College Level Chemistry

Page 44

up to fill up the orbitals that already have an electron in them. This leads to a total of 10 electrons in the five orbitals per period. As always, the spins of the electrons will be opposite when they do inhabit the same orbital. You need to know that it isn’t exactly written in the way you’d think. Rather than write Scandium, for example as 1s22s22p63s23p64s23d1, which would make the most sense, it is instead written with the 3 level orbitals clumped together and the four level orders clumped together, like this: 1s22s22p63s23p63d14s2. This is made even more confusing by the fact that the sequence for chromium is written differently, according to the levels that get filled up first, which makes the chromium sequence go like this: 1s22s22p63s23p63d54s1. So, the rules for filling up electrons in orbitals are that first the Periodic Table is used to find the atomic number or the total electron number. Next, fill up the 1s, 2s, 2p, 3s, 3p, 4s, 4d, and 4p orbitals except that in copper and chromium, the pattern is broken up and has the d orbital and s orbital pattern switched as was described.

ELECTRON AFFINITY The definition of electron affinity is the change in energy (as listed in kilojoules or kJ per mole) in the gaseous phase when an electron is added to the atom in order to form a negative ion. It is basically the likelihood that a neutral atom will gain an electron. It is through chemical equations that atoms gain or lose electrons. A reaction that releases energy is called an exothermic reaction, while a reaction that absorbs energy is called an endothermic reaction. Because energy is released in an exothermic reaction, the energy is given a negative sign. The opposite is true of an endothermic reaction, which is given a positive sign. When an electron is added to a neutral atom, this results in the release of energy, giving the reaction a negative sign. This holds true only for the first electro affinity so first electron affinities are negative. How it looks is this: Atom + an electron goes to a negatively charged ion plus energy (which makes it exothermic). When it comes to adding a second electron; however, there is more energy required to add an electron to what is already a negatively charged

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Summary

6min
pages 242-245

Quiz

2min
pages 238-241

Key Takeaways

1min
page 237

Lipids

1min
pages 235-236

Carbohydrates

2min
pages 228-231

Nucleic Acids

1min
pages 232-234

Proteins

1min
pages 226-227

Benzene Derivatives

1min
page 218

Basics of Biochemistry

1min
page 225

Structural Isomerism

2min
pages 220-222

Isomerism

1min
page 219

Alkenes and Alkynes

1min
page 217

Nernst Equation

2min
pages 205-206

Quiz

3min
pages 209-212

Key Takeaways

1min
page 208

Cycloalkanes

1min
page 216

Electromotive Force

1min
page 207

Quiz

3min
pages 193-196

Key Takeaways

1min
page 192

Faraday’s Law

1min
page 204

Hydrolysis

2min
pages 190-191

Buffers

1min
page 189

pH Scale

1min
pages 185-186

Quiz

3min
pages 176-179

Quiz

3min
pages 165-168

Key Takeaways

1min
page 175

Redox Reactions in Common Situations

1min
page 174

Key Takeaways

1min
page 164

Crystals

3min
pages 133-136

Colloids

1min
pages 162-163

Anomalous Colligative Properties

1min
page 159

Colligative Properties

1min
page 158

Quiz

3min
pages 144-147

Liquid Forces

5min
pages 139-142

Liquids

2min
pages 137-138

Water Condensation, Boiling, and Evaporation

7min
pages 129-132

Key Takeaways

1min
page 120

Chemical Equilibrium

4min
pages 117-119

Quiz

3min
pages 121-124

Energy of Activation

1min
page 116

Rates of Reactions

1min
page 115

Limiting Reagents

1min
page 114

Writing Reactions

4min
pages 111-113

Types of Chemical Reactions

1min
page 110

Quiz

2min
pages 105-107

Key Takeaways

1min
page 104

Hydrogen Bonding

1min
page 102

Bonding in Metals

1min
page 103

Shapes of Molecules

3min
pages 99-101

Covalence

1min
pages 96-97

Molecular Orbital Theory

1min
page 98

Quiz

3min
pages 85-88

Key Takeaways

1min
page 84

Rules of Thermochemistry

1min
page 83

Enthalpy and Energy

3min
pages 81-82

Calorimetry

2min
pages 79-80

Heat Capacity

3min
pages 77-78

Laws of Thermodynamics

3min
pages 75-76

Properties of Heat in Chemistry

2min
page 74

Quiz

3min
pages 69-72

Graham’s Law of Effusion

1min
page 67

Key Takeaways

1min
page 68

Kinetic Theory

1min
page 66

Partial Pressures in Gases

1min
page 65

Boyle’s Gas Law

1min
page 62

Gas laws

1min
page 61

Pressures and Gases

1min
page 60

Quiz

2min
pages 51-54

Magnetic Properties in Atoms

1min
page 49

Electronegativity

1min
page 46

Key Takeaways

1min
page 50

Electron Affinity

3min
pages 44-45

Quiz

2min
pages 32-35

Ionization Energy

1min
page 26

Atomic Mass Number

1min
page 17

Equivalent Weight and Mole Ratio

1min
page 30

Isotopes

1min
page 18

Key Takeaways

1min
page 31

Atomic Number

2min
pages 15-16

Preface

6min
pages 9-12

Atomic Radius

1min
page 25
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