: __NO2(g) + __H2O(l)  __HNO3(aq) + __NO(g) Start with hydrogen it occurs in only one reactant and one product: The 2 H atoms in H2O on the left require a coefficient of 2 in front of HNO 3 on the right: __NO2(g) + __H2O(l)  2HNO3(aq) + __NO(g) The 3 N atoms on the right (2 in 2HNO3 and 1 in NO) require a coefficient of 3 in front of NO 2 on the left; 3NO2(g) + __H2O(l)  2HNO3(aq) + __NO(g) There are now 7 O atoms on each side: 3NO2(g) + H2O(l)  2HNO3(aq) + NO(g) 3.60

3.61

The stoichiometrically equivalent Molar ratio is the ratio of the coefficients in the balanced equation. This can be used as a conversion factor to calculate amounts of reactants or products in a chemical reaction.

3.62

Plan: Write a balanced chemical reaction to obtain the mole ratio between the reactants. Compare the number of particles of each reactant with the mole ratio to find the limiting reactant. Use the limiting reactant to calculate the number of product molecules that will form. Solution: a) The reaction is A2 + B2 → AB3 or, correctly balanced, A2 + 3B2 → 2AB3. The mole ratio between A2 and B2 is 1:3. Three times as many B2 molecules are required as you have of A2 molecules. With 3 A2 molecules present, 3 x 3 = 9 B2 molecules would be required. Since you have only 6 B 2 molecules, B2 is the limiting reagent. b) The balanced equation shows that 2AB3 molecules are produced for every 3 B2 molecules that react. Use the 3:2 mole ratio between the limiting reactant, B2, and AB3:  2 AB3 molecules  Number of molecules of product = 6 B2 molecules   = 4 AB3 molecules  3 B2 molecules 

3.63

The percent yield is the ratio of the actual to the theoretical value. Both yields can be expressed as a mass or mole comparison. The percent yield will be the same since mass and moles are directly proportional.

3.64

Plan: First, write a balanced chemical equation. Since A is the limiting reagent (B is in excess), A is used to determine the amount of C formed, using the mole ratio between reactant A and product C. Solution: Plan: The balanced equation is aA + bB  cC. Divide the mass of A by its molar mass to obtain amount (mol) of A. Use the molar ratio from the balanced equation to find the amount (mol) of C. Multiply amount (mol) of C by its molar mass to obtain mass of C. Roadmap: Mass (g) of A

Divide by M (g/mol) Amount (mol) of A

Molar ratio between A and C Amount (moles) of C

Multiply by M (g/mol) Mass (g) of C 3.65

Plan: First, write a balanced chemical equation. Since the amounts of both reactants are given, the limiting reactant must be determined. Solution: Plan: The balanced equation is dD + eE  fF. Divide the mass of each reactant by its molar mass to obtain amount (mol) of each reactant. Use the appropriate molar ratios from the balanced equation to find the amount (mol) of F obtained from Reactant D and Reactant E. The smaller amount of F is the amount produced. Multiply amount (mol) of F by its molar mass to obtain mass of F. Roadmap: Mass (g) of D

Mass (g) of E

Divide by M (g/mol)

Amount (mol) of D

Amount (mol) of E

Molar ratio between D and F

Molar ratio between E and F

Amount (moles) of F

Amount (moles) of F Choose lower number of moles of F and multiply by M (g/mol)

Mass (g) of F 3.66

Plan: Always check to see if the initial equation is balanced. If the equation is not balanced, it should be balanced before proceeding. Use the mole ratio from the balanced chemical equation to determine the amount (mol) of Cl 2 produced. The equation shows that 1 mole of Cl2 is produced for every 4 moles of HCl that react. Multiply the amount (mol) of Cl2 produced by the molar mass to convert to mass in grams. Solution: 4HCl(aq) + MnO2(s)  MnCl2(aq) + 2H2O(g) + Cl2(g)  1 mol Cl2  a) Amount (mol) of Cl2 = 1.82 mol HCl   = 0.455 mol Cl2  4 mol HCl   70.90 g Cl2  b) Mass (g) of Cl2 = 0.455 mol Cl2   = 32.2595 g= 32.3 g Cl2  1 mol Cl2 

3.67

Plan: Always check to see if the initial equation is balanced. If the equation is not balanced, it should be balanced before proceeding. Divide the amount of reactant in grams by its molar mass to determine amount (mol) of reactant. Use the mole ratio from the balanced chemical equation to determine the amount (mol) of Bi produced. The equation shows that 2 moles of Bi are produced for every 1 mole of Bi2O3 that reacts. Solution: Bi2O3(s) + 3C(s)  2Bi(s) + 3CO(g)  1 mol Bi 2 O3  a) Amount (mol) of Bi2O3 = 283 g Bi 2 O3   = 0.607296 mol= 0.607 mol Bi2O3  466.0 g Bi 2 O3   1 mol Bi 2 O3   2 mol Bi  b) Amount (mol) of Bi = 283 g Bi 2 O3    = 1.21459 mol= 1.21 mol Bi  466.0 g Bi 2 O3   1 mol Bi 2 O3 

3.68

Plan: Convert the mass of oxygen from kilograms to grams and then convert mass (g) to amount (mol) of oxygen by dividing by its molar mass. Use the amount (mol) of oxygen and the mole ratio from the balanced chemical equation to determine the amount (mol) of KNO3 required. Multiply the amount (mol) of KNO3 by its molar mass to obtain the mass in grams. Solution:  103 g  a) Mass (g) of O2 = 56.6 kg O2  = 5.66x104 g O2  1 kg     1 mol O2  3 Amount (mol) of O2 = 5.66x104 g O2   = 1.76875x10 mol O2 32.00 g O 2    4 mol KNO3  3 Amount (mol) of KNO3 = 1.76875 mol O 2   = 1415 mol= 1.42x10 mol KNO3 5 mol O 2  





 101.11 g KNO3  5 b) Mass (g) of KNO3 = 1415 mol KNO3   = 143070.65 g= 1.43x10 g KNO3 1 mol KNO 3   Combining all steps gives:  103 g   1 mol O2  4 mol KNO3   101.11 g KNO3  Mass (g) of KNO3 = 56.6 kg O2   1 kg   32.00 g O  5 mol O   1 mol KNO  2  2 3     5 = 143070.65 g= 1.43x10 g KNO3

3.69

Plan: Convert mass of Cr2S3 to amount (mol) by dividing by its molar mass. Use the mole ratio between Cr 2S3 and Cr2O3 from the balanced chemical equation to determine the amount (mol) of Cr 2O3 required. Multiply the amount (mol) of Cr2O3 by its molar mass to obtain the mass in grams. Solution:

 1 mol Cr2S3  a) Amount (mol) of Cr2S3 = 421 g Cr2S3   = 2.102792 mol Cr2S3  200.21 g Cr2S3   1 mol Cr2 O3  Amount (mol) of Cr2O3 = 2.102792 mol Cr2S3   = 2.102792 mol= 2.10 mol Cr2O3  1 mol Cr2S3   152.00 g Cr2 O3  2 b) Mass (g) of Cr2O3 = 2.102792 mol Cr2 O3   = 319.624 g= 3.20x10 g Cr2O3 1 mol Cr O 2 3   Combining all steps gives:  1 mol Cr2S3  1 mol Cr2 O3   152.00 g Cr2 O3  Mass (g) of Cr2O3 = 421 g Cr2S3      200.21 g Cr2S3  1 mol Cr2S3   1 mol Cr2 O3 

= 319.624 g= 3.20x102 g Cr2O3 3.70

Plan: First, balance the equation. Convert the mass (g) of diborane to amount (mol) of diborane by dividing by its molar mass. Use mole ratios from the balanced chemical equation to determine the amount (mol) of the products. Multiply the mole amount of each product by its molar mass to obtain mass in grams. Solution: The balanced equation is: B2H6(g) + 6H2O(l)  2H3BO3(s) + 6H2(g).  1 mol B2 H 6  Amount (mol) of B2H6 = 43.82 g B2 H 6   = 1.583665 mol B2H6  27.67 g B2 H 6   2 mol H 3 BO3  Amount (mol) of H3BO3 = 1.583665 mol B2 H 6   = 3.16733 mol H3BO3  1 mol B2 H 6   61.83 g H3 BO3  Mass (g) of H3BO3 = 3.16733 mol H3 BO3   = 195.83597 g= 195.8 g H3BO3  1 mol H3 BO3 

Combining all steps gives:  1 mol B2 H 6   2 mol H3 BO3   61.83 g H3 BO3  Mass (g) of H3BO3 = 43.82 g B2 H 6      27.67 g B2 H 6   1 mol B2 H 6   1 mol H3 BO3  = 195.83597 g= 195.8 g H3BO3  6 mol H 2  Amount (mol) of H2 = 1.583665 mol B2 H 6   = 9.50199 mol H2  1 mol B2 H 6   2.016 g H 2  Mass (g) of H2 = 9.50199 mol H 2   = 19.15901 g H2 = 19.16 g H2  1 mol H 2  Combining all steps gives:  1 mol B2 H 6   6 mol H 2   2.016 g H 2  Mass (g) of H2 = 43.82 g B2 H 6     = 19.15601 g= 19.16 g H2  27.67 g B2 H 6   1 mol B2 H 6   1 mol H 2 

3.71

Plan: First, balance the equation. Convert the mass (g) of silver sulfide to amount (mol) of silver sulfide by dividing by its molar mass. Use mole ratios from the balanced chemical equation to determine the amount (mol) of the products. Multiply the mole amount of each product by its molar mass to obtain mass in grams. Solution: First, balance the equation: Ag2S(s) + 2 HCl(aq)  2 AgCl(s) + H2S(g)  1 mol Ag 2S  Amount (mol) of Ag2S = 174 g Ag 2S  = 0.7018959 mol Ag2S  247.9 g Ag 2S   2 mol AgCl  Amount (mol) of AgCl = 0.7018959 mol Ag 2S  = 1.403792 mol AgCl  1 mol Ag 2S 

 143.4 g AgCl  Mass (g) of AgCl = 1.403792 mol Ag 2S  = 201.304 g= 201 g AgCl  1 mol AgCl  Combining all steps gives:  1 mol Ag 2S   2 mol AgCl   143.4 g AgCl  Mass (g) AgCl = 174 g Ag 2S    = 201.304 = 201 g AgCl  247.9 g Ag 2S   1 mol Ag 2S   1 mol AgCl   1 mol H 2S  Amount (mol) of H2S = 0.7018959 mol Ag 2S  = 0.7018959 mol H2S  1 mol Ag 2S   34.09 g H 2S  Mass (g) of H2S = 0.7018959 mol H 2S   = 23.9276 g= 23.9 g H2S  1 mol H 2S 

Combining all steps gives:

3.72

 1 mol Ag 2S  1 mol H 2S   34.09 g H 2S  Mass (g) of H2S = 174 g Ag 2S     = 23.9276 g= 23.9 g H2S  247.9 g Ag 2S  1 mol Ag 2S   1 mol H 2S  Plan: Write the balanced equation by first writing the formulas for the reactants and products. Convert the mass of phosphorus to amount (mol) by dividing by the molar mass, use the mole ratio between phosphorus and chlorine from the balanced chemical equation to obtain amount (mol) of chlorine, and finally divide the amount (mol) of chlorine by its molar mass to obtain amount in grams. Solution: Reactants: formula for phosphorus is given as P 4 and formula for chlorine gas is Cl2 (chlorine occurs as a diatomic molecule). Product: formula for phosphorus pentachloride (the name indicates one phosphorus atom and five chlorine atoms) is PCl5. Equation: P4 + Cl2  PCl5 Balancing the equation: P4 + 10Cl2  4PCl5  1 mol P4  Amount (mol) of P4 = 455 g P4   = 3.67291 mol P4  123.88 g P4   10 mol Cl2  Amount (mol) of Cl2 = 3.67291 mol P4   = 36.7291 mol Cl2  1 mol P4   70.90 g Cl2  3 Mass (g) of Cl2 = 36.7291 mol Cl2   = 2604.09 g= 2.60x10 g Cl2 1 mol Cl 2  

Combining all steps gives:  1 mol P4   10 mol Cl2   70.90 g Cl2  3 Mass (g) of Cl2 = 455 g P4     = 2604.09267 g= 2.60x10 g Cl2 123.88 g P 1 mol P 1 mol Cl 4  4  2  

3.73

Plan: Write the balanced equation by first writing the formulas for the reactants and products. Convert the mass of sulfur to amount (mol) by dividing by the molar mass, use the mole ratio between sulfur and fluorine from the balanced chemical equation to obtain amount (mol) of fluorine, and finally divide the amount (mol) of fluorine by its molar mass to obtain amount in grams. Solution: Reactants: formula for sulfur is given as S8 and formula for fluorine gas is F2 (fluorine occurs as a diatomic molecule). Product: formula for sulfur hexafluoride (the name indicates one sulfur atom and six fluoride atoms) is SCl6. Equation: S8 + F2  SF6 Balancing the equation: S8(s) + 24F2(g)  8SF6(s)  1 mol S8  Amount (mol) of S8 = 17.8 g S8   = 0.0693795 mol S8  256.56 g S8   24 mol F2  Amount (mol) of F2 = 0.0693795 mol S8   = 1.665108 mol F2  1 mol S8 

 38.00 g F2  Mass (g) of F2 = 1.665108 mol F2   = 63.274 g= 63.3 g F2  1 mol F2  Combining all steps gives:  1 mol S8   24 mol F2   38.00 g F2  Mass (g) of F2 = 17.8 g S8     = 63.27409 g= 63.3 g F2  256.56 g S8   1 mol S8   1 mol F2 

