MAGAZINE
NICKEL
T HE M AG A ZINE DE VOT ED TO NICK EL A ND I T S A PPLIC ATIONS NICKEL, VOL. 36, Nº 3, 2021
Social nickel enabling social life Mini capacitors keep us connected
Vaccine production contributing to social contact
Sociable nickel plays nicely with others
REMKO DE WAAL EPA-EFE MX3D
CASE STUDY 23 3D-PRINTED PEDESTRIAN BRIDGE, AMSTERDAM Stainless steel: Arcelor Mittal Architects: Joris Laarman Lab Lead Engineers: Arup Manufacturer: MX3D, a Dutch company focused on large-scale robotic wire arc additive manufacturing (WAAM) Location: Oudezijds Achterburgwal, one of the oldest and most famous canals in the centre of Amsterdam Length: 12.2 m Width: 6.3 m Height: 2.1 m Tested under a 17 ton load, 4,500 kg of Type 308LSi stainless steel was used. Time to print: 6 months NICKEL, VOL. VOL. 36, 36, Nº Nº 3, 3, 2021 2021 22 || NICKEL,
The world's first 3D-printed stainless steel bridge is open in the Netherlands. The designers took advantage of additive manufacturing which enables almost any design to be rapidly built with little scrap and options for either on-site or factory fabrication. In this case, the 12 m bridge was built off-site. Made of 4,500 kilograms of Type 308LSi (UNS S30888) stainless steel welding wire, the fabrication relied on four 6-axis industrial robots fitted with welding torches to 3D-print the structure. These machines produce the bridge sections using an intricate layering process resulting in a raw steel finish. Nickel makes 300 series stainless steel weldable, strong and tough, thus highly amenable for 3D-print constructions. Designers used two methods of 3D-printing—Direct Energy Deposition (DED) and Powder Bed Fusion (PBF). With DED, the printer
feeds material, usually in powder or wire form, through a pen-like nozzle, and an intense heat source melts the metal on contact. Similarly, PBF enables higher resolution, allowing the designers more precision to achieve their vision. A process known as digital laser sintering, was used to weld together the 3D-printed bridge by large robots. It has been fitted out with sensors to collect data that keep track of its performance. On July 15, 2021, it was officially unveiled by Queen Máxima, assisted by, what else? A ribbon-cutting robot.
EDITORIAL: SOCIAL NICKEL ENABLING SOCIAL LIFE
Nickel is a social metal. A strange idea, but when you think about it, it is the basis for what makes nickel really useful. In this edition of Nickel, we examine nickel’s social character, from its chemical and physical properties to the way it enables applications that help humankind connect. Nickel readily mixes with most metals. This allows a wide range of heat- and corrosion-resistant, strong, tough, ductile and weldable alloys with varying useful, even critical physical properties to be produced. It also enables metals to work together in finishes on metals and plastics, and all these social skills are solving problems in almost every aspect of our lives. And what about the applications for nickel which facilitate our own social networking? We look at the role of nickel in miniature capacitors which help power our smart phones – the essential tool for any socialite. Once those electronics that have kept us connected reach the end of their useful life, what happens to them? We discuss the growing area of nickel in electronic waste and how it is being reclaimed from these applications to serve again. Recovered nickel is often reused in alloys such as stainless steel, where producers can take advantage again of its sociable nature. We also examine how nickel-containing stainless steel has helped the pharmaceutical sector rise to the challenge of producing the vaccines that are so badly needed to combat diseases like Covid-19, allowing us to socialise once more.
Nickel enables applications that help humankind connect, thanks to its chemical and physical properties.
