College Level Chemistry

Page 98

This Lewis structure, also called the Lewis dot structure, can be drawn for any type of covalent bond structure. Again, this involves bonding between nonmetals and nonmetals or metalloids only.

MOLECULAR ORBITAL THEORY According to molecular orbital theory, chemical bonding happens when the attractive forces between an electron and two nuclei adjacent to one another overcomes the repulsion of the nuclei with each other. Imagine that there is a region of space between two nuclei that represents the “binding region”. Areas not involved in bonding and where the electron is not located is called the “anti-binding region”. The orbital or orbitals that participate in the binding process become the molecular orbitals of the atom and are the molecular orbitals of the molecule as a whole. The bonding molecular orbital is one that has become involved in the bonding process. As the 1s orbital of the hydrogen atom, for example, becomes close to another 1s orbital of another hydrogen atom, these two molecular orbitals are available for bonding. When these two atoms ultimately share an electron so that there are two electrons in the molecular orbital, it becomes a bonding molecular orbital that is shared between the two atoms. It is also referred to as a sigma orbital. So far, we have referred to an orbital as having a specific shape. So, what is the shape of the orbital when it has combined? It goes back to what we know of orbitals and electrons. When orbitals combine, they can change their shape but, as in any orbital, the electrons must have opposite spin numbers, with one having a +1/2 charge and one having a -1/2 charge. If they are out of phase with each other (both positive or both negative), this is called an antibonding orbital. If the two are in phase with each other, it is called a bonding orbital. Antibonding orbitals will be similar to the canceling out of two wave forms in the ocean water with a nodal surface where the bond cannot occur because the wave does not occur. This is an unfavorable situation. The bonding orbital does not have a nodal surface so the electrons can interact within the space. Remember that a node is a place

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Summary

6min
pages 242-245

Quiz

2min
pages 238-241

Key Takeaways

1min
page 237

Lipids

1min
pages 235-236

Carbohydrates

2min
pages 228-231

Nucleic Acids

1min
pages 232-234

Proteins

1min
pages 226-227

Benzene Derivatives

1min
page 218

Basics of Biochemistry

1min
page 225

Structural Isomerism

2min
pages 220-222

Isomerism

1min
page 219

Alkenes and Alkynes

1min
page 217

Nernst Equation

2min
pages 205-206

Quiz

3min
pages 209-212

Key Takeaways

1min
page 208

Cycloalkanes

1min
page 216

Electromotive Force

1min
page 207

Quiz

3min
pages 193-196

Key Takeaways

1min
page 192

Faraday’s Law

1min
page 204

Hydrolysis

2min
pages 190-191

Buffers

1min
page 189

pH Scale

1min
pages 185-186

Quiz

3min
pages 176-179

Quiz

3min
pages 165-168

Key Takeaways

1min
page 175

Redox Reactions in Common Situations

1min
page 174

Key Takeaways

1min
page 164

Crystals

3min
pages 133-136

Colloids

1min
pages 162-163

Anomalous Colligative Properties

1min
page 159

Colligative Properties

1min
page 158

Quiz

3min
pages 144-147

Liquid Forces

5min
pages 139-142

Liquids

2min
pages 137-138

Water Condensation, Boiling, and Evaporation

7min
pages 129-132

Key Takeaways

1min
page 120

Chemical Equilibrium

4min
pages 117-119

Quiz

3min
pages 121-124

Energy of Activation

1min
page 116

Rates of Reactions

1min
page 115

Limiting Reagents

1min
page 114

Writing Reactions

4min
pages 111-113

Types of Chemical Reactions

1min
page 110

Quiz

2min
pages 105-107

Key Takeaways

1min
page 104

Hydrogen Bonding

1min
page 102

Bonding in Metals

1min
page 103

Shapes of Molecules

3min
pages 99-101

Covalence

1min
pages 96-97

Molecular Orbital Theory

1min
page 98

Quiz

3min
pages 85-88

Key Takeaways

1min
page 84

Rules of Thermochemistry

1min
page 83

Enthalpy and Energy

3min
pages 81-82

Calorimetry

2min
pages 79-80

Heat Capacity

3min
pages 77-78

Laws of Thermodynamics

3min
pages 75-76

Properties of Heat in Chemistry

2min
page 74

Quiz

3min
pages 69-72

Graham’s Law of Effusion

1min
page 67

Key Takeaways

1min
page 68

Kinetic Theory

1min
page 66

Partial Pressures in Gases

1min
page 65

Boyle’s Gas Law

1min
page 62

Gas laws

1min
page 61

Pressures and Gases

1min
page 60

Quiz

2min
pages 51-54

Magnetic Properties in Atoms

1min
page 49

Electronegativity

1min
page 46

Key Takeaways

1min
page 50

Electron Affinity

3min
pages 44-45

Quiz

2min
pages 32-35

Ionization Energy

1min
page 26

Atomic Mass Number

1min
page 17

Equivalent Weight and Mole Ratio

1min
page 30

Isotopes

1min
page 18

Key Takeaways

1min
page 31

Atomic Number

2min
pages 15-16

Preface

6min
pages 9-12

Atomic Radius

1min
page 25
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