3.74

Plan: Begin by writing the chemical formulas of the reactants and products in each step. Next, balance each of the equations. Combine the equations for the separate steps by adjusting the equations so the intermediate (iodine monochloride) cancels. Finally, change the mass of product from kg to grams to amount (mol) by dividing by the molar mass and use the mole ratio between iodine and product to find the amount (mol) of iodine. Multiply amount (mol) by the molar mass of iodine to obtain mass of iodine. Solution: a) Step 1 I2(s) + Cl2(g)  2ICl(s) Step 2 ICl(s) + Cl2(g)  ICl3(s) b) Multiply the coefficients of the second equation by 2, so that ICl(s), an intermediate product, can be eliminated from the overall equation. I2 (s) + Cl2 (g )   2ICl(s)

2ICl(s) + 2Cl2 ( g )   2ICl3 (s) I2(s) + Cl2(g) + 2ICl(s) + 2Cl2(g)  2ICl(s) + 2ICl3(s) Overall equation: I2(s) + 3Cl2(g)  2ICl3(s)  103 g  c) Mass (g) of ICl3 = 2.45 kg ICl3  = 2450 g ICl3  1 kg     1 mol ICl3  Amount (mol) of ICl3 = 2450 g ICl3   = 10.506 mol ICl3  233.2 g ICl3   1 mol I 2  Amount (mol) of I2 = 10.506 mol ICl3   = 5.253 mol I2  2 mol ICl3   253.8 g I 2  3 Mass (g) of I2 = 5.253 mol I 2   = 1333.211 g= 1.33x10 g I2 1 mol I 2  

Combining all steps gives:  103 g   1 mol ICl3  1 mol I2  253.8 g I2  Mass (g) of I2 = 2.45 kg ICl3  = 1333.211 g= 1.33x103 g I2  1 kg   233.2 g ICl  2 mol ICl  1 mol I  3  3  2   

3.75

Plan: Begin by writing the chemical formulas of the reactants and products in each step. Next, balance each of the equations. Combine the equations for the separate steps and cancel the intermediate (lead(II) oxide). Finally, change the mass of lead from metric tons to grams to amount (mol) by dividing by the molar mass and use the mole ratio between lead and sulfur dioxide to find the amount (mol) of sulfur dioxide. Multiply amount (mol) by the molar mass of sulfur dioxide to obtain mass and convert to metric tons. Solution:  a) Step 1 2PbS(s) + 3O2(g)  2PbO(s) + 2SO2(g)  Step 2 2PbO(s) + PbS(s)  3Pb(l) + SO2(g) b) Combine the two reactions: 2PbS(s) + 3O2 (g )   2PbO(s) + 2SO2 (g )

2PbO(s) + PbS(s)   3Pb(l ) + SO2 (g ) 2PbS(s) + 3O2(g) + 2PbO(s) + PbS(s)  2PbO(s) + 2SO2(g) + 3Pb(l) + SO2(g) Overall equation: 3PbS(s) + 3O2(g)  3Pb(l) + 3SO2(g) or  PbS(s) + O2(g)  Pb(l) + SO2(g)

c) 1 metric tonne = 1000 kg  103 kg  103 g  Mass (g) of Pb = ton Pb  = 1.000x106 g Pb  1 ton   1 kg      1 mol Pb  Amount (mol) of Pb = 1x106 g Pb   = 4826.255 mol Pb  207.2 g Pb 





 1 mol SO 2  Amount (mol) of SO2 = 4826.255 mol Pb   = 4826.255 mol SO2  1 mol Pb 

 64.07 g SO2   1 kg  1 mt  Metric tonne SO2 =  4826.255 mol SO2   = 0.309218 mt = 0.3092 mt SO2   3   3   1 mol SO2   10 g  10 kg  Combining all steps gives:  103 kg  103 g   1 mol Pb  1 mol SO2   64.07 g SO2   1 kg  1 mt  Metric tonne SO2 =  mt Pb    103 kg   1 mt   1 kg   207.2 g Pb  1 mol Pb   1 mol SO   103 g    2       = 0.309218 mt= 0.3092 mt SO2

3.76

Plan: Convert the given mass of each reactant to amount (mol) by dividing by the molar mass of that reactant. Use the mole ratio from the balanced chemical equation to find the amount (mol) of CaO formed from each reactant, assuming an excess of the other reactant. The reactant that produces fewer moles of CaO is the limiting reactant. Convert the amount (mol) of CaO obtained from the limiting reactant to grams using the molar mass. Solution: 2Ca(s) + O2(g)  2CaO(s)  1 mol Ca  a) Amount (mol) of Ca = 4.20 g Ca   = 0.104790 mol Ca  40.08 g Ca   2 mol CaO  Amount (mol) of CaO from Ca = 0.104790 mol Ca   = 0.104790 mol= 0.105 mol CaO  2 mol Ca   1 mol O 2  b) Amount (mol) of O2 = 2.80 g O 2   = 0.0875 mol O2  32.00 g O 2   2 mol CaO  Amount (mol) of CaO from O2 = 0.0875 mol O 2   = 0.17500 mol= 0.175 mol CaO  1 mol O 2 

c) Calcium is the limiting reactant since it will form less calcium oxide. d) The mass of CaO formed is determined by the limiting reactant, Ca.  56.08 g CaO  Mass (g) of CaO = 0.104790 mol CaO   = 5.8766 g= 5.88 g CaO  1 mol CaO  Combining all steps gives:  1 mol Ca   2 mol CaO   56.08 g CaO  Mass (g) of CaO =  4.20 g Ca      = 5.8766 g= 5.88 g CaO  40.08 g Ca   2 mol Ca   1 mol CaO 

3.77

Solution: SrH2(s) + 2H2O(l)  Sr(OH)2(s) + 2H2(g)  1 mol SrH 2  a) Amount (mol) of SrH2 =  5.70 g SrH 2    = 0.0635877 mol SrH2  89.64 g SrH 2   2 mol H 2  Amount (mol) of H2 from SrH2 =  0.0635877 mol SrH 2    = 0.127175 mol= 0.127 mol H2  1 mol SrH 2   1 mol H 2 O  b) Mass (g) of H2O =  4.75 g H 2 O    = 0.263596 mol H2O  18.02 g H 2 O   2 mol H 2  Amount (mol) of H2 from H2O =  0.263596 mol H 2 O    = 0.263596 mol= 0.264 mol H2  2 mol H 2 O 

c) SrH2 is the limiting reagent since it will yield fewer moles of hydrogen gas. d) The mass of H2 formed is determined by the limiting reactant, SrH2.  2.016 g H 2  Mass (g) of H2 =  0.127175 mol H 2    = 0.256385 g= 0.256 g H2  1 mol H 2  Combining all steps gives:  1 mol SrH 2   2 mol H 2   2.016 g H2  Mass (g) of H2 =  5.70 g SrH 2      = 0.256385 g= 0.256 g H2  89.64 g SrH 2   1 mol SrH 2   1 mol H2 

3.78

Plan: First, balance the chemical equation. To determine which reactant is limiting, calculate the amount of HIO3 formed from each reactant, assuming an excess of the other reactant. The reactant that produces less product is the limiting reagent. Use the limiting reagent and the mole ratio from the balanced chemical equation to determine the amount of HIO3 formed and the amount of the excess reactant that reacts. The difference between the amount of excess reactant that reacts and the initial amount of reactant supplied gives the amount of excess reactant remaining. Solution: The balanced chemical equation for this reaction is: 2ICl3(s) + 3H2O (l)  ICl(g) + HIO3(aq) + 5HCl(g) Hint: Balance the equation by starting with oxygen. The other elements are in multiple reactants and/or products and are harder to balance initially. Finding the amount (mol) of HIO3 from the amount (mol) of ICl3 (if H2O is limiting):  1 mol ICl3  Amount (mol) of ICl3 =  635 g ICl3    = 2.722985 mol ICl3  233.2 g ICl3   1 mol HIO3  Amount (mol) of HIO3 from ICl3 =  2.722985 mol ICl3    = 1.361492 mol= 1.36 mol HIO3  2 mol ICl3  Finding the amount (mol) of HIO3 from the amount (mol) of H2O (if ICl3 is limiting):  1 mol H 2 O  Amount (mol) of H2O = 118.5 g H 2 O    = 6.57603 mol H2O  18.02 g H 2 O   1 mol HIO3  Amount (mol) HIO3 from H2O = 6.57603 mol H 2 O   = 2.19201 mol= 2.19 mol HIO3  3 mol H 2 O  ICl3 is the limiting reagent and will produce 1.36 mol HIO3.  175.9 g HIO3  Mass (g) of HIO3 = 1.361492 mol HIO3   = 239.486 g= 239 g HIO3  1 mol HIO3 

Combining all steps gives:  1 mol ICl3  1 mol HIO3   175.9 g HIO3  Mass (g) of HIO3 = 635 g ICl3     = 239.486 g= 239 g HIO3  233.2 g ICl3  2 mol ICl3   1 mol HIO3 

The remaining mass of the excess reagent can be calculated from the amount of H 2O combining with the limiting reagent.  3 mol H 2 O  Amount (mol) of H2O required to react with 635 g ICl3 = 2.722985 mol ICl3    2 mol ICl3  = 4.0844775 mol H2O  18.02 g H 2 O  Mass (g) of H2O required to react with 635 g ICl3 = 4.0844775 mol H 2 O    1 mol H 2 O  = 73.6023 g= 73.6 g H2O reacted Mass (g) of remaining H2O = 118.5 g – 73.6 g = 44.9 g H2O 3.79

Plan: First, balance the chemical equation. To determine which reactant is limiting, calculate the amount of H 2S formed from each reactant, assuming an excess of the other reactant. The reactant that produces less product is the limiting reagent. Use the limiting reagent and the mole ratio from the balanced chemical equation to determine the amount of H2S formed and the amount of the excess reactant that reacts. The difference between the amount of excess reactant that reacts and the initial amount of reactant supplied gives the amount of excess reactant remaining. Solution: The balanced chemical equation for this reaction is: Al2S3 (s) + 6H2O (l)  2Al(OH)3 (aq) + 3H2S (g) Finding the amount (mol) of H2S from the amount (mol) of Al2S3 (if H2O is limiting):  1 mol Al2S3  Amount (mol) of Al2S3 = 158 g Al2S3   = 1.05214 mol Al2S3  150.17 g Al2S3   3 mol H 2S  Amount (mol) of H2S from Al2S3 = 1.05214 mol Al2S3   = 3.15642 mol= 3.16 mol H2S  1 mol Al2S3  Finding the amount (mol) of H2S from the amount (mol) of H2O (if Al2S3 is limiting):  1 mol H 2 O  Amount (mol) of H2O = 131 g H 2 O   = 7.26970 mol H2O  18.02 g H 2 O   3 mol H 2S  Amount (mol) of H2S from H2O = 7.26970 mol H 2 O   = 3.63485mol = 3.63 mol H2S  6 mol H 2 O  Al2S3 is the limiting reagent and 3.16 mol of H 2S will form.  34.09 g H 2S  Mass (g) of H2S = 3.15642 mol H 2S  = 107.602 g= 108 g H2S  1 mol H 2S 

Combining all steps gives:  1 mol Al 2S3   3 mol H 2S   34.09 g H 2S  m (H2S) = 158 g Al2S3      = 107.602 g= 108 g H2S  150.17 g Al2S3   1 mol Al 2S3   1 mol H 2S  The remaining mass of the excess reagent can be calculated from the amount of H 2O combining with the limiting reagent.  6 mol H 2 O  Amount (mol) of H2O required to react with 158 g of Al2S3 = 1.05214 mol Al2S3     1 mol Al2S3  = 6.31284 mol H2O  18.02 g H 2 O  Mass (g) of H2O required to react with 158 g of Al2S3 =  6.31284 mol H2 O    = 113.757 g H2O  1 mol H 2 O  Mass (g) of remaining H2O = 131 g H2O – 113.757 g H2O = 17.243 g= 17 g H2O

3.80

Plan: Write the balanced equation; the formula for carbon is C, the formula for oxygen is O 2, and the formula for carbon dioxide is CO2. To determine which reactant is limiting, calculate the amount of CO 2 formed from each reactant, assuming an excess of the other reactant. The reactant that produces less product is the limiting reagent. Use the limiting reagent and the mole ratio from the balanced chemical equation to determine the amount of CO 2 formed and the amount of the excess reactant that reacts. The difference between the amount of excess reactant that reacts and the initial amount of reactant supplied gives the amount of excess reactant remaining. Solution: The balanced equation is: C(s) + O2(g)  CO2(g) Finding the amount (mol) of CO2 from the amount (mol) of carbon (if O2 is limiting):  1 mol CO 2  Amount (mol) of CO2 from C =  0.100 mol C    = 0.100 mol CO2  1 mol C  Finding the amount (mol) of CO2 from the amount (mol) of oxygen (if C is limiting):  1 mol O2  Amount (mol) of O2 =  8.00 g O2    = 0.250 mol O2  32.00 g O2   1 mol CO2  Amount (mol) of CO2 from O2 =  0.250 mol O2    = 0.25000 mol= 0.250 mol CO2  1 mol O2  Carbon is the limiting reactant and will be used to determine the amount of CO 2 that will form.  44.01 g CO2  Mass (g) of CO2 =  0.100 mol CO2    = 4.401 g= 4.40 g CO2  1 mol CO2 

Since carbon is limiting, the O2 is in excess. The amount remaining depends on how much combines with the limiting reagent.  1 mol O 2  Amount (mol) of O2 required to react with 0.100 mol of C =  0.100 mol C    = 0.100 mol O2  1 mol C   32.00 g O 2  Mass (g) of O2 required to react with 0.100 mol of C =  0.100 mol O 2    = 3.20 g O2  1 mol O 2  Mass (g) of remaining O2 = 8.00 g – 3.20 g = 4.80 g O2