This issue celebrates the numerous and diverse applications that nickel contributes to. Even the tiniest amount of nickel in so many applications, collectively makes a huge difference. And as we start to gather again, we are reminded, it’s often the little things that matter! Clare Richardson Editor, Nickel NICKEL, VOL. 36, Nº 3, 2021 | 3
02
Case study no. 23 3D-printed bridge
03
Editorial Social nickel enabling social life
04 06
NICKEL
NOTABLES
CONTENTS
Nickel notables In your pocket Mini capacitors
08
Mining electronic waste A new life for used metals
10
Vital nickel Vaccine production
12
Nickel The sociable metal
13
More power to concrete
Nickel alloys Invar
14
Technical Q&A Buried stainless steel pipes New publications UNS details
YEN STRANDQVIST/CHALMERS UNIVERSITY OF TECHNOLOGY
15 15 16
LUMA Arles Tower Inspired by van Gogh
Nickel magazine is published by Nickel Institute www.nickelinstitute.org Dr. Hudson Bates, President Clare Richardson, Editor communications@nickelinstitute.org Contributors: Gary Coates, Jim Fritz, Richard Matheson, Geir Moe, Kim Oakes, Odette Ziezold Design: Constructive Communications Material has been prepared for the general information of the reader and should not be used or relied upon for specific applications without first securing competent advice. While the material is believed to be technically correct, Nickel Institute, its members, staff and consultants do not represent or warrant its suitability for any general or specific use and assume no liability or responsibility of any kind in connection with the information herein. ISSN 0829-8351 Printed in Canada on recycled paper by Hayes Print Group Cover: iStock©coffeekai Stock image credits: pg. 3 iStock©Orbon Alija pg. 6 Shutterstock©OlegDoroshin pg 8. iStock©Lya_Cattel, pg 9. iStock©pagadesign pg.10 iStock©SDI Productions, pg.11 iStock©Drazen Zigic, pg. 12 iStock©maki_shmaki
4 | NICKEL, VOL. 36, Nº 3, 2021
Turn an apartment into a giant battery? Researchers Tang and Zhang at Chalmers University in Sweden have developed a prototype for a rechargeable, cement-based battery. The breakthrough involved embedding a concrete mix with short carbon fibres, an iron-coated mesh of carbon fibre, and mesh coated in nickel, using iron for the anode and nickel for the cathode. Research yielded an average energy density of 7 watt-hours per square meter. Low compared to commercial batteries, but through sheer volume, the technique is capable of storing and delivering a substantial amount of energy. Concrete is the world’s most widely used construction material, so when the cement-based battery is incorporated into buildings, bridges, and sidewalks in the future, it could be a construction game-changer towards greater sustainability.
CHINA ARCHITECTURE DESIGN & RESEARCH GROUP PHOTO: ZHANG GUANGYUAN
Branching out in China It’s a futuristic forest where whimsical architecture meets technological ingenuity. Located in Nanjing, China and part of the Jiangsu Garden Expo, the Future Garden features 42 stainless steel trees that act as umbrellas supporting the roof. Each tree is the same and they are all connected to one another. The acrylic panel is the top of the lotus leaf, the first of its kind in the world. The area, transformed from reclaimed mines and an abandoned cement plant, is now a delight to the eye, despite its complex ground conditions and construction challenges. It was successfully completed using 1,000 tons of nickelcontaining Type 316L (UNS S31603) stainless steel.
ELECTRICAIR
Flying electric
In a significant step towards greener skies, ElectricAir's founder Gary Freedman recorded the world’s longest flight over water by a pure electric plane, making a 40-minute journey across the New Zealand’s Cook Strait. Powered by two nickel-containing lithium battery packs to drive the electric motor, they can last up to 90 minutes and be recharged in under an hour. The solo flight came 101 years after the first conventional aircraft flight over the strait that separates New Zealand’s two main islands and timed to coincide with the opening of the October 2021 U.N. Climate Summit in Scotland. “The start of radical change.” Freedman says, “Bigger, longer-range electric aircraft are on the way and are ideal for short haul routes.”
Measuring the sweet in sweat Scientists from Pennsylvania State University have
the glucose as verified by commercially available
published the details of an innovative, noninvasive,
monitors. “We want to work to see how we can apply this
low-cost sensor that can detect glucose in sweat, in
technology for daily monitoring of a patient,” Cheng said.
Biosensors and Bioelectronics. First constructed with laser-induced graphene (LIG), it was “not sensitive to glucose at all”. They then chose nickel because of PENNSYLVANIA STATE UNIVERSITY
its “robust glucose sensitivity.” Attaching the reusable device to the arm one hour and three hours after a meal, the subject performed a brief workout. While the concentration of glucose in sweat is about 100 times less than in blood, the new device accurately measured NICKEL, VOL. 36, Nº 3, 2021 | 5
NICKEL IN YOUR POCKET MINIATURE CAPACITORS KEEP US CONNECTED Nickel has allowed MLCCs to shrink in size by reducing the thickness of the dielectric layer, while maintaining the same capacitance values.