3.81

Plan: Write the balanced equation; the formula for hydrogen is H2, the formula for oxygen is O2, and the formula for water is H2O. To determine which reactant is limiting, calculate the amount of H 2O formed from each reactant, assuming an excess of the other reactant. The reactant that produces less product is the limiting reagent. Use the limiting reagent and the mole ratio from the balanced chemical equation to determine the amount of H 2O formed and the amount of the excess reactant that reacts. The difference between the amount of excess reactant that reacts and the initial amount of reactant supplied gives the amount of excess reactant remaining. Solution: The balanced equation is: 2H2(g) + O2(g)  2H2O(l) Finding the amount (mol) of H2O from the amount (mol) of hydrogen (if O 2 is limiting):  1 mol H 2  Amount (mol) of H2 = 0.0375 g H 2   = 0.01860 mol H2  2.016 g H 2   2 mol H 2 O  Amount (mol) of H2O from H2 = 0.01860 mol H 2   = 0.01860 mol= 0.0186 mol H2O  2 mol H 2  Finding the amount (mol) of H2O from the amount (mol) of oxygen (if H2 is limiting):  2 mol H 2 O  Mole of H2O from O2 = 0.0185 mol O 2   = 0.0370 mol H2O  1 mol O 2 

The hydrogen is the limiting reactant, and will be used to determine the amount of water that will form.  18.02 g H 2 O  Mass (g) of H2O = 0.01860 mol H 2 O   = 0.335172 g= 0.335 g H2O  1 mol H 2 O 

Since the hydrogen is limiting; the oxygen must be the excess reactant. The amount of excess reactant is determined from the limiting reactant.  1 mol O 2  Amount (mol) of O2 required to react with 0.0375 g of H2 = 0.01860 mol H 2   = 0.00930 mol O2  2 mol H 2   32.00 g O 2  Mass (g) of O2 required to react with 0.0375 g of H2 = 0.00930 mol O 2   = 0.2976 g O2  1 mol O 2   32.00 mol O 2  Mass of O2 supplied = 0.0185 mol O 2   = 0.5920 g O2  1 mol O 2 

Mass (g) of remaining O2 = 0.5920 g – 0.2976 g = 0.2944 g= 0.294 g O2 3.82

Plan: The question asks for the mass of each substance present at the end of the reaction. ―Substance‖ refers to both reactants and products. Solve this problem using multiple steps. Recognizing that this is a limiting reactant problem, first write a balanced chemical equation. To determine which reactant is limiting, calculate the amount of any product formed from each reactant, assuming an excess of the other reactant. The reactant that produces less product is the limiting reagent. Any product can be used to predict the limiting reactant; in this case, AlCl3 is used. Use the limiting reagent and the mole ratio from the balanced chemical equation to determine the amount of both products formed and the amount of the excess reactant that reacts. The difference between the amount of excess reactant that reacts and the initial amount of reactant supplied gives the amount of excess reactant remaining. Solution: The balanced chemical equation is: Al(NO2)3(aq) + 3NH4Cl(aq)  AlCl3(aq) + 3N2(g) + 6H2O(l) Now determine the limiting reagent. We will use the amount (mol) of AlCl 3 produced to determine which is limiting. Finding the amount (mol) of AlCl3 from the amount (mol) of Al(NO2)3 (if NH4Cl is limiting):  1 mol Al(NO 2 )3  Amount (mol) of Al(NO2)3 = 72.5 g Al(NO 2 )3   = 0.43937 mol Al(NO2)3  165.01 g Al(NO 2 )3   1 mol AlCl3  Amount (mol) of AlCl3 from Al(NO2)3 =  0.43937 mol Al(NO 2 )3    = 0.43937 mol= 0.439 mol  1 mol Al(NO 2 )3  AlCl3 Finding the amount (mol) of AlCl3 from the amount (mol) of NH4Cl (if Al(NO2)3 is limiting):  1 mol NH 4 Cl  Amount (mol) of NH4Cl = 58.6 g NH 4 Cl   = 1.09553 mol NH4Cl  53.49 g NH 4 Cl   1 mol AlCl3  Amount (mol) of AlCl3 from NH4Cl = 1.09553 mol NH 4 Cl   = 0.365177 mol= 0.365 mol AlCl3  3 mol NH 4 Cl  Ammonium chloride is the limiting reactant, and it is used for all subsequent calculations. Mass of substances after the reaction: Al(NO2)3: Mass (g) of Al(NO2)3 (the excess reactant) required to react with 58.6 g of NH 4Cl =  1 mol Al(NO 2 )3   165.01 g Al(NO 2 )3  1.09553 mol NH 4 Cl   = 60.2579 g= 60.3 g Al(NO2)3   3 mol NH 4 Cl   1 mol Al(NO 2 )3 

Al(NO2)3 remaining: 72.5 g – 60.3 g = 12.2 g Al(NO2)3 NH4Cl: None left since it is the limiting reagent. AlCl3:  133.33 g AlCl3  Mass (g) of AlCl3 = 0.365177 mol AlCl3   = 48.689 g= 48.7 g AlCl3  1 mol AlCl3  N 2:

 3 mol N 2   28.02 g N 2  Mass (g) of N2 = 1.09553 mol NH 4 Cl    = 30.697 g= 30.7 g N2  3 mol NH 4 Cl   1 mol N 2  H2O:  6 mol H 2 O   18.02 g H 2 O  Mass (g) of H2O = 1.09553 mol NH 4 Cl    = 39.483 g= 39.5 g H2O  3 mol NH 4 Cl   1 mol H 2 O 

3.83

Plan: The question asks for the mass of each substance present at the end of the reaction. ―Substance‖ refers to both reactants and products. Solve this problem using multiple steps. Recognizing that this is a limiting reactant problem, first write a balanced chemical equation. To determine which reactant is limiting, calculate the amount of any product formed from each reactant, assuming an excess of the other reactant. The reactant that produces less product is the limiting reagent. Any product can be used to predict the limiting reactant; in this case, CaF 2 is used. Use the limiting reagent and the mole ratio from the balanced chemical equation to determine the amount of both products formed and the amount of the excess reactant that reacts. The difference between the amount of excess reactant that reacts and the initial amount of reactant supplied gives the amount of excess reactant remaining. Solution: The balanced chemical equation is: Ca(NO3)2(s) + 2NH4F(s)  CaF2(s) + 2N2O(g) + 4H2O(g) Now determine the limiting reagent. We will use the amount (mol) of CaF 2 produced to determine which is limiting. Finding the amount (mol) of CaF2 from the amount (mol) of Ca(NO3)2 (if NH4F is limiting):  1 mol Ca(NO3 ) 2  Amount (mol) of Ca(NO3)2 = 16.8 g Ca(NO3 ) 2   = 0.1023766 mol Ca(NO3)2  164.10 g Ca(NO3 ) 2   1 mol CaF2  Amount (mol) of CaF2 from Ca(NO3)2 = 0.1023766 mol Ca(NO3 ) 2   1 mol Ca(NO ) 3 2   = 0.1023766 mol= 0.102 mol CaF2 Finding the amount (mol) of CaF2 from the amount (mol) of NH4F (if Ca(NO3)2 is limiting):  1 mol NH 4 F  Amount (mol) of NH4F = 17.50 g NH 4 F   = 0.47246 mol NH4F  37.04 g NH 4 F   1 mol CaF2  Amount (mol) of CaF2 from NH4F = 0.47246 mol NH 4 F   = 0.23623 mol = 0.236 mol CaF2  2 mol NH 4 F  Calcium nitrate is the limiting reactant, and it is used for all subsequent calculations Mass of substances after the reaction: Ca(NO3)2: None (It is the limiting reactant.) NH4F: Mass (g) of NH4F (the excess reactant) required to react with 16.8 g of Ca(NO 3)2 =  2 mol NH 4 F   37.04 g NH 4 F  0.1023766 mol Ca(NO3 )2    = 7.58406 g NH4F  1 mol Ca(NO3 ) 2   1 mol NH 4 F 

NH4F remaining: 17.50 g – 7.58 g = 9.9159 = 9.92 g NH4F CaF2:  1 mol CaF2  78.08 g CaF2  Mass (g) of CaF2 = 0.1023766 mol Ca(NO3 ) 2    = 7.99356 g= 7.99 g CaF2  1 mol Ca(NO3 ) 2   1 mol CaF2  N2O:  2 mol N 2 O  44.02 g N 2 O  Mass (g) of N2O = 0.1023766 mol Ca(NO3 ) 2    = 9.0132 g= 9.01 g N2O  1 mol Ca(NO3 ) 2   1 mol N 2 O  H2O:  4 mol H 2 O   18.02 g H 2 O  Mass (g) of H2O = 0.1023766 mol Ca(NO3 ) 2    = 7.3793 =g 7.38 g H2O  1 mol Ca(NO3 ) 2   1 mol H 2 O  Silberberg, Amateis, Venkateswaran, Chen, Chemistry: The Molecular Nature of Matter and Change, 3rd Canadian Edition Page 3-94 Instructor‘s Solution Manual © Copyright 2021 McGraw-Hill Ryerson Ltd.

3.84

Plan: Express the yield of each step as a fraction of 1.00; multiply the fraction of the first step by that of the second step and then multiply by 100 to get the overall percent yield. Solution: 73% = 0.73; 68% = 0.68 (0.73 x 0.68) x 100% = 49.64% = 50.%

3.85

Plan: Express the yield of each step as a fraction of 1.00; multiply the fraction of the first step by that of the second step and then multiply by 100 to get the overall percent yield. Solution: 48% = 0.48; 73% = 0.73 (0.48 x 0.73) x 100 %= 35.04% = 35%

3.86

Plan: Write and balance the chemical equation using the formulas of the substances. Determine the theoretical yield of the reaction from the mass of tungsten(VI) oxide. To do that, convert the mass of tungsten(VI) oxide to amount (mol) by dividing by its molar mass and then use the mole ratio between tungsten(VI) oxide and water to determine the amount (mol) and then mass of water that should be produced. Use the density of water to determine the actual yield of water in grams. The actual yield divided by the theoretical yield just calculated (with the result multiplied by 100%) gives the percent yield. Solution: The balanced chemical equation is: WO3(s) + 3H2(g)  W(s) + 3H2O(l) Determining the theoretical yield of H2O:  1 mol WO3  Amount (mol) of WO3 = 45.5 g WO3   = 0.1962053 mol WO3  231.9 g WO3   3 mol H 2 O   18.02 g H 2 O  Mass (g) of H2O (theoretical yield) = 0.1962053 mol WO3    = 10.60686 g H2O  1 mol WO3   1 mol H 2 O  Determining the actual yield of H2O:  1.00 g H 2 O  Mass (g) of H2O (actual yield) = 9.60 mL H 2 O   = 9.60 g H2O  1 mL H 2 O   9.60 g H 2 O   actual Yield  % yield =   x 100% = 90.5075% = 90.5%  x 100% =   theoretical Yield   10.60686 g H 2 O 

3.87

Plan: Write and balance the chemical equation using the formulas of the substances. Determine the theoretical yield of the reaction from the mass of phosphorus trichloride. To do that, convert the mass of phosphorus trichloride to amount (mol) by dividing by its molar mass and then use the mole ratio between phosphorus trichloride and HCl to determine the amount (mol) and then mass of HCl that should be produced. The actual yield of the HCl is given. The actual yield divided by the theoretical yield just calculated (with the result multiplied by 100%) gives the percent yield. Solution: The balanced chemical equation is: PCl3(l) + 3H2O(l)  H3PO3(aq) + 3HCl(g) Determining the theoretical yield of HCl:  1 mol PCl3  Amount (mol) of PCl3 = 200. g PCl3   = 1.456452 mol PCl3  137.32 g PCl3   3 mol HCl   36.46 g HCl  Mass (g) of HCl (theoretical yield) = 1.456452 mol PCl3    = 159.3067 g HCl  1 mol PCl3   1 mol HCl  Actual yield (g) of HCl is given as 128 g HCl. Calculate the percent yield:  128 g HCl   actual Yield  % yield =   x 100% = 80.3481586 %= 80.3%  x 100% =  theoretical Yield  159.3067 g HCl   

3.88

Plan: Write the balanced chemical equation. Since quantities of two reactants are given, we must determine which is the limiting reactant. To determine which reactant is limiting, calculate the amount of any product formed from each reactant, assuming an excess of the other reactant. The reactant that produces less product is the limiting reagent. Any product can be used to predict the limiting reactant; in this case, CH 3Cl is used. Only 75.0% of the calculated amounts of products actually form, so the actual yield is 75% of the theoretical yield. Solution: The balanced equation is: CH4(g) + Cl2(g)  CH3Cl(g) + HCl(g) Determining the limiting reactant: Finding the amount (mol) of CH3Cl from the amount (mol) of CH4 (if Cl2 is limiting):  1 mol CH 4  Amount (mol) of CH4 = 20.5 g CH 4   = 1.278055 mol CH4  16.04 g CH 4   1 mol CH3Cl  Amount (mol) of CH3Cl from CH4 = 1.278055 mol CH 4   = 1.278055 mol CH3Cl  1 mol CH 4  Finding the amount (mol) of CH3Cl from the amount (mol) of Cl2 (if CH4 is limiting):  1 mol Cl2  Amount (mol) of Cl2 = 45.0 g Cl2   = 0.634697 mol Cl2  70.90 g Cl2   1 mol CH3Cl  Amount (mol) of CH3Cl from Cl2 = 0.634697 mol Cl2   = 0.634697 mol CH3Cl  1 mol Cl2  Chlorine is the limiting reactant and is used to determine the theoretical yield of CH 3Cl:  50.48 g CH3Cl  Mass (g) of CH3Cl (theoretical yield) = 0.634697 mol CH3Cl   = 32.0395 g CH3Cl  1 mol CH3Cl 

 actual yield  % yield =   x 100%  theoretical yield  % yield 75% Actual yield (g) of CH3Cl = theoretical yield  = 32.0395 g CH3Cl  100% 100% = 24.02962 g= 24.0 g CH3Cl

3.89

 1 mol Ca 3 N 2  Amount (mol) of Ca3N2 from N2 = 1.08851 mol N 2   = 1.08851 mol Ca3N2  1 mol N 2  Ca is the limiting reactant and is used to determine the theoretical yield of Ca3N2.