The smartphone in your pocket is a complex electronic system incorporating many different functions that are all powered by the same internal battery. An electronic circuit is composed of individual electronic components, such as resistors, transistors, capacitors, inductors, and diodes, connected by conductive wires or traces through which electric current can flow. The capacitor is a component which has the ability or “capacity” to store energy in the form of an electrical charge, much like a small rechargeable battery. Capacitors are essential for an electronic circuit to function. If power supplies could provide a constant voltage regardless of the current draw and there were no components that produced electrical noise, capacitors would not be required. But fluctuating voltage is a reality and has to be smoothed out. The capacitor provides buffer storage that always makes sure there is enough current for all components and filters out ‘noise’ to ensure the various electronic subcircuits function as designed. In consumer electronics, there are often hundreds and in the case of high-end smartphones, such as an iPhone, more than a thousand miniature capacitors. Known as MultiLayer Ceramic Capacitors (MLCCs), they can be as small as a grain of sand on your favourite vacation beach. Their function is to decouple subcircuits from each other, so they are not affected by inconsistencies
6 | NICKEL, VOL. 36, Nº 3, 2021
in the power supply caused by activity in another subcircuit. The anatomy of an MLCC
In its basic form, a MLCC consists of two or more parallel metal plates (electrodes) which are electrically separated by an insulating material known as a dielectric. Currently MLCCs can possess 600 parallel electrodes less than one micrometre thick. MLCCs were first invented more than 40 years ago to replace disc ceramic capacitors. Disc ceramic capacitors have two lone leads which were typically mounted through holes in the printed circuit board. They were neither conducive to rapid installation nor miniaturisation of electronics. The rectangular shape of the MLCC allowed for high-speed surface mounting. MLCCs initially used silver-palladium (Ag-Pd) as the electrode, and were replaced by nickel in the early 2000s. Nickel electrodes offered
TAIYO YUDEN EUROPE GMBH
In 2020, 4,800 tonnes of nickel powder were used to make Multi-Layer Ceramic Capacitors, which can be as small as a grain of sand. several advantages over Ag-Pd, including:
bands, aerospace systems as well
• Thinner dielectric layers • Higher capacitance values (better volumetric efficiency) • Lower cost
Advanced Driver Assistance Systems
Nickel is now the material of choice in the manufacture of MLCCs. It has allowed MLCCs to shrink in size by reducing the thickness of the dielectric layer, while maintaining the same capacitance values. Nickelcontaining MLCCs are found in smart phones, wearable electronics such as smart watches and fitness
as smart cars, particularly cars with (ADAS). In fact, you will find MLCCs anywhere there are miniaturised electronics. As many as four trillion MLCCs are manufactured annually of which 40% are used in the assembly of smart phones. In 2020, 4,800 tonnes of nickel were used in the fabrication of MLCCs to create the tiny components that keep us connected and without which our electronic devices would not function. NICKEL, VOL. 36, Nº 3, 2021 | 7
MINING ELECTRONIC WASTE A NEW LIFE FOR USED METALS “Our processes are based on complex lead/copper/nickel metallurgy, using these base metals as collectors for precious metals and other metals, so called "impurities", such as antimony, bismuth, tin, selenium, tellurium and indium.” —Umicore
“E-scrap, including LIB-scrap, is placed in a copper smelting converter after pretreatment. After that, it is separated into crude nickel sulfate by electrolysis and sent to a nickel refinery to become pure nickel sulfate, which is used as a raw material for batteries.” —Sumitomo Metal Mining
“Thanks to the modular structure of our new recycling systems, we are able to react very flexibly to the market and needs and thus return more and more metalcontaining materials to the material cycle.” —Aurubis
8 | NICKEL, VOL. 36, Nº 3, 2021
Think of the largest cruise ship. Then imagine how much it weighs – just over 100,000 tonnes, in fact. Now think about 500 of those ships, and what they weigh. That is the staggering amount of new electronic waste that we generate every year. Over 53 million tonnes in 2020 alone, according to the Global E-waste Monitor. And every year there will be more, with 74 million tonnes projected for 2030. But today, only about 10 million tonnes of e-waste gets truly recycled, meaning we are recovering the metals and other valuable materials, including nickel. The remaining 43 million tonnes of e-waste, estimated to contain recoverable material worth around US$55 billion, is not recycled, and is landfilled instead. Cellphones, computers, TVs, appliances and other electronic components which we use every day are finding an unsatisfactory end-of-life. Complex recovery
There is nickel in the e-waste, although the amount depends on the particular electronic components being recycled. Recovery is quite complex, as nickel is a “social metal”, mixing well with most other metals. Typically, the nickel content may be between 0.5 and 2% of the total weight of a component, far less than its copper and iron content. Nickel is used in electronics for its key attributes, for example as shown by its use in MLCCs (see page 6). The precious metals – gold, palladium and silver – even if present in much smaller quantities, may have a larger monetary value. But in the circular economy, we need to recover as much as we can, and the Nickel Institute members are doing their part. Proprietary processing
Each nickel producer involved in recycling has its own and often
proprietary processing route for e-waste. It starts with pre-processing, as e-waste contains a large amount of plastics, ceramics and other non-metallic materials that have a separate path – the metallic fraction is what is of prime interest. Even there, steel in appliances can be magnetically separated out and sent to steel mills for direct recycling. Shredding of, for example, circuit boards and even whole cellphones into small pieces can help in the separation process. Some companies will have a separate recycling line for the various types of batteries, the supply of which for recycling is expected to increase rapidly as electric vehicle batteries come to the end of their life. The processes involved in recovery of the metals, copper, nickel and the precious metals, involve pyrometallurgy (high temperature), hydrometallurgy (dissolution in acids) or both. Some companies can recover other metals used in electronics, such as indium, selenium, bismuth and other metals present in even smaller amounts. Important raw material
E-waste has been handled by some of our members for over 30 years now. It is an important raw material, and they are willing to process it in greater quantities in the future. This material, now waste, mined many years ago, can be made into new and essential electronic components to be enjoyed by us all. Even though the amount of nickel in e-waste is relatively small, the nickel industry is a valuable partner with society in accomplishing the goal of creating a circular economy.
“Vale traditionally has pyrometallurgically processed recycled materials but is evaluating hydrometallurgical routes as well. We have a robust flowsheet with several options to process this material and will continue to advance our ability to process Black Mass.” —Vale
“Our Rönnskär smelter in northern Sweden is one of the world's largest recyclers of metal from electronic material. The facility also minimises its emissions and generates district heating from electronic material.” —Boliden
“We have recycled more than one million tonnes of electronic scrap since the 1990s.” —Glencore
NICKEL, VOL. 36, Nº 3, 2021 | 9
VITAL NICKEL IN VACCINE PRODUCTION
Tangential flow filtration skid used in vaccine production
Although 2020 and 2021 were filled with much bad news and suffering caused by COVID-19, vaccine development was the one bright spot that continues to bring hope that the pandemic may be brought under control. The rapid development of highly effective vaccines by pharmaceutical companies, scientists and governments will certainly be remembered as one of the greatest accomplishments of our time.
COTTER BROTHERS CORP
With the development of these vaccines, the next challenge is to produce hundreds of millions of doses as quickly as possible, but traditional pharmaceutical vaccine production capacity is not readily available. The construction and approval of a new pharmaceutical plant with bio-reactors and the supporting “water for injection” (WFI) and clean-in-place (CIP) systems can take 18 months or longer to be operational. During a pandemic this timing is just too slow. To speed up vaccine production the 10 | NICKEL, VOL. 36, Nº 3, 2021
industry has turned to single-use technologies. With this approach, polymer materials are used for the bio-reactors which are sanitised using gamma irradiation and are disposed after one use. This technology does not require the supporting WFI and CIP systems and production can be brought on line in a much shorter time period. The most widely used material of construction in traditional pharmaceutical plants is nickel-containing Type 316L (UNS S31603) stainless steel and
With the single-use approach a polymer bag is used as the bio-reactor. This method employs less stainless steel and other corrosion resistant alloys than traditional production. Although single-use production does displace some stainless steels, the nickel-containing austenitic stainless steels continue to play a vital role in vaccine production. The polymer bio-reactor bags must be placed inside metal containers called “totes” for mechanical support and temperature control. The totes are constructed from polished Type 304L (S30403) stainless steel to maintain hygiene and cleanability of the production environment. The purification of the vaccine product is an important and necessary step in the production process. With single-use production the purification is achieved using tangential flow filtration (TFF). This technique employs membrane filtration where a feed stream passes parallel to a membrane face. A portion of the stream passes
through the membrane, the permeate, and the remainder of the stream, the retentate, is recirculated back to the feed. During vaccine production this process is performed in a purification skid. The structural frame of the skid is constructed of polished Type 304L stainless steel and the tubing, which is in contact with the product, is constructed of electropolished Type 316L stainless steel.