 148.26 g Ca 3 N 2  Mass (g) of Ca3N2 (theoretical yield) = 0.470725 mol Ca 3 N 2   = 69.7897 g Ca3N2  1 mol Ca 3 N 2   actual yield  % yield =   x 100%  theoretical yield 

Actual yield (g) of Ca3N2 = 3.90

% yield 93% theoretical yield  = 69.7897 g Ca 3 N2  = 64.9044 g= 64.9 g Ca3N2 100% 100%

Plan: Write the balanced equation; the formula for fluorine is F2, the formula for carbon tetrafluoride is CF4, and the formula for nitrogen trifluoride is NF3. To determine which reactant is limiting, calculate the amount of CF 4 formed from each reactant, assuming an excess of the other reactant. The reactant that produces less product is the limiting reagent. Use the limiting reagent and the mole ratio from the balanced chemical equation to determine the mass of CF4 formed. Solution: The balanced chemical equation is: (CN)2(g) + 7F2(g)  2CF4(g) + 2NF3(g) Determining the limiting reactant: Finding the amount (mol) of CF4 from the amount (mol) of (CN)2 (if F2 is limiting):  1 mol (CN) 2   2 mol CF4  Amount (mol) of CF4 from (CN)2 = 60.0 g (CN) 2    = 2.30592 mol CF4  52.04 g (CN) 2   1 mol (CN) 2  Finding the amount (mol) of CF4 from the amount (mol) of F2 (if (CN)2 is limiting):  1 mol F2   2 mol CF4  Amount (mol) of CF4 from F2 = 60.0 g F2    = 0.4511278 mol CF4  38.00 g F2   7 mol F2  F2 is the limiting reactant, and will be used to calculate the amount of CF 4 produced.  1 mol F2   2 mol CF4   88.01 g CF4  Mass (g) of CF4 = 60.0 g F2     = 39.70376 g= 39.7 g CF4  38.00 g F2   7 mol F2   1 mol CF4 

3.91 Plan: Write and balance the chemical reaction. Remember that both chlorine and oxygen exist as diatomic molecules. Use the mole ratio between oxygen and dichlorine monoxide to find the amount (mol) of dichlorine monoxide that reacted. Multiply the amount in moles by Avogadro‘s number to convert to number of molecules. Solution: a) Both oxygen and chlorine are diatomic. Scene A best represents the product mixture as there are O2 and Cl2 molecules in Scene A. Scene B shows oxygen and chlorine atoms and Scene C shows atoms and molecules. Oxygen and chlorine atoms are NOT products of this reaction. b) The balanced reaction is 2Cl2O(g) → 2Cl2(g) + O2(g). c) There is a 2:1 mole ratio between Cl2 and O2. In Scene A, there are 6 green molecules and 3 red molecules. Since twice as many Cl2 molecules are produced as there are O2 molecules produced, the red molecules are the O2 molecules. Amount (mol) of Cl2O =  2 O atoms   0.050 mol O atoms   1 mol O 2 molecules   2 mol Cl2 O  3 O2 molecules     2 mol O atoms   1 mol O  1 O atom   2   1 O 2 molecule   = 0.30 mol Cl2O  6.022x1023 Cl 2O molecules  Molecules of Cl2O =  0.30 mol Cl 2O     1 mol Cl 2O   = 1.8066x1023 molecules= 1.8x1023 Cl2O molecules

3.92

Solution: The balanced chemical equation is: 4NH3(g) + 5O2(g)  4NO(g) + 6H2O(g) Determining the limiting reactant: Finding the amount (mol) of NO from the amount of NH 3 (if O2 is limiting):  1 mol NH3   4 mol NO  Amount (mol) of NO from NH3 = 485 g NH3    = 28.47915 mol NO  17.03 g NH3   4 mol NH3  Finding the amount (mol) of NO from the amount of O 2 (if NH3 is limiting):  1 mol O 2   4 mol NO  Amount (mol) of NO from O2 = 792 g O 2    = 19.8 mol NO  32.00 g O 2   5 mol O 2  O2 is the limiting reactant, and will be used to calculate the amount of NO formed:  30.01 g NO  Mass (g) of NO = 19.8 mol NO   = 594.198 g= 594 g NO  1 mol NO  Combining all of the steps gives:  1 mol O 2   4 mol NO   30.01 g NO  Mass (g) of NO = 792 g O 2     = 594.198 g= 594 g NO  32.00 g O 2   5 mol O 2   1 mol NO  3.93

Plan: Write a balanced equation. Use the density of butane to convert the given volume of butane to mass and divide by the molar mass of butane to convert mass to amount (mol). Use the mole ratio between butane and oxygen to find the amount (mol) and then mass of oxygen required for the reaction. The mole ratio between butane and water is used to find the amount (mol) of water produced and the mole ratio between butane and carbon dioxide is used to find the amount (mol) of carbon dioxide produced. The total amount (mol) of product are multiplied by Avogadro‘s number to find the number of product molecules. Solution: The balanced chemical equation is: 2C4H10(g) + 13O2(g)  8CO2(g) + 10H2O(g)  0.579 g C4 H10   1 mol C4 H10  a) Amount (mol) of C4H10 = 5.50 mL C4 H10    = 0.054792 mol C4H10  1 mL C4 H10   58.12 g C4 H10   13 mol O 2   32.00 g O 2  Mass (g) of O2 = 0.054792 mol C4 H10    = 11.3967 g= 11.4 g O2  2 mol C4 H10   1 mol O 2   10 mol H 2 O  b) Amount (mol) of H2O = 0.054792 mol C4 H10   = 0.27396 mol= 0.274 mol H2O  2 mol C4 H10   8 mol CO 2  c) Amount (mol) of CO2 = 0.054792 mol C4 H10   = 0.219168 mol CO2  2 mol C4 H10  Total amount (mol) = 0.27396 mol H2O + 0.219168 mol CO2 = 0.493128 mol  6.022 x1023 molecules  23 23 Total molecules =  0.493128 mol    = 2.96962x10 molecules= 2.97x10 molecules  1 mol  

3.94

Plan: Write a balanced equation for the reaction. Convert the given mass of each reactant to amount (mol) by dividing by the molar mass of that reactant. Use the mole ratio from the balanced chemical equation to find the amount (mol) of NaBH4 formed from each reactant, assuming an excess of the other reactant. The reactant that produces fewer moles of product is the limiting reactant. Convert the amount (mol) of NaBH 4 obtained from the limiting reactant to grams using the molar mass. This is the theoretical yield of NaBH 4. Since there is a yield of 88.5%, the amount of NaBH4 actually obtained will be 88.5% of the theoretical yield. Solution: The balanced chemical equation is: 2NaH(s) + B2H6(g)  2NaBH4(s) Determining the limiting reactant:

Finding the amount (mol) of NaBH4 from the amount of NaH (if B2H6 is limiting):  1 mol NaH   2 mol NaBH 4  Amount (mol) of NaBH4 from NaH = 7.98 g NaH    = 0.3325 mol NaBH4  24.00 g NaH   2 mol NaH  Finding the amount (mol) of NaBH4 from the amount of B2H6 (if NaH is limiting):  1 mol B2 H 6   2 mol NaBH 4  Amount (mol) of NaBH4 from B2H6 = 8.16 g B2 H 6    = 0.58981 mol NaBH4  27.67 g B2 H 6   1 mol B2 H 6  NaH is the limiting reactant, and will be used to calculate the theoretical yield of NaBH 4.  37.83 g NaBH 4  Mass (g) of NaBH4 = 0.3325 mol NaBH 4   = 12.5785 g NaBH4  1 mol NaBH 4   actual Yield  % yield =   x 100%  theoretical Yield 

88.5%   % yield  Mass (g) of NaBH4 =  theoretical yield  =    12.5785 g NaHB4   100%   100%  = 11.13197 g= 11.1 g NaBH4 Combining all steps gives:  1 mol NaH  2 mol NaBH 4   37.83 g NaBH 4   88.5%  Mass (g) of NaBH4 = 7.98 g NaH       24.00 g NaH  2 mol NaH  1 mol NaBH 4   100%  = 11.13197 g= 11.1 g NaBH4 3.95

Plan: The spheres represent particles of solute and the amount of solute per given volume of solution determines its concentration. Concentration(mol/L) = amount (mol) of solute/volume (L) of solution. Solution: a) Box C has more solute added because it contains 2 more spheres than Box A contains. b) Box B has more solvent because solvent molecules have displaced two solute molecules. c) Box C has a higher concentration, because it has a greater amount (mol) of solute per volume of solution. d) Box B has a lower concentration, because it has a smaller amount (mol) of solute per volume of solution.

3.96

Plan: Recall that concentration (mol/L) = amount (mol) of solute/volume (L) of solution. Solution: a) cdil = concentration (mol/L) of the diluted solution cconc = concentration (mol/L) of the concentrated solution Vdil = volume of the diluted solution Vconc = volume of the concentrated solution The equation works because the quantity (moles) of solute remains the same when a solution is diluted; only the amount of solvent changes. c x V = amount (mol); cdil x Vdil = cconc x Vconc amount (mol)dil = amount (mol)conc Amount (mol) solute b) Concentration (mol/L) = volume of solution Amount (mol) CaCl2 = concentration (mol/L) · volume of solution; Mass CaCl 2 = concentration (mol/L) · volume of solution · molar mass of CaCl2.

3.97

Plan: Remember that concentration (mol/L)is amount (mol) of solute/volume of solution. Solution: Volumes may not be additive when two different solutions are mixed, so the final volume may be slightly different from 1000.0 mL. The correct method would state, ―Take 100.0 mL of the 10.0 mol/L solution and add water until the total volume is 1000. mL.‖

3.98

3.99

Plan: Recall that concentration (mol/L) = amount (mol) of solute/volume (L) of solution. Here you can use the number of particles in place of amount (mol) of solute. Solution: a) Solution B has the highest concentration (mol/L) as it has the largest number of particles, 12, in a volume of 50 mL. b) Solutions A and F both have 8 particles in a volume of 50 mL and thus the same concentration (mol/L). Solutions C, D, and E all have 4 particles in a volume of 50 mL and thus have the same concentration (mol/L). c) Mixing Solutions A and C results in 8 + 4 = 12 particles in a volume of 100 mL. That is a lower concentration (mol/L) than that of Solution B which has 12 particles in a volume of 50 mL or 24 particles in a volume of 100 mL. d) Adding 50 mL to Solution D would result in 4 particles in a total volume of 100 mL; adding 75 mL to Solution F would result in 4 particles in a volume of 100 mL. The concentration (mol/L) of each solution would be the same. e) Solution A has 8 particles in a volume of 50 mL while Solution E has the equivalent of 4 particles in a volume of 50 mL. The concentration (mol/L) of Solution E is half that of Solution A. Therefore half of the volume, 12.5 mL, of Solution E must be evaporated. When 12.5 mL of solvent is evaporated from Solution E, the result will be 2 particles in 12.5 mL or 8 particles in 50 mL as in Solution A.  moles solute  Plan: In all cases, use the known quantities and the definition of concentration (mol/L)  c   V of solution (L)   to find the unknown quantity. Volume must be expressed in litres. The molar mass is used to convert amount (mol) to mass (g). The chemical formulas must be written to determine the molar mass. (a) You will need to convert volume from millilitres to litres, multiply by the concentration (mol/L) to find amount (mol), and convert amount (mol) to mass in grams. (b) Convert mass of solute to amount (mol) and volume from mL to litres. Divide the amount (mol) by the volume. (c) Multiply the concentration (mol/L) by the volume. Solution: a) Calculating amount (mol) of solute in solution:  103 L   0.267 mol Ca(C2 H3O2 )2  Amount (mol) of Ca(C2H3O2)2 = 185.8 mL    1 mL   1L    = 0.0496086 mol Ca(C2H3O2)2 Converting from amount (mol) of solute to mass:  158.17 g Ca(C2 H3O 2 ) 2  Mass (g) of Ca(C2H3O2)2 = 0.0496086 mol Ca(C2 H3O 2 ) 2    1 mol Ca(C2 H3O 2 ) 2  = 7.84659 g= 7.85 g Ca(C2H3O2)2 b) Converting mass of solute to amount (mol):  1 mol KI  Amount (mol) of KI =  21.1 g KI    = 0.127108 moles KI  166.0 g KI   103 L  Volume (L) = 500. mL  = 0.500 L  1 mL    0.127108 mol KI concentration (mol/L) of KI = = 0.254216 mol/L= 0.254 mol/L KI 0.500 L  0.850 mol NaCN  c) Amount (mol) of NaCN = 145.6 L   = 123.76 mol= 124 mol NaCN 1L  

3.100

solute. Use Avogadro‘s number to determine the number of ions present. (c) Divide amount (millimoles) by volume (millilitres); concentration (mol/L) may not only be expressed as moles/L, but also as mmoles/mL. Solution: a) Converting mass of solute to amount (mol):  1 mol KOH  Amount (mol) of KOH = 8.42 g KOH   = 0.15006 mol KOH  56.11 g KOH 

 1L  Volume (L) of KOH solution = 0.15006 mol KOH   = 0.066398 L KOH solution  2.26 mol   1L  Volume (mL) of KOH solution = 0.066398 L KOH  3  = 66.39823 mL= 66.4 mL KOH solution  10 mL 

 2.3 mol CuCl2  b) Amount (mol) of CuCl2 = 52 L   = 119.6 mol CuCl2 L    1 mol Cu 2   Amount (mol) of Cu2+ ions = 119.6 mol CuCl2  = 119.6 mol Cu2+ ions  1 mol CuCl  2   Converting amount (mol) of ions to number of ions:  6.022 x1023 Cu 2  ions  Number of Cu2+ ions = 119.6 mol Cu 2  ions  = 7.2023x1025 ions= 7.2x1025 Cu2+ ions  1 mol Cu 2  ions   

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 135 mmol glucose  c) c glucose =   = 0.490909 mol/L= 0.491mol/L glucose 275 mL   Note: Since 1 mmol is 10–3 mol and 1 mL is 10–3 L, we can use these units instead of converting to mol and L since concentration (mol/L) is a ratio of mol/L. Concentration (mol/L) may not only be expressed as moles/L, but also as mmoles/mL.