Large rectangular totes used for vaccine production
Pharmaceutical equipment is most often built to the ASME BPE (Bioprocessing Equipment) standard. It covers materials, design, fabrication, inspections, testing and certification where high levels of hygiene are required. The worldwide demand for COVID-19 vaccines will continue for the foreseeable future and large traditional production facilities will eventually be built. Until that is accomplished single-use production will continue to be employed for rapid production of these lifesavers. In either case, nickel-containing alloys will continue to serve as vital materials of construction.
COTTER BROTHERS CORP
when increased corrosion resistance is needed higher alloyed stainless steels or nickel alloys are selected.
NICKEL, VOL. 36, Nº 3, 2021 | 11
NICKEL THE SOCIABLE METAL Remember back to your early days in school when the teacher might include the statement “plays nicely with others” in a report card? This also describes nickel, a versatile element which will alloy with most metals. The breadth of nickel-containing alloys and their applications is unmatched.
Nickel readily mixes with iron, copper, chromium, molybdenum, titanium, cobalt, and tungsten producing useful and critical engineering alloys.
Nickel forms binary (two element) alloys with copper, molybdenum, titanium, iron and chromium. It also forms tertiary alloys where iron is the third element either because iron is essential to the alloy’s properties, or the presence of iron is not objectionable to the alloy’s properties and thus is added to reduce cost. Then there are multi-element alloys which contain many of the aforementioned elements, in particular the corrosion-resistant stainless steels and nickel-based alloys. The presence of
Corrosion resistant stainless steels and nickel-base alloys
Multielement alloys
Tertiary element alloys
Binary element alloys
Name Alloy 400 Cu-Ni 70-30 Alloy B-2 Nitinol Alloy 36 Nichrome 80-20 Kovar ® Alloy 80 Alloy 600 Alloy 33 MP35N® Alloy 188 Alloy 617 316 6% Mo SS Alloy 625 Alloy C-276 Alloy 718 310 330
UNS
Ni
N04400 C71500 N10665 N01555 K93600 N06003 K94610 N14080 N06600 R20033 R30035 R30188 N06617 S31600 S31254 N06625 N10276 N07718 S31000 N08330
66 30 72 55 36 80 29 80 75 32 35 22 54 10 18 60 58 52 20 35
* Approximate composition of significant elements
12 | NICKEL, VOL. 36, Nº 3, 2021
Composition, wt.%* Other 32 Cu 70 Cu 28 Mo 45 Ti 64 Fe 20 Cr 17 Co, 54 Fe 5 Mo, 14 Fe 15 Cr, 8 Fe 33 Cr, 34 Fe 35 Co, 20 Cr, 10 Mo 40 Co, 22 Cr, 14 W 12.5 Co, 22 Cr, 9 Mo 16 Cr, 2 Mo, 70 Fe 20 Cr, 6 Mo, 55 Fe 21 Cr, 8 Mo, 3.5 Nb, 4 Fe 15 Cr, 16 Mo, 5 Fe, 3.5 W 19 Cr, 5 Nb, 3 Mo 25 Cr, 52 Fe 19 Cr, 1.2 Si, 44 Fe
chromium, molybdenum and other elements provide corrosion resistance. But nickel is essential to maintain an austenitic microstructure which gives these alloys their excellent fabrication and welding characteristics. Higher concentrations of nickel are required as the content of these other elements is increased. Thanks to the ‘sociability’ of nickel, many corrosion-resistant alloys are possible. Without them the production of most of the chemicals used by industry would be more difficult and more expensive using other less satisfactory metals.
Characteristics Corrosion resistance Corrosion resistance Corrosion resistance Shape memory and super elasticity Low expansion Electrical heating elements Low expansion High magnetic permeability Corrosion resistance Corrosion resistance High strength, corrosion resistance High temperature service High temperature service Corrosion resistance Corrosion resistance Corrosion resistance Corrosion resistance High strength, corrosion resistance High temperature service High temperature service
INVAR – A NOBEL ALLOY In the temperature range from room temperature up to the maximum temperature of your kitchen oven, about 260 °C (500 °F), steel which is an alloy of iron and carbon expands in size. Generally, this expansion is not noticeable nor large enough to cause a problem, but for some equipment such as precision measuring devices and mechanical clocks, thermal expansion in EMILIO SEGRÈ VISUAL ARCHIVES
this temperature range is a significant problem. In 1895, Swiss physicist Charles Edouard Guillaume discovered the uniquely low coefficient of expansion of the iron-nickel alloy with 64% iron and 36% nickel for which he was awarded the Nobel Prize in Physics in 1920. This alloy was named Invar, which comes from the word invariable, referring to its relative lack of expansion or contraction in this temperature range. Between 20 °C to 100 °C (68 °F to 212 °F) the rate of thermal expansion of Invar is about one-tenth that of ordinary steel. As nickel increases from 36 to 50%, the thermal expansion rate increases. This has led to the development of an entire family of iron-nickel alloys with their rate of thermal expansion optimised for specific temperature ranges, which are collectively known as controlled expansion alloys.