3.101

 moles solute  Plan: In all cases, use the known quantities and the definition of concentration (mol/L)  c   V of solution (L)   to find the unknown quantity. Volume must be expressed in litres. The molar mass is used to convert amount (mol) to mass (g). The chemical formulas must be written to determine the molar mass. (a) Convert volume in millilitres to litres, multiply the volume by the concentration (mol/L) to obtain amount (mol) of solute, and convert amount (mol) to mass in grams. (b) The simplest way will be to convert the mass (milligrams) to amount (millimoles). concentration (mol/L) may not only be expressed as moles/L, but also as mmoles/mL. (c) Convert the volume from millilitres to litres and find the amount (mol) of solute and amount (mol) of ions by multiplying the volume and concentration (mol/L). Use Avogadro‘s number to determine the number of ions present. Solution: a) Calculating amount (mol) of solute in solution:  103 L   5.62 x102 mol K 2SO4  Amount (mol) of K2SO4 =  475 mL    = 0.026695 mol K2SO4  1 mL   L    Converting amount (mol) of solute to mass:  174.27 g K 2SO 4  Mass (g) of K2SO4 = 0.026695 mol K 2SO 4   = 4.6521 g= 4.65 g K2SO4  1 mol K 2SO 4 

b) Calculating amount (mmol) of solute:  7.25 mg CaCl2   1 mmol CaCl2  amount (mmol)of CaCl2 =   = 0.065327 mmol CaCl2  1 mL    110.98 mg CaCl2  Calculating concentration (mol/L):  0.065327 mmol CaCl2  concentration (mol/L) of CaCl2 =   = 0.065327 mol/L= 0.0653 mol/L CaCl2 1 mL   If you believe that concentration (mol/L) must be moles/litres then the calculation becomes: Silberberg, Amateis, Venkateswaran, Chen, Chemistry: The Molecular Nature of Matter and Change, 3rd Canadian Edition Page 3-101 Instructor‘s Solution Manual © Copyright 2021 McGraw-Hill Ryerson Ltd.

 7.25 mg CaCl2   103 g  1 mL   1 mol CaCl2  concentration (mol/L) of CaCl2 =        3   1 mL    1 mg   10 L   110.98 g CaCl2  = 0.065327 mol/L= 0.0653 mol/L CaCl2 Notice that the two central terms cancel each other. c) Converting volume in L to mL:  103 L  Volume (L) = 1 mL  = 0.001 L  1 mL   

Calculating amount (mol) of solute and amount (mol) of ions:  0.184 mol MgBr2  –4 Amount (mol) of MgBr2 = 0.001 L   = 1.84x10 mol MgBr2 1L    1 mol Mg 2   Amount (mol) of Mg2+ ions = 1.84 x 104 mol MgBr2  = 1.84x10–4 mol Mg2+ ions  1 mol MgBr  2  

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 6.022 x1023 Mg 2  ions  Number of Mg2+ ions = 1.84x104 Mg 2  ions   1 mol Mg 2  ions    = 1.1080x1020 ions= 1.11x1020 Mg2+ ions

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3.102

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moles solute   Plan: In all cases, use the known quantities and the definition of concentration (mol/L)  c  to L of solution   find the unknown quantity. Volume must be expressed in litres. The molar mass is used to convert amount (mol) to grams. The chemical formulas must be written to determine the molar mass. (a) Convert mass of solute to amount (mol) and volume from mL to litres. Divide the amount (mol) by the volume. (b) You will need to convert mass of solute to amount (mol) and divide by the concentration (mol/L) to obtain volume in litres. (c) Divide the amount (mmol) of solute by the concentration (mol/L) to obtain volume in mL. Solution: a) Calculating amount (mol) of solute:  1 mol AgNO3  Amount (mol) of AgNO3 = 46.0 g AgNO3   = 0.2707475 mol AgNO3  169.9 g AgNO3   103 L  Volume (L) = 335 mL  = 0.335 L  1 mL    Calculating the concentration (mol/L):  0.2707574 mol AgNO3  concentration (mol/L) of AgNO3 =   = 0.80823 mol/L= 0.808 mol/L AgNO3 0.335 L   b) Calculating amount (mol) of solute:  1 mol MnSO 4  Amount (mol) of MnSO4 = 63.0 g MnSO 4   = 0.417191 mol MnSO4  151.01 g MnSO 4 

Calculating volume of solution:   1L Volume (L) of solution = 0.417191 mol MnSO 4   = 1.08361 L= 1.08 L MnSO4 solution  0.385 mol MnSO 4    1mL c) Volume (mL) of ATP solution = 1.68 mmol ATP    2  6.44 x10 mmol ATP  = 26.087 mL= 26.1 mL ATP solution

3.103

litres; it only requires that the volume units match. In part c), it is necessary to find the amount (mol) of sodium ions in each separate solution, add these two mole amounts, and divide by the total volume of the two solutions. Solution: a) c1 = 0.250 mol/L KCl V1 = 37.00 mL c2 = ? V2 = 150.00 mL c1V1= c2V2 c x V1  0.250 mol / L  37.00 mL  c2 = 1 = = 0.061667 mol/L= 0.0617 mol/L KCl V2 150.0 mL b) c1 = 0.0706 mol/L (NH4)2SO4 V1 = 25.71 mL c2 = ? V2 = 500.00 mL c1V1= c2V2 c x V1  0.0706 mol / L  25.71 mL  c2 = 1 = = 0.003630 mol/L= 0.00363 mol/L (NH4)2SO4 V2 500.0 mL  103 L   0.348 mol NaCl   1 mol Na   c) Amount (mol) of Na+ from NaCl solution = 3.58 mL      1 mL   1L   1 mol NaCl    = 0.00124584 mol Na+  103 L   6.81x102 mol Na 2SO4   2 mol Na   Amount (mol) of Na+ from Na2SO4 solution =  500. mL       1 mL   1L     1 mol Na 2SO4  = 0.0681 mol Na+ + Total amount (mol) of Na ions = 0.00124584 mol Na+ ions + 0.0681 mol Na+ ions = 0.06934584 mol Na+ ions Total volume = 3.58 mL + 500. mL = 503.58 mL = 0.50358 L

total moles Na  ions 0.06934584 mol Na  ions = total volume 0.50358 L = 0.1377057 mol/L= 0.138 mol/L Na+ ions

concentration (mol/L) of Na+ =

3.104

Plan: These are dilution problems. Dilution problems can be solved by converting to amount (mol) and using the new volume; however, it is much easier to use c1V1 = c2V2. The dilution equation does not require a volume in litres; it only requires that the volume units match. Solution: a) c1 = 2.050 mol/L Cu(NO3)2 V1 = ? c2 = 0.8543 mol/L Cu(NO3)2 V2 = 750.0 mL c1V1= c2V2  0.8543 mol / L  750.0 mL c x V2 V1 = 2 = = 312.5488 mL= 312.5 mL c1 2.050 mol / L b) c1 = 1.63 mol/L CaCl2

 1.63 mol CaCl2   2 mol Cl  – c1 Cl– =   = 3.26 mol/L Cl ions   1L    1 mol CaCl2 

c1 = 3.26 mol/L Cl– V1 = ? c2 = 2.86x10–2 mol/L Cl– ions V2 = 350. mL c1V1= c2V2

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2.86x102 mol/L  350. mL  c2 x V2 = = 3.07055 mL= 3.07 mL 3.26 mol/L c1 c) c1 = 0.155 mol/L Li2CO3 V1 = 18.0 mL c2 = 0.0700mol/L Li2CO3 c1V1= c2V2 c x V1  0.155 mol/L 18.0 mL = 39.8571 mL= 39.9 mL V2 = 1 = c2  0.0700 mol/L 

V1 =

3.105

V2 = ?

Plan: Use the density of the solution to find the mass of 1 L of solution. Volume in litres must be converted to volume in mL. The 70.0% by mass translates to 70.0 g solute/100 g solution and is used to find the mass of

HNO3 in 1 L of solution. Convert mass of HNO3 to amount (mol) to obtain amount (mol)/L, concentration (mol/L). Solution:  1 mL   1.41 g solution  a) Mass (g) of 1 L of solution = 1 L solution  3    = 1410 g solution  10 L  1 mL     70.0 g HNO3  Mass (g) of HNO3 in 1 L of solution = 1410 g solution   = 987 g HNO3 in 1 L  100 g solution   1 mol HNO3  b) Amount (mol) of HNO3 = 987 g HNO3   = 15.6617 mol HNO3  63.02 g HNO3 

 15.6617 mol HNO3  concentration (mol/L) of HNO3 =   = 15.6617 mol/L= 15.7 mol/L HNO3 1 L solution   3.106

Plan: Use the concentration (mol/L) of the solution to find the amount (mol) of H2SO4 in 1 mL. Convert amount (mol) of H2SO4 to mass of H2SO4, divide that mass by the mass of 1 mL of solution, and multiply by 100 for mass percent. Use the density of the solution to find the mass of 1 mL of solution. Solution:  18.3 mol H 2SO4   103 L  –2 a) Amount (mol) of H2SO4 in 1 mL =   = 1.83x10 mol H2SO4/mL   1 L 1 mL     98.09 g H 2SO4  b) Mass of H2SO4 in 1 mL = 1.83x102 mol H 2SO4   = 1.79505 g H2SO4  1 mol H 2SO4 

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 1.84 g  Mass of 1 mL of solution = 1 mL   = 1.84 g solution  1 mL  1.79505 g H 2SO 4 mass of H 2SO4 Mass percent = 100%  = 97.5571 %= 97.6% H2SO4 by mass 100%  = 1.84 g solution mass of solution 3.107

Plan: Convert the mass of calcium carbonate to amount (mol), and use the mole ratio in the balanced chemical equation to find the amount (mol) of hydrochloric acid required to react with this amount (mol) of calcium carbonate. Use the concentration (mol/L) of HCl to find the volume that contains this amount (mol). Solution: 2HCl(aq) + CaCO3(s)  CaCl2(aq) + CO2(g) + H2O(l) Converting from mass of CaCO3 to amount (mol):  1 mol CaCO3  Amount (mol) of CaCO3 = 16.2 g CaCO3   = 0.161854 mol CaCO3  100.09 g CaCO3  Converting from amount (mol) of CaCO3 to amount (mol) of HCl:  2 mol HCl  Amount (mol) of HCl = 0.161854 mol CaCO3   = 0.323708 mol HCl  1 mol CaCO3  Converting from amount (mol) of HCl to volume:    1 mL  1L Volume (mL) of HCl = 0.323708 mol HCl    3  = 845.1906 mL= 845 mL HCl solution  0.383 mol HCl   10 L 

3.108

Plan: Convert the volume of NaOH solution to litres and multiply by the concentration (mol/L) of the solution to obtain amount (mol) of NaOH. Use the mole ratio in the balanced chemical equation to find the amount (mol) of NaH2PO4 required to react with this amount (mol) of NaOH. Finally, convert amount (mol) of NaH 2PO4 to mass. Solution: NaH2PO4(s) + 2NaOH(aq)  Na3PO4(aq) + 2H2O(l)

 103 L  Volume (L) = 43.74 mL  = 0.04374 mL  1 mL    Finding amount (mol) of NaOH:  0.285 mol NaOH  Amount (mol) of NaOH = 0.04374 L   = 0.0124659 mol NaOH 1L  

Converting from amount (mol) of NaOH to amount (mol) of NaH 2PO4:  1 mol NaH 2 PO 4  Amount (mol) of NaH2PO4 = 0.0124659 mol NaOH   = 0.00623295 mol NaH2PO4  2 mol NaOH  Converting from amount (mol) of NaH2PO4 to mass:

3.109

 119.98 g NaH 2 PO 4  Mass (g) of NaH2PO4 = 0.00623295 mol NaH 2 PO 4   = 0.747829 g= 0.748 g NaH2PO4  1 mol NaH 2 PO 4  Plan: The first step is to write and balance the chemical equation for the reaction. Multiply the concentration (mol/L) and volume of each of the reactants to determine the amount (mol) of each. To determine which reactant is limiting, calculate the amount of barium sulfate formed from each reactant, assuming an excess of the other reactant. The reactant that produces less product is the limiting reagent. Use the limiting reagent and the mole ratio from the balanced chemical equation to determine the mass of barium sulfate formed. Solution: The balanced chemical equation is: BaCl2(aq) + Na2SO4(aq)  BaSO4(s) + 2NaCl(aq)  103 L   0.160 mol BaCl2  Amount (mol) of BaCl2 = 35.0 mL   = 0.00560 mol BaCl2  1 mL   1L    Finding the amount (mol) of BaSO4 from the amount (mol) of BaCl2 (if Na2SO4 is limiting):  1 mol BaSO 4  Amount (mol) of BaSO4 from BaCl2 = 0.00560 moL BaCl2   = 0.00560 mol BaSO4  1 mol BaCl2 

 103 L   0.065 mol Na 2SO4  Amount (mol) of Na2SO4 = 58.0 mL   = 0.00377 mol Na2SO4  1 mL   1L    Finding the amount (mol) of BaSO4 from the amount (mol) of Na2SO4 (if BaCl2 is limiting):  1 mol BaSO 4  Amount (mol) BaSO4 from Na2SO4 = 0.00377 moL Na 2SO 4   = 0.00377 mol BaSO4  1 mol Na 2SO 4  Sodium sulfate is the limiting reactant. Converting from amount (mol) of BaSO4 to mass:  233.4 g BaSO 4  Mass (g) of BaSO4 = 0.0377 moL BaSO 4   = 0.879918 g= 0.88 g BaSO4  1 mol BaSO 4  3.110

Plan: The first step is to write and balance the chemical equation for the reaction. Use the concentration (mol/L) and volume of each of the reactants to determine the amount (mol) of each. To determine which reactant is limiting, calculate the amount of either product formed from each reactant, assuming an excess of the other reactant. The reactant that produces less product is the limiting reagent. Use the limiting reagent and the mole ratio from the balanced chemical equation to determine the amount of the excess reactant that reacts. The difference between the amount of excess reactant that reacts and the initial amount of reactant supplied gives the amount of excess reactant remaining. Solution: The balanced chemical equation is: H2SO4(aq) + 2NaOH(aq)  Na2SO4(aq) + 2H2O(l) We can use either product to determine the limiting reactant. We will use sodium sulfate.  103 L   0.210 mol H 2SO4  Amount (mol) of H2SO4 = 350.0 mL   = 0.0735 mol H2SO4  1 mL   1L   

Finding the amount (mol) of Na2SO4 from the amount (mol) of H2SO4 (if NaOH is limiting):  1 mol Na 2SO 4  Amount (mol) of Na2SO4 from H2SO4 = 0.0735 moL H 2SO 4   = 0.0735 mol Na2SO4  1 mol H 2SO 4   0.196 mol NaOH  Amount (mol) of NaOH = 0.500 L   = 0.0980 mol NaOH 1L   Finding the amount (mol) of Na2SO4 from the amount (mol) of NaOH (if H2SO4 is limiting):  1 mol Na 2SO 4  Amount (mol) of Na2SO4 from NaOH = 0.0980 mol NaOH   = 0.0490 mol Na2SO4  2 mol NaOH 

NaOH is the limiting reactant and will be used in the remainder of the calculations.  1 mol H 2SO 4  Amount (mol) of H2SO4 that react with NaOH = 0.0980 mol NaOH   = 0.0490 mol H2SO4  2 mol NaOH  Amount (mol) of H2SO4 remaining = initial amount (mol) – amount (mol) reacting with NaOH = 0.0735 mol – 0.0490 mol = 0.0245 mol H2SO4 3.111

 amount (mol) solute  Plan: Recall the definition of concentration (mol/L)  c   . Convert mass of solute to volume (L) of solution   amount (mol) and volume from mL to litres. Divide the amount (mol) by the volume. Solution:  1 mol NaClO  Amount (mol) of NaClO = 20.5 g NaClO   = 0.2785896 mol NaClO  74.44 g NaClO   103 L  Volume (L) = 375 mL  = 0.375 L  1 mL     0.2753896 mol NaClO  concentration (mol/L) of NaClO =   = 0.73437 mol/L= 0.734 mol/L NaClO 0.375 L  

3.112

Plan: The first part of the problem is a simple dilution problem (c1V1 = c2V2). The volume in units of litres can be used. In part b), convert mass of HCl to amount (mol) and use the concentration (mol/L) to find the volume that contains that amount (mol). Solution: a) c1 = 11.7 mol/L V1 = ? c2 = 3.5 mol/L V2 = 3.0 L  3.5 mol/L  3.0 L c x V2 V1 = 2 = = 0.897436 L c1 11.7 mol/L Instructions: Be sure to wear goggles to protect your eyes! Pour approximately 2.0 L of water into the container. Add slowly and with mixing 0.90 L of 11.7 mol/L HCl into the water. Dilute to 3.0 L with water. b) Converting from mass of HCl to amount (mol) of HCl:  1 mol HCl  Amount (mol) of HCl = 9.66 g HCl   = 0.264948 mol HCl  36.46 g HCl  Converting from amount (mol) of HCl to volume:    1 mL  1L Volume (mL) of solution = 0.264948 mol HCl    3   11.7 mol HCl   10 L  = 22.64513 mL= 22.6 mL muriatic acid solution

3.113

Plan: Use the volume and concentration (mol/L) of HCl to find the amount (mol) of HCl added to the metal. That amount (mol) minus the amount (mol) of HCl that remain after reaction gives the amount (mol) of HCl that actually reacted. Use the amount (mol) of reacted HCl and the mole ratio in the balanced chemical equation to find the amount (mol) of Mg that reacted. Convert amount (mol) of Mg to mass of Mg, divide that mass by the mass of impure metal sample, and multiply by 100 to find mass %.

Solution: Mg(s) + 2HCl(aq)  MgCl2(aq) + H2(g)  0.750 mol HCl  Amount (mol) of HCl added =   0.100 L  = 0.0750 mol HCl 1L   Amount (mol) of HCl reacting with Mg = amount (mol) of added HCl – amount (mol) of HCl remaining = 0.0750 mol – 0.0125 mol HCl = 0.0625 mol HCl  1 mol Mg  Amount (mol) of Mg reacting = 0.0625 mol HCl   = 0.03125 mol Mg  2 mol HCl   24.31 g Mg  Mass (g) of Mg = 0.03125 mol Mg   = 0.7596875 g Mg  1 mol Mg  mass of Mg 0.7596875 g Mg Mass percent Mg = 100%  = 100%  = 57.552 %= 57.6% Mg mass of sample 1.32 g sample

3.114

Plan: Review the discussion on the polar nature of water. Solution: Water is polar because the distribution of its bonding electrons is unequal, resulting in polar bonds, and the shape of the molecule (bent) is unsymmetrical.

3.115

Plan: Review the discussion on water soluble compounds. Solution: Ionic and polar covalent compounds are most likely to be soluble in water. Because water is polar, the partial charges in its molecules are able to interact with the charges, either ionic or dipole-induced, in other substances.

3.116

Plan: Solutions that conduct an electric current contain electrolytes. Solution: Ions must be present in an aqueous solution for it to conduct an electric current. Ions come from ionic compounds or from other electrolytes such as acids and bases.

3.117

Plan: Review the discussion on ionic compounds in water. Solution: The ions on the surface of the solid attract the water molecules (cations attract the ―negative‖ ends and anions attract the ―positive‖ ends of the water molecules). The interaction of the solvent with the ions overcomes the attraction of the oppositely charged ions for one another, and they are released into the solution.

3.118

Plan: Recall that ionic compounds dissociate into their ions when dissolved in water. Examine the charges of the ions in each scene and the ratio of cations to anions. Solution: a) CaCl2 dissociates to produce one Ca2+ ion for every two Cl– ions. Scene B contains four 2+ ions and twice that number of 1– ions. b) Li2SO4 dissociates to produce two Li+ ions for every one SO42– ion. Scene C contains eight 1+ ions and half as many 2– ions. c) NH4Br dissociates to produce one NH4+ ion for every one Br– ion. Scene A contains equal numbers of 1+ and 1– ions.

3.119

Plan: Write the formula for magnesium nitrate and note the ratio of magnesium ions to nitrate ions. Solution: Upon dissolving the salt in water, magnesium nitrate, Mg(NO 3)2, would dissociate to form one Mg2+ ion for every two NO3– ions, thus forming twice as many nitrate ions. Scene B best represents a volume of magnesium nitrate solution. Only Scene B has twice as many nitrate ions (red circles) as magnesium ions (blue circles).

3.120

Plan: Review the discussion of ionic compounds in water. Solution:

In some ionic compounds, the force of the attraction between the ions is so strong that it cannot be overcome by the interaction of the ions with the water molecules. These compounds will be insoluble in water. 3.121

Plan: Review the discussion of covalent compounds in water. Solution: The interaction with water depends on the structure of the molecule. If the interaction is strong, the substance will be soluble; otherwise, the substance will not be very soluble. Covalent compounds that contain polar groups interact well with the polar solvent water and therefore dissolve in water. Covalent compounds that do not contain polar bonds are not soluble in water.

3.122

Plan: Review the discussion of covalent compounds in water. Solution: Some covalent compounds that contain the hydrogen atom dissociate into ions when dissolved in water. These compounds form acidic solutions in water; three examples are HCl, HNO3, and HBr.

3.123

Plan: Compounds that are soluble in water tend to be ionic compounds or covalent compounds that have polar bonds. Many ionic compounds are soluble in water because the attractive force between the oppositely charged ions in an ionic compound are replaced with an attractive force between the polar water molecule and the ions when the compound is dissolved in water. Covalent compounds with polar bonds are often soluble in water since the polar bonds of the covalent compound interact with those in water. Solution: a) Benzene, a covalent compound, is likely to be insoluble in water because it is nonpolar and water is polar. b) Sodium hydroxide (NaOH) is an ionic compound and is therefore likely to be soluble in water. c) Ethanol (CH3CH2OH) will likely be soluble in water because it contains a polar –OH bond like water. d) Potassium acetate (KC2H3O2) is an ionic compound and will likely be soluble in water.

3.124

Plan: Compounds that are soluble in water tend to be ionic compounds or covalent compounds that have polar bonds. Many ionic compounds are soluble in water because the attractive force between the oppositely charged ions in an ionic compound are replaced with an attractive force between the polar water molecule and the ions when the compound is dissolved in water. Covalent compounds with polar bonds are often soluble in water since the polar bonds of the covalent compound interact with those in water. Solution: a) Lithium nitrate is an ionic compound and is expected to be soluble in water. b) Pentane (C5H12) has no bonds of significant polarity, so it would be expected to be insoluble in the polar solvent water. c) Glycine (H2NCH2COOH) is a covalent compound, but it contains polar N–H and O–H bonds. This would make the molecule interact well with polar water molecules, and make it likely that it would be soluble. d) Ethylene glycol (HOCH2CH2OH) molecules contain polar O–H bonds, similar to water, so it would be expected to be soluble.

3.125

Plan: Substances whose aqueous solutions conduct an electric current are electrolytes such as ionic compounds, acids, and bases. Solution: a) Cesium bromide, CsBr, is a soluble ionic compound, and a solution of this salt in water contains Cs + and Br– ions. Its solution conducts an electric current. b) HI is a strong acid that dissociates completely in water. Its aqueous solution contains H + and I– ions, so it conducts an electric current.

3.126

Plan: Substances whose aqueous solutions conduct an electric current are electrolytes such as ionic compounds, acids, and bases. Solution: a) Potassium sulfate, K2SO4, is an ionic compound that is soluble in water, producing K+ and SO42– ions. Its solution conducts an electric current. b) Sucrose is neither an ionic compound, an acid, nor a base, so it would be a nonelectrolyte (even though it‘s soluble in water). Its solution does not conduct an electric current.

3.127

b) Each mole of Ba(OH)2•8H2O forms 1 mole of Ba2+ ions and 2 moles of OH– ions, or a total of 3 moles of ions: Ba(OH)2•8H2O(s) → Ba2+(aq) + 2OH–(aq). The waters of hydration become part of the larger bulk of water. Convert mass to amount (mol) using the molar mass.  1 mol Ba(OH) 2 •8H 2O    3 mol ions Amount (mol) of ions =  25.4 g Ba(OH) 2 •8H 2O      315.4 g Ba(OH) 2 •8H 2O   1 mol Ba(OH) 2 •8H 2O  = 0.2415980 mol= 0.242 mol of ions c) Each mole of LiCl produces 2 moles of ions (1 mole of Li + ions and 1 mole of Cl– ions): LiCl(s) → Li+(aq) + Cl–(aq). Recall that a mole contains 6.022x1023 entities, so a mole of LiCl contains 6.022x1023 units of LiCl, more easily expressed as formula units.    2 mol ions  1 mol LiCl Amount (mol) of ions = 3.55x1019 FU LiCl    23  6.022 x10 FU LiCl   1 mol LiCl 





= 1.17901x10–4 mol= 1.18x10–4 mol of ions

3.128





= 7.03839x10–5 = 7.04x10–5 mol of ions c) Each mole of Sr(HCO3)2 produces 3 moles of ions (1 mole of Sr2+ ions and 2 moles of HCO3– ions): Sr(HCO3)2(s) → Sr2+(aq) + 2HCO3–(aq). Recall that a mole contains 6.022x1023 entities, so a mole of Sr(HCO3)2 contains 6.022x1023 units of Sr(HCO3)2, more easily expressed as formula units.    1 mol Sr(HCO3 )2 3 mol ions Amount (mol) of ions = 4.03x1019 FU Sr(HCO3 ) 2   6.022 x1023 FU Sr(HCO )   1 mol Sr(HCO )  3 2  3 2   = 2.0076x10–4 = 2.01x10–4 mol of ions



3.129



b) Each mole of NiBr2•3H2O forms 1mole of Ni2+ ions and 2 moles of Br– ions, or a total of 3 moles of ions: NiBr2•3H2O(s)  Ni2+(aq) + 2Br–(aq). The waters of hydration become part of the larger bulk of water. Convert mass to amount (mol) using the molar mass.  1 mol NiBr2 •3H 2O    3 mol ions Amount (mol) of ions = 6.88 x 103 g NiBr2 •3H 2O     272.54 g NiBr2 •3H 2O   1 mol NiBr2 •3H 2O 





= 7.5732x10–5 mol= 7.57x10–5 mol of ions c) Each mole of FeCl3 forms 1mole of Fe3+ ions and 3 moles of Cl– ions, or a total of 4 moles of ions: FeCl3(s) Fe3+(aq) + 3Cl–(aq). Recall that a mole contains 6.022x1023 entities, so a mole of FeCl3 contains 6.022x1023 units of FeCl3, more easily expressed as formula units.    4 mol ions  1 mol FeCl3 Amount (mol) of ions = 2.23x1022 FU FeCl3   6.022x1023 FU FeCl   1 mol FeCl  3 3   = 0.148124 mol= 0.148 mol of ions