aerospace applications to tight tolerances. Bi-metal strips with a low expansion alloy on one side and a high expansion alloy on the other side will function as a thermally activated switch. Invar also retains good strength and toughness at cryogenic temperatures and is used to manufacture membranes for containment of Liquefied Natural Gas (LNG).
These alloys allow for the tailoring of expansion rates to match those of various glasses and ceramics to produce hermetic glass-to-metal and ceramic-to-metal seals to protect electronics from gases and liquids. Moulds can be produced to manufacture composite materials for
Swiss physicist and Nobel Prize winner Charles Edouard Guillaume
Invar ® can be used as a membrane layer for LNG ship transport.
This iron-nickel alloy system is critical for producing precision measurement equipment, thermal switches and protecting electronics.
Controlled expansion alloys Fe
K93600
36
bal
Kovar®
K94610
29
bal
Alloy 42
K94100
41
bal
Alloy 52
N14052
52
bal
Co ROLAND MOURON CUVE
Ni Invar 36 ®
17
NICKEL, VOL. 36, Nº 3, 2021 | 13
ASK AN EXPERT FAQ FROM THE NICKEL INSTITUTE TECHNICAL ADVICE LINE
NICKEL
O N L I N E
Geir Moe P.Eng. is the Technical Inquiry Service Coordinator at the Nickel Institute. Along with other material specialists situated around the world, Geir helps end-users and specifiers of nickelcontaining materials seeking technical support. The team is on hand to provide technical advice free of charge on a wide range of applications such as stainless steel, nickel alloys and nickel plating to enable nickel to be used with confidence. https://inquiries.nickelinstitute.org/
WWW.NICKELINSTITUTE.ORG
SUBSCRIBE to Nickel magazine free of charge and receive a printed copy or an e-mail notice when a new issue is published. www.nickelinstitute.org READ Nickel magazine online in several languages. www.nickelinstitute.org/nickel-magazine/ SEARCH BACK ISSUES of Nickel magazine from our online archive, going back to 2009. www.nickelinstitute.org/nickel-magazine/ FOLLOW US on Twitter @NickelInstitute JOIN US on LinkedIn – visit the Nickel Institute’s page WATCH nickel-related videos on the Nickel Institute YouTube channel www.youtube.com/user/NickelInstitute
14 | NICKEL, VOL. 36, Nº 3, 2021
Q A
Q: I would like to know if buried stainless steel piping needs corrosion protection measures for pipe exterior surfaces (soil side).
A: This is not a simple question because soil types vary in their corrosivity and corrosivity can vary depending upon the time of year. Generally, buried steel pipelines and tanks suffer from corrosion when the soil presents one or more of the following conditions:
• • • •
High moisture content A pH value less than 4.5 A resistivity less than 1000 Ω-cm Presence of chlorides, sulphides and bacteria • Presence of stray currents If the soil is well compacted so oxygen is excluded, then corrosion would be stifled. Free draining soils that lose water content quickly, typically above the water table, are less corrosive than soils that hold moisture for a long time. The presence of chloride in soils in marine areas or adjacent to roadways where de-icing salts are applied can also be problematic. And organic matter or sulphides can provide nutrients for microbial activity which may cause microbiologically influenced corrosion (MIC). In most circumstances Type 316L (UNS S31603) is a suitable alloy. But if corrosive soil conditions cannot be mitigated by use of well
drained backfill or because of the presence of corrosive species, such as chloride, the choices are to use a more corrosion resistant stainless steel, such as 2205 (S32205), 2507 (S32750) or 6Mo Type (S31254) or, wrapping in petrolatum tape. Coatings are not usual because of the probability of mechanical damage. Useful references that discuss this topic, include: Soil Corrosion Test for Stainless Steel Pipes – 10-year Burial Test Result Report available for free download from: www.nickelinstitute.org Corrosion Resistance of Stainless Steels in Soils and Concrete by Pierre-Jean Cunat available for free download from: www.worldstainless.org
NEW PUBLICATIONS Two new AISC stainless steel standards published AISC (American Institute of Steel Construction) has published two new stainless steel standards. ANSI/AISC 370-21 Specification for Structural Stainless Steel Buildings and ANSI/AISC 31321 Code of Standard Practice for Structural Stainless Steel Buildings are available to download free of charge at: www.aisc.org/ publications/steel-standards/ The availability of these eagerly anticipated standards will help engineers, materials specifiers and designers take full advantage of the
outstanding properties of stainless steel in building, construction and large infrastructure projects such as bridges. These codes are significant because they are the first US specifications for structural use of heavier gauge hot rolled and welded stainless steel sections. The AISC codes are also used by structural engineers in many other global regions. Nickel Institute and Team Stainless consultants Nancy Baddoo (Steel Construction Institute, UK) and Catherine Houska, along with steel producers and product manufacturers have worked closely with AISC over the last three years to develop these important new standards.