3.130



Plan: To determine the total amount (mol) of ions released, write an equation that shows the compound dissociating into ions with the correct molar ratios. Convert mass and formula units to amount (mol) of compound and use the molar ratio to convert amount (mol) of compound to amount (mol) of ions. Solution: a) Each mole of Na2HPO4 forms 2 moles of Na+ ions and 1 mole of HPO42– ions, or a total of 3 moles of ions: Na2HPO4(s)  2Na+(aq) + HPO42–(aq).  3 mol ions  Amount (mol) of ions =  0.734 mol Na 2 HPO 4    = 2.202mol = 2.20 mol of ions  1 mol Na 2 HPO 4  b) Each mole of CuSO4•5H2O forms 1 mole of Cu2+ ions and 1 mole of SO42– ions, or a total of 2 moles of ions: CuSO4•5H2O(s)  Cu2+(aq) + SO42–(aq). The waters of hydration become part of the larger bulk of water. Convert mass to amount (mol) using the molar mass.  1 mol CuSO4 •5H 2O    2 mol ions Amount (mol) of ions =  3.86 g CuSO4 •5H 2O       249.70 g CuSO 4 •5H 2O   1 mol CuSO 4 •5H 2O  = 3.0907x10–2 mol= 3.09x10–2 mol of ions c) Each mole of NiCl2 forms 1mole of Ni2+ ions and 2 moles of Cl– ions, or a total of 3 moles of ions: NiCl2(s)  Ni2+(aq) + 2Cl–(aq). Recall that a mole contains 6.022x1023 entities, so a mole of NiCl2 contains 6.022x1023 units of NiCl2, more easily expressed as formula units.    3 mol ions  1 mol NiCl2 Amount (mol) of ions = 8.66x1020 FU NiCl 2   6.022x1023 FU NiCl   1 mol NiCl  2  2   –3 –3 = 4.31418x10 = 4.31x10 mol of ions



3.131



Plan: To determine the total amount (mol) of ions released, write an equation that shows the compound dissociating into ions with the correct molar ratios. Convert the information given to amount (mol) of compound and use the molar ratio to convert amount (mol) of compound to amount (mol) of ions. Avogadro‘s number is used to convert amount (mol) of ions to numbers of ions. Solution: a) Each mole of AlCl3 forms 1mole of Al3+ ions and 3 moles of Cl– ions: AlCl3(s)  Al3+(aq) + 3Cl–(aq). Concentration (mol/L) and volume must be converted to amount (mol) of AlCl 3.  103 L   0.45 mol AlCl3  Amount (mol) of AlCl3 = 130. mL    = 0.0585 mol AlCl3  1 mL   L   

 1 mol Al3   Amount (mol) of Al3+ =  0.0585 mol AlCl3   = 0.0585 mol = 0.058 mol Al3+  1 mol AlCl  3    6.022x1023 Al3  22 22 3+ Number of Al3+ ions = 0.0585 mol Al 3   1 mol Al3  = 3.52287x 10 ions= 3.5x10 Al ions  





 3 mol Cl  Amount (mol) of Cl– =  0.0585 mol AlCl3   = 0.1755 mol= 0.18 mol Cl–  1 mol AlCl  3   

 

Cl  = 1.05686x10 ions= 1.1x10 Cl ions 0.1755 mol Cl   6.022x10 1 mol Cl 

Number of Cl– ions =

–



  b) Each mole of Li2SO4 forms 2 moles of Li+ ions and 1 mole of SO42– ions: Li2SO4(s) 2Li+(aq) + SO42–(aq).  103 L   2.59 g Li 2SO4   1 mol Li 2SO 4  Amount (mol) of Li2SO4 =  9.80 mL      1 mL   1L  109.95 g Li 2SO 4    = 2.3085x10–4 mol Li2SO4  2 mol Li   Amount (mol) of Li+ = 2.3085x104 mol Li2SO4  = 4.6170x10–4 mol= 4.62x10–4 mol Li+  1 mol Li SO  2 4  







 

x 10 Li  = 2.7804x10 ions= 2.78x10 Li ions  4.6170x10 mol Li   6.022 1 mol Li 4

Number of Li+ ions =







 1 mol SO42   Amount (mol) of SO42– = 2.3085x104 mol Li2SO4  = 2.3085x10–4 mol= 2.31x10–4 mol SO42–  1 mol Li SO  2 4  





 6.022 x 1023 SO42   2.3085x104 mol SO4 2    1 mol SO 2   4   = 1.39018x1020 = 1.39x1020 SO42– ions c) Each mole of KBr forms 1 mole of K+ ions and 1 mole of Br– ions: KBr(s)  K+(aq) + Br–(aq).  103 L   3.68 x1022 FU KBr    1 mol KBr Amount (mol) of KBr =  245 mL      = 0.01497 mol KBr 23  1 mL   L     6.022x10 FU KBr  Number of SO42– ions =





 1 mol K   Amount (mol) of K+ =  0.01497 mol KBr   = 0.01497 mol= 1.50x10–2 mol K+  1 mol KBr   

 6.022 x1023 K   Number of K+ ions = 0.01497 mol K   = 9.016x1021 ions= 9.02x1021 K+ ions  1 mol K    





 1 mol Br   Amount (mol) of Br– =  0.01497 mol KBr   = 0.01497 mol= 1.50x10–2 mol Br–  1 mol KBr    Number of Br– ions = 3.132



 

x10 Br  = 9.016x10 ions= 9.02x10 Br ions 0.01497 mol Br   6.022 1 mol Br 

–



  Plan: To determine the total amount (mol) of ions released, write an equation that shows the compound dissociating into ions with the correct molar ratios. Convert the information given to amount (mol) of compound and use the molar ratio to convert amount (mol) of compound to amount (mol) of ions. Avogadro‘s number is used to convert amount (mol) of ions to numbers of ions. Solution: a) Each mole of MgCl2 forms 1 mole of Mg2+ ions and 2 moles of Cl– ions: MgCl2(s)  Mg2+(aq) + 2Cl–(aq).  103 L   1.75 mol MgCl2  Amount (mol) of MgCl2 =  88.mL    = 0.154 mol MgCl2  1 mL   L     1 mol Mg 2   Amount (mol) of Mg2+ =  0.154 mol MgCl2   = 0.154 mol = 0.15 mol Mg2+  1 mol MgCl  2  



2 

Mg  = 9.27388x10 ions= 9.3x10 Mg ions 0.154 mol Mg   6.022x10 1 mol Mg 2

Number of Mg2+ ions =

2





 2 mol Cl  Amount (mol) of Cl– =  0.154 mol MgCl2   = 0.308mol = 0.31 mol Cl–  1 mol MgCl  2    6.022x1023 Cl   0.308 mol Cl   = 1.854776x1023 ions= 1.9x1023 Cl– ions  1 mol Cl     b) Each mole of Al2(SO4)3 forms 2 moles of Al3+ ions and 3 moles of SO42– ions: Al2(SO4)3(s)  2Al3+(aq) + 3SO42–(aq).  103 L   0.22 g Al2 (SO4 )3   1 mol Al2 (SO4 )3  Amount (mol) of Al2(SO4)3 =  321 mL      1 mL   1L  342.17 g Al2 (SO4 )3    = 2.06389x10–4 mol Al2(SO4)3  2 mol Al3  Amount (mol) of Al3+ = 2.06389x104 mol Al2 (SO4 )3   1 mol Al (SO )  2 4 3  = 4.12777x10–4 mol= 4.1x10–4 mol Al3+  6.022x1023 Al3  Number of Al3+ ions = 4.12777x104 mol Al3  = 2.4857x1020 ions= 2.5x1020 Al3+ ions  1 mol Al3    Number of Cl– ions =













 3 mol SO4 2   Amount (mol) of SO42– = 2.06389x104 mol Al2 (SO4 )3   1 mol Al (SO )  2 4 3  = 6.191659x10–4 mol= 6.2x10–4 mol SO42 6.022 x1023 SO42   Number of SO42– ions = 6.191659 x104 mol SO42    1 mol SO 2   4   20 20 2– = 3.7286x10 ions= 3.7x10 SO4 ions c) Each mole of CsNO3 forms 1 mole of Cs+ ions and 1 mole of NO3– ions: CsNO3(s)  Cs+(aq) + NO3–(aq)  8.83x1021 FU CsNO3    1 mol CsNO3 Amount (mol) of CsNO3 = 1.65 L   = 0.024194 mol CsNO3   23    6.022x10 FU CsNO  L 3  









 1 mol Cs  Amount (mol) of Cs+ =  0.024194 mol CsNO3   = 0.024194 mol= 0.0242 mol Cs+  1 mol CsNO  3    6.022x1023 Cs  Number of Cs+ ions = 0.024194 mol Cs  = 1.45695x1022 ions= 1.46x1022 Cs+ ions  1 mol Cs   





 1 mol NO3  Amount (mol) of NO3– =  0.024194 mol CsNO3   = 0.024194 mol= 0.0242 mol NO3–  1 mol CsNO  3    6.022x1023 NO3  Number of NO3– ions = 0.024194 mol NO3  = 1.45695x1022 ions= 1.46x1022 NO3– ions  1 mol NO   3  



3.133



Plan: The acids in this problem are all strong acids, so you can assume that all acid molecules dissociate completely to yield H+ ions and associated anions. One mole of HClO4, HNO3, and HCl each produce one mole of H+ upon dissociation, so amount (mol) H+ = amount (mol) acid. Calculate the amount (mol) of acid by multiplying the concentration (mol/L) by the volume in litres. Solution: a) HClO4(aq) → H+(aq) + ClO4–(aq)

 0.25 mol  + Amount (mol) H+ = mol HClO4 = 1.40 L   = 0.35 mol H  1L  b) HNO3(aq) → H+(aq) + NO3–(aq)  103 L   0.92 mol  Amount (mol) H+ = mol HNO3 =  6.8 mL   = 6.256x10–3 mol= 6.3x10–3 mol H+  1 mL   1 L    c) HCl(aq) → H+(aq) + Cl–(aq)  0.085 mol  + Amount (mol) H+ = mol HCl =  2.6 L    = 0.221 mol= 0.22 mol H 1 L   3.134

Plan: The acids in this problem are all strong acids, so you can assume that all acid molecules dissociate completely to yield H+ ions and associated anions. One mole of HBr, HI, and HNO 3 each produce one mole of H+ upon dissociation, so amount (mol) H+ = amount (mol) acid. Calculate the amount (mol) of acid by multiplying the concentration (mol/L) by the volume in litres. Solution: a) HBr(aq) → H+(aq) + Br–(aq)  103 L   0.75 mol  Amount (mol) H+ = mol HBr = 1.4 mL   = 1.05x10–3 mol= 1.0x10–3 mol H+  1 mL   1 L    + – b) HI(aq) → H (aq) + I (aq)  103 L   1.98 mol  Amount (mol) H+ = mol HI =  2.47 mL   = 4.8906x10–3 mol= 4.89x10–3 mol H+  1 mL   1 L    c) HNO3(aq) → H+(aq) + NO3–(aq)  103 L   0.270 mol  + Amount (mol) H+ = mol HNO3 =  395 mL    = 0.10665 mol= 0.107 mol H  1 mL   1 L   

3.135

Plan: Convert the mass of the seawater in kg to g and use the density to convert the mass of the seawater to volume in L. Convert mass of each compound to amount (mol) of compound and then use the molar ratio in the dissociation of the compound to find the amount (mol) of each ion. The concentration (mol/L) of each ion is the amount (mol) of ion divided by the volume of the seawater. To find the total concentration (mol/L) of the alkali metal ions [Group 1], add the amount (mol) of the alkali metal ions and divide by the volume of the seawater. Perform the same calculation to find the total concentration (mol/L) of the alkaline earth metal ions [Group 2] and the anions (the negatively charged ions). Solution: a) The volume of the seawater is needed.  103 g  cm3   1 mL   103 L  Volume (L) of seawater = 1.00 kg   = 0.97560976 L  1 kg   1.025 g   1 cm3   1 mL       The amount (mol) of each ion are needed. If an ion comes from more than one source, the total amount (mol) are needed. NaCl: Each mole of NaCl forms 1 mole of Na+ ions and 1 mole of Cl– ions: NaCl(s)  Na+(aq) + Cl–(aq)  1 mol NaCl  Amount (mol) of NaCl =  26.5 g NaCl    = 0.4534565 mol NaCl  58.44 g NaCl 

 1 mol Na   Amount (mol) of Na+ =  0.4534565 mol NaCl  = 0.4534565 mol Na+  1 mol NaCl     1 mol Cl  Amount (mol) of Cl– =  0.4534565 mol NaCl  = 0.4534565 mol Cl–  1 mol NaCl   

MgCl2: Each mole of MgCl2 forms 1 mole of Mg2+ ions and 2 moles of Cl– ions: MgCl2(s)  Mg2+(aq) + 2Cl–(aq)  1 mol MgCl 2  Amount (mol) of MgCl2 =  2.40 g MgCl2    = 0.025207 mol MgCl2  95.21 g MgCl2 

 1 mol Mg 2   Amount (mol) of Mg2+ =  0.025207 mol MgCl2   = 0.025207 mol Mg2+  1 mol MgCl  2    2 mol Cl  Amount (mol) of Cl– =  0.025207 mol MgCl2   = 0.050415 mol Cl–  1 mol MgCl  2   MgSO4: Each mole of MgSO4 forms 1 mole of Mg2+ ions and 1 mole of SO42– ions: MgSO4(s)  Mg2+(aq) + SO42–(aq)  1 mol MgSO4  Amount (mol) of MgSO4 =  3.35 g MgSO4    = 0.0278285 mol MgSO4  120.38 g MgSO4 

 1 mol Mg 2   Amount (mol) of Mg2+ =  0.0278285 mol MgSO4   = 0.0278285 mol Mg2+  1 mol MgSO  4    1 mol SO42   Amount (mol) of SO42– =  0.0278285 mol MgSO4   = 0.0278285 mol SO42–  1 mol MgSO  4   CaCl2: Each mole of CaCl2 forms 1 mole of Ca2+ ions and 2 moles of Cl– ions: CaCl2(s)  Ca2+(aq) + 2Cl–(aq)  1 mol CaCl2   1 mol Ca 2   Amount (mol) of CaCl2 = 1.20 g CaCl2    = 0.0108128 mol CaCl2    110.98 g CaCl2   1 mol CaCl2   1 mol Ca 2   Amount (mol) of Ca2+ =  0.0108128 mol CaCl2   = 0.0108128 mol Ca2+  1 mol CaCl  2  

 2 mol Cl  Amount (mol) of Cl– =  0.0108128 mol CaCl2   = 0.0216255 mol Cl–  1 mol CaCl  2   KCl: Each mole of KCl forms 1 mole of K+ ions and 1 mole of Cl– ions: KCl(s)  K+(aq) + Cl–(aq)  1 mol KCl  Amount (mol) of KCl = 1.05 g KCl    = 0.0140845 mol KCl  74.55 g KCl 

 1 mol K   Amount (mol) of K+ =  0.0140845 mol KCl  = 0.0140845 mol K+  1 mol KCl     1 mol Cl  Amount (mol) of Cl– =  0.0140845 mol KCl  = 0.0140845 mol Cl–  1 mol KCl    NaHCO3: Each mole of NaHCO3 forms 1 mole of Na+ ions and 1 mole of HCO3– ions: NaHCO3(s)  Na+(aq) + HCO3–(aq)  1 mol NaHCO3  Amount (mol) of NaHCO3 =  0.315 g NaHCO3    = 0.00374955 mol NaHCO3  84.01 g NaHCO3 

 1 mol Na   Amount (mol) of Na+ =  0.00374955 mol NaHCO3   = 0.00374955 mol Na+  1 mol NaHCO  3   Silberberg, Amateis, Venkateswaran, Chen, Chemistry: The Molecular Nature of Matter and Change, 3rd Canadian Edition Page 3-114 Instructor‘s Solution Manual © Copyright 2021 McGraw-Hill Ryerson Ltd.

 1 mol HCO3  Amount (mol) of HCO3– =  0.00374955 mol NaHCO3   = 0.00374955 mol HCO3–  1 mol NaHCO  3   NaBr Each mole of NaBr forms 1 mole of Na+ ions and 1 mole of Br– ions: NaBr(s)  Na+(aq) + Br–(aq)  1 mol NaBr  Amount (mol) of NaBr =  0.098 g NaBr    = 0.0009524735 mol NaBr  102.89 g NaBr 

 1 mol Na   Amount (mol) of Na+ =  0.0009524735 mol NaBr   = 0.0009524735 mol Na+  1 mol NaBr     1 mol Br   Amount (mol) of Br– =  0.0009524735 mol NaBr   = 0.0009524735 mol Br–  1 mol NaBr    Total amount (mol) of each ion: Cl–: 0.4534565 mol + 0.050415 mol + 0.0216255 mol + 0.0140845 mol = 0.5395815 mol Cl – + Na : 0.4534565 mol+ 0.00374955 mol + 0.0009524735 mol = 0.458158523 mol Na+ Mg2+: 0.025207 mol+ 0.0278285 mol= 0.0530355 mol Mg2+ SO42–: 0.0278285 mol SO42– Ca2+: 0.0108128 mol Ca2+ + K: 0.0140845 mol K+ – HCO3 : 0.00374955 mol HCO3– Br–: 0.0009524735 mol Br– Dividing each amount (mol) by the volume (0.97560976 L) and rounding to the proper number of significant figures gives the concentration (mol/L) mol c= L 0.5395815 mol Cl c Cl– = = 0.55307 mol/L = 0.553 mol/L Cl– 0.97560976 L 0.45815823 mol Na  = 0.469612 mol/L = 0.470 mol/L Na+ 0.97560976 L

c Na+ =

c Mg2+ =

0.0530355 mol Mg2  = 0.054361 mol/L = 0.0544 mol/L Mg2+ 0.97560976 L

c SO42– =

0.0278285 mol SO4 2  = 0.028524 mol/L = 0.0285 mol/L SO42– 0.97560976 L

c Ca2+ =

0.0108128 mol Ca 2  = 0.011083 mol/L = 0.0111 mol/L Ca2+ 0.97560976 L

c K+ =

0.0140845 mol K 0.97560976 L

c HCO3– =

= 0.014437 mol/L = 0.0144 mol/L K+

0.00374955 mol HCO3 = 0.003843 mol/L = 0.00384 mol/L HCO3– 0.97560976 L

0.0009524735 mol Br  = 0.0009763 mol/L = 0.00098 mol/L Br–. 0.97560976 L b) The alkali metal cations are Na+ and K+. Add the concentrations (mol/L) of the individual ions. 0.469612 mol/L Na+ + 0.014437 mol/L K+ = 0.484049 mol/L = 0.484 mol/L total for alkali metal cations c) The alkaline earth metal cations are Mg2+ and Ca2+. Add the concentrations (mol/L) of the individual ions. 0.054361 mol/L Mg2+ + 0.011083 mol/L Ca2+ = 0.065444 mol/L = 0.0654 mol/L total for alkaline earth cations d) The anions are Cl–, SO42–, HCO3–, and Br–. Add the concentrations (mol/L) of the individual ions. 0.55307 mol/L Cl– + 0.028524 mol/L SO42– + 0.003843 mol/L HCO3– + 0.0009763 mol/L Br–

c Br– =

= 0.5864133 mol/L = 0.586 mol/L total for anions 3.136

Plan: Use the concentration (mol/L) and volume of the ions to find the amount (mol) of each ion. Multiply the amount (mol) of each ion by that ion‘s charge to find the total amount (mol) of charge. Since sodium ions have a +1 charge, the total amount (mol) of charge equals the amount (mol) of sodium ions. Solution:  0.015 mol Ca 2   2+ Amount (mol) of Ca2+ = 1.0 x103 L   = 15 mol Ca  L  





 2 mol charge  Amount (mol) of charge from Ca2+ = 15 mol Ca 2   = 30. mol charge from Ca2+  1 mol Ca 2    





 0.0010 mol Fe3  3+ Amount (mol) of Fe3+ = 1.0x103 L   = 1.0 mol Fe  L  





 3 mol charge  Amount (mol) of charge from Fe3+ = 1.0 mol Fe3   = 3.0 mol charge from Fe3+  1 mol Fe3     Total amount (mol) of charge = 30. mol + 3.0 mol = 33 mol charge  1 mol Na   Amount (mol) Na+ =  33 mol charge   = 33 mol Na+  1 mol charge   





3.137

Plan: Review the definition of spectator ions. Solution: Ions in solution that do not participate in the reaction do not appear in a net ionic equation. These spectator ions remain as dissolved ions throughout the reaction. These ions are only present to balance charge.

3.138

Plan: Write the total ionic and net ionic equations for the reaction given. The total ionic equation shows all soluble ionic substances dissociated into ions. The net ionic equation eliminates the spectator ions. New equations may be written by replacing the spectator ions in the given equation by other spectator ions. Solution: The reaction given has the following total ionic and net ionic equations: Total ionic equation: Ba2+(aq) + 2NO3–(aq) + 2Na+(aq) + CO32–(aq)  BaCO3(s) + 2Na+(aq) + 2NO3–(aq) The spectator ions are underlined and are omitted: Net ionic equation: Ba2+(aq) + CO32–(aq)  BaCO3(s) New equations will contain a soluble barium compound and a soluble carbonate compound. The ―new‖ equations are: Molecular: BaCl2(aq) + K2CO3(aq)  BaCO3(s) + 2KCl(aq) Total ionic: Ba2+(aq) + 2Cl–(aq) + 2K+(aq) + CO32–(aq)  BaCO3(s) + 2K+(aq) + 2Cl–(aq) Molecular: BaBr2(aq) + (NH4)2CO3(aq)  BaCO3(s) + 2NH4Br(aq) Total ionic: Ba2+(aq) + 2Br–(aq) + 2NH4+(aq) + CO32–(aq)  BaCO3(s) + 2NH4+(aq) + 2Br–(aq)

3.139

Plan: Write the balanced chemical equation. Change masses of CO2 and O2 to amount (mol). Use stoichiometry and limiting reagents to find the amount (mol) of CO 2 formed. Use stoichiometry to determine the reagent in excess and its amount. Use the actual amount and the amount found above of CO2 to determine the percent yield.

Solution: a) 2 CO (g) + O2 (g)  2 CO2 (g) b)

We need 2 mol of CO for each mol of O2; therefore 0.625 mol of O 2 would need 1.25 mol of CO, which we do not have. So CO is the limiting reagent (LR). Therefore, 0.714 mol of CO 2 is formed. Silberberg, Amateis, Venkateswaran, Chen, Chemistry: The Molecular Nature of Matter and Change, 3rd Canadian Edition Page 3-116 Instructor‘s Solution Manual © Copyright 2021 McGraw-Hill Ryerson Ltd.

( )( ) c) Since all the CO is used, the amount of O2 used is ½ n(CO) or 0.714 mol/2 = 0.357 mol. Since we started with 0.625 mol of O2, we are left with 0.625 – 0.357 = 0.268 mol of O2, which corresponds to ( )( ) d) If the actual amount of CO2 formed is 12.7 g, the percent yield is

3.140

Plan: First determine the empirical formula. Convert the mass of each element to amount (mol) by dividing the mass of each element by its molar mass. Divide each of the amount (mol) by the smaller value, and convert to whole numbers to get the empirical formula. The subscripts in the molecular formula are whole-number multiples of the subscripts in the empirical formula. To find this whole number, divide the molar mass of the compound by its empirical formula mass. Multiply each subscript in the empirical formula by the whole number. Solution:  1 mol S  Amount (mol) of S = 2.288 g S   = 0.0713439 mol S  32.07 g S   1 mol N  Amount (mol) of N = 1.000 g N   = 0.0713776 mol N  14.01 g N  Preliminary formula is S0.0713439N0.0713776 Converting to integer subscripts (dividing all by the smallest subscript): S 0.0713439 N 0.0713776 → S1N1 0.0713439

0.0713439

The empirical formula is SN. Formula mass of empirical formula = 32.07 g/mol S + 14.01 g/mol N = 46.08 g/mol  184.27 g/mol  molar mass of compound Whole-number multiple = =   =4 empirical formula mass  46.08 g/mol  Multiplying the subscripts in SN by 4 gives S4N4 as the molecular formula. 3.141

Plan: The first step is to write and balance the chemical equation for the reaction. Convert the mass of each reactant to amount (mol) by dividing by the molar mass, remembering that the mass of the phosphoric acid reactant is 85% of the given mass of phosphoric acid solution. To determine which reactant is limiting, calculate the amount of hydroxyapatite formed from each reactant, assuming an excess of the other reactant. The reactant that produces less product is the limiting reagent. Use the limiting reagent and the mole ratio from the balanced chemical equation to determine the amount of hydroxyapatite that forms. Solution: a) The balanced equation is: 5Ca(OH)2(aq) + 3H3PO4(aq) → Ca5(PO4)3(OH)(s) + 9H2O(l) b) Finding the amount (mol) of Ca5(PO4)3(OH) from the amount (mol) of Ca(OH)2 (if H3PO4 is limiting):  1 mol Ca(OH) 2  Amount (mol) of Ca(OH)2 = 100. g Ca(OH) 2   = 1.349528 mol Ca(OH)2  74.10 g Ca(OH) 2   1 mol Ca 5 (PO 4 )3 (OH)  Amount (mol) of Ca5(PO4)3(OH) from Ca(OH)2 = 1.349528 mol Ca(OH) 2   5 mol Ca(OH) 2   = 0.2699056 mol Ca5(PO4)3(OH) Finding the amount (mol) of Ca5(PO4)3(OH) from the amount (mol) of H3PO4 (if Ca(OH)2 is limiting):    1 mol H3 PO 4  85 g H3 PO 4 Amount (mol) of H3PO4 = 100. g H3 PO 4 solution     100. g H3 PO 4 solution   97.99 g H3 PO 4 

= 0.867435 mol H3PO4

 1 mol Ca 5 (PO 4 )3 (OH)  Amount (mol) of Ca5(PO4)3(OH) from H3PO4 = 0.867435 mol H3 PO 4 solution   3 mol H3 PO 4   = 0.289145 mol Ca5(PO4)3(OH) Ca(OH)2 is the limiting reactant, and will be used to calculate the amount of Ca 5(PO4)3(OH) produced.  502.32 g Ca 5 (PO 4 )3 (OH)  Mass (g) of Ca5(PO4)3(OH) = 0.2699056 mol Ca 5 (PO 4 )3 (OH)    1 mol Ca 5 (PO 4 )3 (OH) 

= 135.57898 g= 140 g Ca5(PO4)3(OH) 3.142

Plan: The amount (mol) of narceine and the amount (mol) of water are required. We can assume any mass of narceine hydrate (we will use 100 g), and use this mass to determine the amount (mol) of hydrate. The amount (mol) of water in the hydrate is obtained by taking 10.8% of the 100 g mass of hydrate and converting the mass to amount (mol) of water. Divide the amount (mol) of water by the amount (mol) of hydrate to find the value of x. Solution: Assuming a 100 g sample of narceine hydrate:  1 mol narceine hydrate  Amount (mol) of narceine hydrate = 100 g narceine hydrate    499.52 g narceine hydrate  = 0.20019 mol narceine hydrate   10.8% H 2 O Mass (g) of H2O = 100 g narceine hydrate   = 10.8 g H2O  100% narceine hydrate   1 mol H 2 O  Amount (mol) of H2O = 10.8 g H 2 O   = 0.59933 mol H2O  18.02 g H 2 O  moles of H 2 O 0.59933 mol = x= =3 moles of hydrate 0.20019 mol Thus, there are three water molecules per mole of hydrate. The formula for narceine hydrate is narceine•3H2O.

3.143

C2H6

30.07

6 mol(1.008 g/mol) 100%  = 20.11% H 30.07 g

Propane

C3H8

44.09

8 mol(1.008 g/mol) 100%  = 18.29% H 44.09 g

Benzene

C6H6

78.11

6 mol(1.008 g/mol) 100%  = 7.743% H 78.11 g

Ethanol

C2H5OH

46.07

6 mol(1.008 g/mol) 100%  = 13.13% H 46.07 g

Cetyl palmitate

C32H64O2

480.83

64 mol(1.008 g/mol) 100%  = 13.42% H 480.83 g

The hydrogen percentage decreases in the following order: Ethane > Propane > Cetyl palmitate > Ethanol > Benzene