New Video: Nickel Enabling Clean Energy The Nickel Institute has created a short, fun and dynamic video showing what nickel contributes to technologies that help combat climate change. The video presents an industry that is taking its responsibilities, acknowledges that
more needs to be done and produces a product that has a critical role in clean energy technologies. Available on the Nickel Institute’s YouTube channel and website. nickelinstitute.org
UNS DETAILS UNS
Chemical compositions (% by weight) of the alloys and stainless steels mentioned in this issue of Nickel.
C
Cr
Cu
Fe
Mn
Mo
N
Ni
P
S
Si
S30403 pg 11
0.03 max
18.020.0
-
bal
2.00 max
-
-
8.012.0
0.045 max
0.030 max
1.00 max
S30888 pg 2
0.03 max
19.522.0
0.50 max
bal
1.02.5
0.75 max
9.011.0
0.03 max
0.03 max
0.65 1.00
S31254 pg 14
0.020 max
19.520.5
0.501.00
bal
1.00 max
6.06.5
0.180.22
17.518.5
0.030 max
0.010 max
0.80 max
S31603 pg 5,10,11,14,16
0.030 max
16.018.0
-
bal
2.00 max
2.003.00
-
10.014.0
0.045 max
0.030 max
1.00 max
S32205 pg 14
0.030 max
22.023.0
-
bal
2.00 max
3.003.50
0.140.20
4.506.50
0.030 max
0.020 max
1.00 max
S32750 pg 14
0.030 max
24.026.0
-
bal
1.20 max
3.05.0
0.240.32
6.08.0
0.035 max
0.020 max
0.80 max
NICKEL, VOL. 36, Nº 3, 2021 | 15
It’s a striking, bold new centrepiece in the French city of Arles, a 56-metrehigh tower. Its twisted facade is composed of 11,000 irregularly arranged stainless steel panels, punctuated by protruding glass window boxes, rising from a circular glass drum. Designed by Pritzker Prize-winning architect Frank Gehry, it pays tribute to the surrounding landscape and what was perhaps, in their own time, Arles’ most famous residents: the Romans and the artist Vincent van Gogh. The “creative campus” hub is on a former railyard that was left vacant in 1986.
© ADRIAN DEWEERDT
© IWAN BAAN
A LUMINOUS ICON LUMA ARLES TOWER
The cylindrical base invokes Arles’s two-tiered Roman amphitheatre built in 90 AD. The gleaming stainless steel clad upper levels were inspired by Vincent van Gogh’s Starry Night, painted in 1889 while he was at the Saint-Paul-de-Mausole asylum. 16 NICKEL, | NICKEL,VOL. VOL.36,36,NºNº3,3,2021 2021
Gehry elaborated on his vision for the Tower, “The façade of the new building takes its inspiration from the limestone peaks of Les Alpilles. The building changes in appearance as one moves around it, as each of the panels reflects light differently. Rendered in stainless steel, the building panels simultaneously reference the tradition of masonry construction
of the region and the industrial heritage of its immediate site.” The building is clad in 220 tonnes of Type 316L (UNS S31603) patterned stainless steel. Patterned stainless steel is a cold rolling process where a specific pattern is embossed onto the sheet. The embossing process releases tension from the sheets to achieve ultimate light reflectivity.